• Title/Summary/Keyword: Sulfur dioxide effect

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High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere (고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구)

  • Lee, Han-sang;Jung, Jine-sung;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

An Experimental Study On The Effect of Bopaetang on Rats with Exposured to Sulfur Dioxide (보폐탕이 이산화황에 폭로된 흰쥐의 호흡기 손상에 미치는 영향( I ))

  • Soh Kyung-Sun
    • Journal of Society of Preventive Korean Medicine
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    • v.2 no.1
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    • pp.55-65
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    • 1998
  • Surfur dioxide, one of the air pollutants, has been related increasing morbidity rates due to respiratory damages. To investigate the effect of Bopaetang(補肺湯) on rats induced by exposur of $SO_2$, an experimental study was done the changes on white blood cell(W5C), the content of glycoprotein in treachea and the edema, congestion, inflammatory infiltrates of trachea. The experimental groups are the normal group, control group and sample group( administered Bopaetang to rats induced by exposur of $SO_2$). The results were as follows; 1. The change on WBC on rats induced by exposur of $SO_2$ were made significant differences in sample group compared with control group. 2. The content of Glycoprotein In trachea were made significant differences in sample group compared with control group. 3. The edema, congestion, inflammatory infiltrates of treachea were made significant differences in sample group compared with control group.

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Effect of Inorganic Nanocomposite Based Liners on Deodorization of Kimchi

  • Chung, Kwon;Park, Hyun Jin;Shin, Yang Jai
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.2
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    • pp.55-62
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    • 2021
  • This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO2), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl2, and TiO2 powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

INTEGRATED LIFE-CYCLE COST ANALYSIS CONSIDERING ENVIRONMENTAL COSTS: A HIGHWAY PROJECT CASE

  • Woo-Sik Jang;Heedae Park;Sungmin Kim;Seung Heon Han;Jong Seo Jeon
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.273-279
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    • 2011
  • Concerns over the environment have spawned a number of research studies in the construction industry, as the construction of built environments and large infrastructures involves diverse environmental impacts and loads of hazardous emissions. Many researchers have attempted to quantify these environmental loads, including greenhouse gases, carbon dioxide, nitrogen dioxide, and sulfur dioxide, to name a few. However, little research has been conducted regarding integrating the life-cycle assessment (LCA) of environmental loads with the current life-cycle cost analysis (LCCA) approach. This study aims to estimate the environmental loads as a monetary value using the European Climate Exchange (ECX) rate and, then, to integrate those impacts with the pure construction cost. Toward this end, this study suggests an integrated approach that takes into account the environmental effect on the evaluation of the life-cycle cost (LCC). The bill of quantity (BOQ) data of a real highway project are collected and analyzed for this purpose. As a result, considering the environmental loads in the pavement process, the total LCC increased 16% from the traditional LCC cost. This study suggests an integrated approach that will account the environmental effect on the LCC. Additionally, this study is expected to contribute to better decision-making, from the perspective of more sustainable development, for government as well as for contractors.

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Measurement of Sulfur Dioxide Concentration Using Wavelength Modulation Spectroscopy With Optical Multi-Absorption Signals at 7.6 µm Wavelength Region (7.6 µm 파장 영역의 다중 광 흡수 신호 파장 변조 분광법을 이용한 이산화황 농도 측정)

  • Song, Aran;Jeong, Nakwon;Bae, Sungwoo;Hwang, Jungho;Lee, Changyeop;Kim, Daehae
    • Clean Technology
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    • v.26 no.4
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    • pp.293-303
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    • 2020
  • According to the World Health Organization (WHO), air pollution is a typical health hazard, resulting in about 7 million premature deaths each year. Sulfur dioxide (SO2) is one of the major air pollutants, and the combustion process with sulfur-containing fuels generates it. Measuring SO2 generation in large combustion environments in real time and optimizing reduction facilities based on measured values are necessary to reduce the compound's presence. This paper describes the concentration measurement for SO2, a particulate matter precursor, using a wavelength modulation spectroscopy (WMS) of tunable diode laser absorption spectroscopy (TDLAS). This study employed a quantum cascade laser operating at 7.6 ㎛ as a light source. It demonstrated concentration measurement possibility using 64 multi-absorption lines between 7623.7 and 7626.0 nm. The experiments were conducted in a multi-pass cell with a total path length of 28 and 76 m at 1 atm, 296 K. The SO2 concentration was tested in two types: high concentration (1000 to 5000 ppm) and low concentration (10 ppm or less). Additionally, the effect of H2O interference in the atmosphere on the measurement of SO2 was confirmed by N2 purging the laser's path. The detection limit for SO2 was 3 ppm, and results were compared with the electronic chemical sensor and nondispersive infrared (NDIR) sensor.

The Study on Foam Formation in Waterslag-Bentonite System (수광재와 백토조합물에서의 기포형성에 관한 연구)

  • 김종희;송한식
    • Journal of the Korean Ceramic Society
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    • v.14 no.4
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    • pp.248-255
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    • 1977
  • The effect of firing temperature, soaking time and batch composition upon the glass phase and pore formation as well as their distribution in slag foamed glass was investigated. Sulfur dioxide gas produced by the oxidation and reduction of metal sulfide in waterslag was attributed to foam forming agent. Slag foamed glass matrix was mainly composed of 35~60% glas phase and melilite crystalline phase. The increment of bentonite addition in batch lowered the foam forming temperature in studied system. The result showed also that the foam size distribution was broadened as th firing temperature wa inbereased.

