• Title/Summary/Keyword: Sulfur detection

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Identification of 5-Jung-color and 5-Kan-color In Video (비디오에서 오정색과 오간색 식별)

  • Shin, Seong-Yoon;Pyo, Seong-Bae
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.1
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    • pp.103-109
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    • 2010
  • As color was used for formative language since a human activity was beginning, all the symptoms in the world that the human eye can see is present. In this paper, we identify Korea traditional color harmony for extracted key frames from scene change detection. Traditional color is classified as 5-Jung-color and 5-Kan-color, and determine whether to harmony. Red, blue, yellow, black, and white, called 5-Jung-color and pink, blue, purple, sulfur, and green, called the 5-Kan-color was identified. First, we extract edge using Canny algorithm. And, we are labeling and clustering colors around the edge. Finally, we identify the traditional color using identification method of traditional color harmony. The proposed study in this paper has been proven through experiments.

Effects of Chemical Etching with Sulfuric Acid on Glass Surface

  • Jang, H.K.;Chung, Y.L.;S.W.Whangbo;C.N.Whang;Lee, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.165-165
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    • 2000
  • Glass slides were chemically etched with sulfuric acid using five different methods. we investigated the effects of the chemical etching conditions on such properties as chemical composition, surface roughness, and the thermal stability of the glass. Sodium and carbon atoms in the surface of the glass are effectively eliminated by chemical etching with sulfuric acid. The glass slides were boiled for 30 min in 95% sulfuric acid and were depth profiled at room temperature with X-ray photoelectron spectroscopy (XPS), the Na ls signal was not detected in the detection limit of XPS. Surface morphology of the glass was very different depending on the concentration of sulfuric acid. The surface of the glass etched with 50% sulfuric acid was rougher than that of glass etched with 95% sulfuric acid. The sodium concentration of the glass boiled for 30 min in 95% sulfuric acid was nearly zero at the glass surface, and the sodium composition changed very little with annealing temperatures up to 35$0^{\circ}C$ in a vacuum environment. However the sulfur concentration at the glass surface due to the sulfuric acid increased with increasing temperature.

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Characteristic of Odorous Compounds Emitted from Livestock Waste Treatment Facilities Combined Methane Fermentation and Composting Process (메탄발효와 퇴비화 공정이 연계된 가축분뇨 처리시설에서 발생되는 악취물질 특성 조사)

  • Ko, Han Jong;Kim, Ki Youn;Kim, Hyeon Tae;Ko, Moon Seok;Higuchi, Takasi;Umeda, Mikio
    • Journal of Animal Science and Technology
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    • v.50 no.3
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    • pp.391-400
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    • 2008
  • Odor management is significantly concerned with sustainable livestock production because odor nuisance is a primary cause for complaint to neighbors. This study was conducted to measure the concentration of odorous compounds, odor intensity, and odor offensiveness at unit process in animal waste treatment facility combined composting and methane fermentation process by an instrumental analysis and direct olfactory method. Ammonia, sulfur-containing compounds, and volatile fatty acid were analyzed at each process units and boundary area in summer and winter, respectively. Higher concentration of odorants occurred in the summer than in the winter due to high ambient temperature. The maximum concentration of odorants was detected in composting pile when mixed manure was being turned followed by inlet, curing, outlet, and screen & packing process. Highest concentration of detected odorous compounds was ammonia ranging from 3.4 to 224.7 ppm. Among the sulfur-containing compounds measured, hydrogen sulfide was a maximum level of 2.3 ppm and most of them exceeded reported odor detection thresholds. Acetic acid was the largest proportion of VFA generated, reaching a maximum of 51 to 89%, followed by propionic and butyric acid at 1.9 to 35% and 1.8 to 15%, respectively. Malodor assessment by a human panel appeared a similar tendency in instrumental analysis data. Odor quotient for predicting major odor-causing compounds was calculated by dividing concentrations measured in process units by odor detection thresholds. In the composting process, hydrogen sulfide, ammonia, dimethyl sulfide, and methyl mercaptan were deeply associated with odor-causing compounds, while the major malodor compounds in the inlet process were methyl mercaptan, hydrogen sulfide, and butyric acid.

The Study on the Migration of Sulfite in Commercial Wooden Chopsticks (국내 유통 나무젓가락 중 이산화황 이행량에 관한 연구)

  • Park, Na-Young;Yun, Hae-Jung;Jeon, Dae-Hoon;Choi, Hyun-Cheol;Eom, Mi-Ok;Kim, Hyung-Il;Sung, Jun-Hyun;Choi, Hyun-Rock;Lee, Young-Ja
    • Journal of Food Hygiene and Safety
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    • v.23 no.3
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    • pp.218-221
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    • 2008
  • The levels of sulfites in wooden chopsticks were analyzed using two different methods, distillation-alkali titration and ion chromatography. According to the two methods, Sulfur dioxide($SO_2$) was validated by 0.6 and 0.2 ${\mu}ml$ of limit of detection(LOD), 1.8 and 0.5 ${\mu}ml$ of limit of quantification, (LOQ) and a $R^2>0.998$ for linearity, respectively. The recoveries of $SO_2$ from food simulants spiked ar levels of 100 ppm were 70.2-100.2%. 158 samples of wooden chopsticks were monitored the migrated amounts of sulfites. Sulfites were detected in 30 samples in ranged of 0.6 to 15.5 ppm. Maximum migration level, 15.5 ppm of sulfites was considered giving no harmful effect to human since it was reached 5.5% of estimated SML.

