• Title/Summary/Keyword: Sulphur

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세계 인산질 비료 현황

  • Korea Fertilizer Industry Association
    • 비료회보
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    • s.589
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    • pp.10-35
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    • 2006
  • 지금까지 Fertilizer International에서 발표한 240명 이상의 전 세계 인산 비료업계 종사자들이 영국 Sulphur Events의 제2회 인산 회의 및 전시를 위해 브뤼셀에 모인 것에 대한 사진 기사와 간단한 보고로 이루어졌다. 매일 참가자들이 성황을 이룬 것에서 입증된 것처럼, 2일 간의 회기에 발표된 논문들이 회의 성공의 주요 요소였다. 다음은 회의에서 발표된 논문들을 요약한 것이다.

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Agglomeration of fine anthracite using oil and modified styrene (Oil과 Modified Styrene을 사용(使用)한 미립(微粒) 무연탄(無煙炭)의 응집(凝集))

  • Lee, Jae-Jang;Jang, Dong-Sung
    • Journal of Industrial Technology
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    • v.7
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    • pp.27-47
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    • 1987
  • Fine anthracite is very difficult to upgrade by conventional processes such as gravity concentration or froth flotation, because large quantities of fine coals are generated at the mining and preparation stages and a significant portion of these fine coals are mixed with gangue minerals. This study, therefore, was carried out for the purpose of improving recovery of low ash clean coal, effective beneficiation of low-grade coking coal and removal of sulphur from high-sulphur coals by employing the method of selective agglomeration using oil or polystrene flocculants, for coals which are generally hydrophobic in nature will be extracted by using flocculants. Studies were performed by varying solid concentration, concetration of bridging liquid, mixing speed and mixing time, balling speed and balling time, dispersant dosage, flocculant dosage, pulp pH, and particle size. The results were : when the methods of the oil agglomeration and selective flocculation were employ(in the two process the sample was ground to the size of -74 micron), 1) ash content of the agglomerated coal was 9.85, 7.83%, 2) combustibel recovery of it was 98.5%, 93.5%, respectively. It was observed in selective flocculation that polystyrene is an effective flocculant for coal, De-entrapment of shale from the concentrate flocculated by mechanical agitation was necessary for substantional reductions in final ash content.

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Recovery Process for the Recycling of Waste Carbon Black

  • Lee, Sungoh;Nampyo Kook;Tam Tran;Bangsup Shin;Kim, Myongjun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.215-219
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    • 2001
  • Impurities removal from waste carbon black was carried out to produce high-grade carbon black. A lot of hydrophilic carbon black is produced as a byproduct of the hydrogen production process by flame decomposition of water. Due to its impurity content such as sulphur, iron, ash and etc., it can only be used as low-grade carbon or burnt out. High-grade hydrophilic carbon black is 3-5 times more expensive than oil-based carbon black because of its process difficulties and requires pollutant treatment. Hydrophilic carbon is normally used far conductive materials for batteries, pigment for plastics, electric wire covering, additives for rubber, etc.. In these applications, hydrophilic carbon must maintain its high purity. In this study magnetic separation, froth flotation and ultrasonic treatment were employed to remove impurities from the low-grade hydrophilic carbon black. As results, the ash, iron and sulphur content of product decreased to less than 0.01wt.%, 0.0lwt.% and 0.3wt.% respectively, and the surface area of product was about 930 $m^2$/g.

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Synthesis, Characterization and Antimicrobial Activity of Zirconium (IV) Complexes

  • Sharma, Shobhana;Jain, Asha;Saxena, Sanjiv
    • Journal of the Korean Chemical Society
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    • v.56 no.4
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    • pp.440-447
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    • 2012
  • Heteroleptic complexes of zirconium (IV) derived from bulky Schiff base ligands containing a sulphur atom and oximes of heterocyclic ${\beta}$-diketones of the general formula ZrLL' (where $LH_2=RCNH(C_6H_4)SC:C(OH)N(C_6H_5)N:CCH_3$, $R=-C_6H_5$, $-C_6H_4Cl(p)$ and $L^{\prime}H_2=R^{\prime}C:(NOH)C:C(OH)N(C_6H_5)N:CCH_3$, $R^{\prime}=-CH_2CH_3$, $-C_6H_5$, $-C_6H_4Cl(p)$ were prepared by the reactions of zirconium tetrachloride with disodium salts of Schiff bases ($L\;Na_2$) and oximes of heterocyclic ${\beta}$-diketones ($L^{\prime}\;Na_2$) in 1:1:1 molar ratio in dry refluxing THF. The structures of these monomeric zirconium (IV) complexes were elucidated with the help of elemental analysis, molecular weight measurements, spectroscopic (IR, NMR and mass) studies. A distorted trigonal bipyramidal geometry may be suggested for these heteroleptic zirconium (IV) complexes. The ligands (bulky Schiff base ligands containing a sulphur atom and oximes of heterocyclic ${\beta}$-diketones) and their heteroleptic complexes of zirconium (IV) were screened against A. flavus, P. aeruginesa and E. coli.