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Studies on the Effects of Ginseng Extract for Mucociliary Change in Mice Nasal Septum Epithelia Exposured to Sulfur Dioxide gas (인삼(人蔘) 추출액(抽出液)이 SO2 Gas에 폭로(暴露)된 새앙쥐 호흡기상피(呼吸器上皮)의 섬모(纖毛)변화에 미치는 영향(影響)에 관한 연구(硏究))

  • Kim, Moo-Kang;Cho, Sung-Whan;Ryu, Si-Yun;Lee, Geun-Jwa;Han, Kyong-O;Lee, Chul-Ho
    • Korean Journal of Veterinary Research
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    • v.31 no.3
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    • pp.241-251
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    • 1991
  • In order to investigate the effect of Panax ginseng extract and it's degree in mucociliary change of mice nasal septum epithelia exposured to sulfur dioxide, 96 ICR male mice were used. They were at first divided the 4th week, the 8th week or the 16th week groups according to the age after birth and 6 hour or 12 hour groups according to the $SO_2$ gas exposured hour in a day, and at control, 50mg, 100mg and 200mg injection groups according to the dosage of the freeze-drying powder of the ginseng extract which was injected into the mouse peritoneal cavities in the condition of the solution solved with physiological saline solution. Each subgroups which were divided finaly included 4 male mice. The histological tissue sections for observation were made from nasal septum, posterior nasal orfice and trachea. The results obtained by experiments were summarized as followings. 1. The loss of the nasal mucosa epithelial cilia of the mouse exponsure to the $SO_2$ gas after ginseng extract injection was apparently diminish eompare to those exposured only $SO_2$ gas without pretreatment of ginseng extract (p<0.01). 2. The inhibition effect for the loss of nasal mucocilia according to the ginseng extract dosages not found in this research (p>0.05). 3. There were differences in the loss of nasal mucosa cilia according to the $SO_2$ gas exposure time between the control group and ginseng extract pretreatment group (p<0.01). 4. According to the increase of the postnatal time, there were remarkable differences between the control group and the ginseng extract pretreatment groups in the loss of nasal mucosa cilia (p<0.01). 5. Ciliary changes of the posterior nasal orifice and trachea according to the $SO_2$ gas exposure time, mice age and ginseng dosages, were not dearly observed in this light microscopical observation.

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Effect of Green Buffer Zone in Reducing Gaseous Air Pollutants in the Shiwha Industrial Area (시화공단 완충녹지대의 대기오염물질 저감 효과 분석)

  • Song Young-Bae
    • Journal of the Korean Institute of Landscape Architecture
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    • v.33 no.6 s.113
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    • pp.90-97
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    • 2006
  • The effects of a green buffer zone to protect a residential area from air pollution from industrial facilities and traffic was examined by analyzing the case of a green buffer zone in the Shiwha industrial complex. The green buffer zone is 175 m wide. The intent was to assess the dispersion patterns of atmospheric air pollutants and the reduction in concentration around the green buffer zone. To measure atmospheric sulfur dioxide$(SO_2)$ and nitrogen dioxide$(NO_2)$ concentration, badge-type passive samplers were used and set up at 76 locations in order to measure the concentration of air pollutants with respect to the spatial dispersion. The weighted mean values of $SO_2\;and\;NO_2$ concentration were $3\~57 ppb\;and\;18\~62 ppb$ and the differences among the green buffer zone, the industrial area and the residential areas were $0.7\~1.1 ppb$. Mean values of atmospheric concentrations of $NO_2$ were similar in industrial and, residential areas and the green buffer zone. Results of the study show that the effect of the green buffer zone on reducing the dispersion of air pollutants was very low. This study also recommends that micro-climate, i.e., wind direction should be considered as a factor for planning and design of green buffer zones.

Reduction of Nitrous Oxide Emission by EGR Method on Diesel Engine (디젤엔진에서 배기가스 재순환 방법을 이용한 아산화질소의 배출률 저감)

  • Yoo, Dong-Hoon
    • Journal of Power System Engineering
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    • v.19 no.3
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    • pp.16-21
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    • 2015
  • Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.

NOx Removal of Mn Based Catalyst for the Pretreatment Condition and Sulfur Dioxide (전처리 조건 및 황산화물에 대한 Mn-Cu계 촉매의 탈질특성)

  • Park, Kwang-Hee;You, Seung-Han;Park, Young-Ok;Kim, Sang-Wung;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.4
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    • pp.1923-1930
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    • 2012
  • Mn-Cu catalysts were tested for selective catalytic reduction of NOx with NH3. Influence of initial reaction temperature was studied for NOx conversion in which reaction temperature was changed three patterns. NOx conversion of catalysts calcined at 200, 300 and $340^{\circ}C$ was measured during the changing temperature. Hydrogen conversion efficiency of calcined catalysts was also measured in the $H_2$-TPR system. The deactivation effect of $SO_2$ on catalyst was investigated with the on-off control of $SO_2$ supply. The catalyst which calcined above $340^{\circ}C$ was somewhat deactivated with thermal shock. The reason of deactivation was draw from the results of surface area and hydrogen conversion.