• 한국재료학회지
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• 제21권2호
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• pp.73-77
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• 2011

Specific heat of a crystal is the sum of electronic specific heat, which is the specific heat of conduction electrons, and lattice specific heat, which is the specific heat of the lattice. Since properties such as crystal structure and Debye temperature do not change even in the superconducting state, the lattice specific heat may remain unchanged between the normal and the superconducting state. The difference of specific heat between the normal and superconducting state may be caused only by the electronic specific heat difference between the normal and superconducting states. Critical temperature, at which transition occurs, becomes lower than $T_{c0}$ under the influence of a magnetic field. It is well known that specific heat also changes abruptly at this critical temperature, but magnetic field dependence of jump of specific heat has not yet been developed theoretically. In this paper, specific heat jump of superconducting crystals at low temperature is derived as an explicit function of applied magnetic field H by using the thermodynamic relations of A. C. Rose-Innes and E. H. Rhoderick. The derived specific heat jump is compared with experimental data for superconducting crystals of $MgCNi_3$, $LiTi_2O_4$ and $Nd_{0.5}Ca_{0.5}MnO_3$. Our specific heat jump function well explains the jump up or down phenomena of superconducting crystals.

• 한국결정성장학회지
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• 제15권4호
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• pp.141-144
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• 2005

[ $(Y_{0.5}Sm_{0.25}Nd_{0.25})Ba_2Cu_3O_y$ ] [(YSN)-123] high $T_c$ composite superconductors with $CeO_2$ addition were systematically investigated by top seeded melt growth (TSMG) process in air atmosphere. A melt textured $NdBa_2Cu_3O_y$ (Nd-123) single crystal was used as a seed for achieving the c-axis alignment large grains perpendicular to the surface of (YSN)-123 composite oxides. The size of $(Y_{0.5}Sm_{0.25}Nd_{0.25})_2BaCuO_5$ [(YSN)211] nonsuperconducting inclusions of the melt textured (YSN)-123 samples with $CeO_2$ addition were remarkably reduced and uniformly distributed within the (YSN)123 superconducting matrix except in the region very close to the Nd-123 seed crystal. The sample showed a sharp superconducting transition of 91 K.

• 한국전기전자재료학회논문지
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• 제36권1호
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• pp.70-73
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• 2023

To improve superconductor properties, the size of the crystal grains of the superconductor should be adjusted, the amount of electricity flowing through the superconductor should be increased, and the superconductor should be designed to withstand external magnetic fields. It is necessary to control the microstructure so that many flux pinning centers are developed inside the superconductor so that defects are generated physically or chemically, and the micro secondary phase for trapped magnetic flux must be dispersed inside the superconductor. In order to measure the superconducting magnetic force of the superconducting bulk in a simplified manner, the superconducting magnetic force was analyzed using an Nd-Fe-B permanent magnet of 3.80 kG. In particular, by delaying the growth of partially melted Y₂BaCuO₅ particles, we devised a plan to refine Y₂BaCuO₅ particles to effectively improve superconducting magnetic force, and analyzed superconducting magnetic force in a single crystal YBa₂Cu₃O_7-y superconducting bulk using a gauss meter. The melted superconducting bulk traps 80% or more of the applied magnetic field, and can be used as a bulk magnet of high magnetic field magnetization applicable to electric power equipment.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2004년도 High Temperature Superconductivity Vol.XIV
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• pp.25-25
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• 2004

• 한국결정성장학회지
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• 제9권2호
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• pp.137-140
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• 1999

Flux법에 의해 성장된 $Bi_2Sr_2CaCu_2O_{8+{\delta}}(Bi2212)$ 단결정의 초전도 특성에 미치는 열처리 및 불순물의 영향을 자화측정에 의해 조사하였다. 초전도 특성은 불순물인 Mg와 Al의 영향을 받음을 알 수 있었으며, 초전도 전이온도(T,) 는 Mg 불순물의 영향에 의해 보다 낮아졌다. 그러나 성장된 결정은 열처리에 의해 초전도 특성이 개선됨을 알 수 있었 으며, 특히 MgO 도가니 사용에 의해 성장된 결정이 $Al_2O_3$ 도가니에 비해서 반자계특성이 현저하게 증가되었다. 반자계 특성의 개선효과에 의해 Mg 불순물은 초전도 특성 열화의 주요 요소라고 생각될 수 없음을 알 수 있었다.

• 한국결정성장학회지
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• 제15권5호
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• pp.188-192
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• 2005

High $T_c(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y[(YNS)-123]$ superconductors with/without $CeO_2$ additive were systematically investigated by the zone melt growth process in air. Cylindrical green rods of (YNS)-123 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mould. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_2BaCuO_5[(YNS)211]$ nonsuperconducting inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$[(YNS)123] superconducting matrix. In this study, optimum melting temperature and growth rate were $1100^{\circ}C$ and 3 mm/hr, respectively. The directionally melt-textured (YNS)-123 sample with $CeO_2$ additive showed an onset critical temperature $(T_c)\;T_c{\geq}93K$ and sharp superconducting transition.

• 한국전자통신학회논문지
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• 제13권1호
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• pp.23-28
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• 2018

초전도 결정의 임계 온도 $T_{CH}$에서의 비열 불연속 폭을, Gibbs 자유 에너지에 관한 열역학 관계식과 임계 자기장 $H_{CT}$의 선형 모델을 이용하여, 인가 자기장 H의 함수로 이론적으로 구한다. 그리고 구한 비열 불연속 폭을 J. Kacmarcik 등에 의한 MgCNi3 초전도체 결정 대상의 실험 결과와 비교 분석한다. 여기서 구한 비열 불연속 폭은 초전도체 결정의 비열 점프 업 현상을 잘 설명한다.

• 한국전기전자재료학회논문지
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• 제31권2호
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• pp.90-93
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• 2018

This aim of this study was to develop a process for creating bulk single-crystal YBaCuO superconductors in a high magnetic field. To support the bulk unidirectional growth of $YBa_2Cu_3O_{7-y}$, $SmBa_2Cu_3O_{7-y}$ seeds were planted inside YBaCuO composites and samples were produced by melting, enabling the growth of two YBaCuO superconductors. Due to the magnetism generated inside the superconductor of the upper sample, the magnetization inside the superconducting single crystals was evenly distributed, the sharpness of the induced magnetic force was improved, and the superconducting magnetization were significantly improved. This approach is widely applicable for the production of superconducting wires and current leads used for DC power breakers.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.486-489
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• 2002

Temperature(T) dependence of the sheet resistance( $R_{$\square$}$) has been investigated on the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The $R_{$\square$}$-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition took place, with the resistance on the normal state, RN, reaching 4.l㏀ at 80 K. This $R_{N}$ value is close to the universal quantum number, h/(2e)$^2$≡6.5㏀ predicted by the Kosterlitz-Thouless(KT) transition theory. The $R_{$\square$}$-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.e.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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• pp.18-21
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• 1999

This paper is to present the general descriptions and their research trend of MRl/NMR which has already commercialized and also is more successful than any other applications of superconducting magnet, Superconducting Single Crystal Growing Equipment and Superconducting Magnetic Separation technology which are practically used in the related areas, and power electric application machine, which is the most effective and efficient one among the applications using high magnetic field. Therefore, it is hoped that this study will help to establish the ground of the industrial application of superconductivity in Korea.