Effect of Low Sulphur Fuel Oil Use on Korean Container Shipping Companies by IMO Environmental Regulations (IMO 환경규제에 따른 저유황 연료유 사용이 국적 컨테이너 선사에 미치는 영향)

  • Park, Sunghwa;Han, Chulhwan;Kim, Taeil
    • Journal of Korea Port Economic Association
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    • v.36 no.1
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    • pp.23-40
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    • 2020
  • This study examined the background of IMO environmental regulations and countermeasures of domestic and foreign liner shipping companies and also analyzed the additional cost and profitability of container shipping companies by implementation of IMO 2020, when the fuel oil is converted to low sulfur oil. The results show that the national flag carrier would incur significant additional costs when using low sulfur oil, which would worsen its profitability in all scenarios. These analysis results suggest that for regional shipping companies need reasonable BAF setting standards, which is flexible to the price of fuel oil and also seek ways to co-exist through mutual cooperation among oil refiners, shippers and shipping companies.

Operational behaviour and reliability measures of a viscose staple fibre plant including deliberate failures

  • Sengar, Surabhi;Singh, S.B.
    • International Journal of Reliability and Applications
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    • v.13 no.1
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    • pp.1-17
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    • 2012
  • This Paper deals with the stochastic behavior and failure analysis of a Viscose Staple Fibre Plant which produces fibre for making clothes. The fibre making plant is a complex system with various subsystems as: Vendor (supplies Charcoal and Sulphur, raw materials for the process), Carbon di sulphide Plant, Acid Plant, Pulp Plant and Processing Plant. The considered system can completely fail due to failure of any of the subsystems. The Carbon di Sulphide Plant can fail in two different ways, due to lack of Sulphur or Charcoal. Processing Plant has the configuration 5-out-of-10: d and 6-out-of-10: f. It is also assumed that the system can fail due to workers strike and catastrophic failure. All failures follow exponential time distribution whereas all repairs follow general time distribution. Preventive Maintenance policy has been applied to reduce the failure in the system. Various reliability characteristics such as transition state probabilities, steady state behavior, reliability, availability, M.T.T.F and the cost analysis have been obtained using supplementary variable technique and Gumbel-Hougaard copula methodology.

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The Fabrication of $n^+-p^+$ InP Solar Cells by the Diffusion of Sulphur (S확산에 의한 $n^+-p^+$ InP 태양전지의 제작)

  • Jung, Ki-Ung;Kim, Seon-Tai;Moon, Dong-Chan
    • Solar Energy
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    • v.10 no.3
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    • pp.60-65
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    • 1990
  • [ $n^+-p^+$ ] InP homojunction solar cells were fabricated by thermal diffusion of sulphur into a $p^+$-InP wafer($p=4{\times}10^{18}cm^{-3}$), and a SiO film($600{\AA}$ thick) was coated on the $n^+$ layer as an antireflection(AR) coating by an e-beam evaporator. The volume of the cells were $5{\times}5{\times}0.3mm^3$. The front contact grids of the cells with 16 finger pattern of which width and space were $20{\mu}m$ and $300{\mu}m$ respectively, were formed by photo-lithography technique. The junction depth of sulphur were as shallow as about 0.4r m We found out the fabricated solar cells that, with increasing the diffusion time, short circuit current densities($J_{sc}$), series resistances($R_s$) and energy conversion efficiencies(${\eta}$) were increased. The cells show good spectral responses in the region of $5,000-9,000{\AA}$. The short circuit current density, the open circuit voltage( $V_{oc}$), the fill factor(F.F) and the energy conversion efficiency of the cell were $13.16mA/cm^2$, 0.38V, 53.74% and 10.1% respectively.

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A Dynamic-Stochastic Model for Air Pollutant Concentration (大氣汚染濃度에 관한 動的確率모델)

  • 김해경
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.3
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    • pp.156-168
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    • 1991
  • The purpose of this paper is to develop a stochastic model for daily sulphur dioxide $(SO_2)$ concentrations prediction in urban area (Seoul). For this, the influence of the meteorological parameters on the $SO_2$ concentrations is investigated by a statistical analysis of the 24-hr averaged $SO_2$ levels of Seoul area during 1989 $\sim$ 1990. The annual fluctuations of the regression trend, periodicity and dependence of the daily concentration are also analyzed. Based on these, a nonlinear regression transfer function model for the prediction of daily $SO_2$ concentrations is derived. A statistical procedure for using the model to predict the concentration level is also proposed.

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