Analysis and Mechanistic Investigation of Redox Process of 2-Amino-1-cyclopentene-1-dithiocarboxylate by Adsorptive Stripping Voltammetry on Glassy Carbon Electrode (Glassy Carbon 전극에서의 벗김 전압-전류법을 이용한 2-Amino-1-cyclopentene-1-dithiocarboxylate 의 분석과 전극 반응 메카니즘의 연구)

  • Yoon-Bo Shim;Duk-Soo Park;Sung-Nak Choi;Mi-Sook Won
    • Journal of the Korean Chemical Society
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    • v.32 no.1
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    • pp.37-47
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    • 1988
  • The electrochemical behavior of 2-Amino-1-cyclopentene-1-dithiocarboxylate (acdc) was investigated by the use of polarography, cyclic voltammetry and cathodic stripping voltammetry at glassy carbon electrode. In this study, it was found that the dimer of the acdc was deposited on the glassy carbon electrode via one-electron oxidation process at +0.25V vs. SCE. The ring formation between two dithio group occurs along with the elimination of one sulfur atom. The elimination of sulfur atom occurs via two electron oxidation process at +0.8V vs. SCE. The most sensitive cathodic stripping peak due to the formation of the dimer was observed at -0.85V vs. SCE. The peak relationship between current and concentration was fairly linear in the range of 3${\times}10^{-5}{\sim}1.0{\times}10^{-6}$M. The preconcentration procedure enhanced the sensitivity about 100 times for the analysis of acdc using diffusion current. Detection limit was found to be $2.5{\times}10^{-7}$M and relative standard deviation was ${\pm}$4.1 % at $5.0{\times}10^{-6}$M DC polarography.

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Studies of gas chromatographic analysis of malodorous S compounds in air (대기 중 악취황 성분들에 대한 GC 분석의 특성)

  • Kim, Ki-Hyun;Oh, Sang In;Choi, Y.J.
    • Analytical Science and Technology
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    • v.17 no.2
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    • pp.145-152
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    • 2004
  • In this study, analytical characteristics of S gas detection technique were investigated against four major reduced S compounds (including hydrogen sulfide; methyl mercaptan; dimethyl sulfide (DMS); and dimethyl disulfide (DMDS)). To analyze such properties, an analytical system was constructed by combining the GC/PFPD system with the loop injection method. The results of our analysis indicated that response behavior of S gases differs greatly between compounds; H2S exhibited the weakest sensitivity of all compounds, while DMDS with two S-atom compounds the strongest sensitivity. To learn more about their response behavior on GC/PFPD method, their calibration patterns were compared using the three arbitrarily set concentration ranges of low, intermediate, and high. The results showed that calibration patterns of each compound are distinguished because of different factors. There was a line of evidence that calibration of $H_2S$ was affected noticeably by adsorptive loss within the system, whereas those of DMS and DMDS were influenced most sensitively by such factor as the linearity response at a given PMT voltage setting. The overall results of our study suggest that quantification of malordorous S compounds require a better knowledge of compound-specific response behavior against GC detection.

Removal Efficiency of the Deodorization Equipment and Characteristics of Malodor during the Process in Co-treatment of Sewage and Food Waste of Su-young Wastewater Treatment Plant in Busan (부산수영하수처리장 하수와 음식물쓰레기 병합처리 시 공정별 악취특성 및 후처리시설 효율평가)

  • Lee, Hyung-Don;Kang, Dae-Jong;Lee, Min-Ho;Kang, Dong-Hyo;Oh, Kwang-Joong
    • Clean Technology
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    • v.18 no.4
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    • pp.379-389
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    • 2012
  • Environmental issues are being paid more attention due to income growth, urban overcrowding, and population growth in Korea. Among the various environmental problems, odor damage is the one of the serious factors. To take example for food waste combination treatment in Su-young wastewater treatment plant in Busan, many complaints occurred because this plant locate around residential areas. The purpose of this work is not only to analyze odorous elements and their contributions but also to evaluate odor quotient (OQ), sum of odor quotient (SOQ), and treatment efficiency of bio-filter. The results of dilution sensory test of complex odor, grinder, leachate, hopper indicated higher order complex odors happen in July and August. The main odorous elements consisted of hydrogen sulfide, ammonia, methly mercaptan and acetaldehyde, which were analyzed by instrumental detection method, and methyl mercaptan was exceeded over 3,571 times of threshold. In addition, result of contribution of odor was methyl mercaptan (49.95 to 59.08%), hydrogen sulfide (20.43 to 29.27%), trimethylamine (8.82 to 13.42%) and acetaldehyde (9.17 to 11.35%). Other facilities were compared with the contribution of the odor using OQ and SOQ during the process. Sulfur compounds, acetaldehyde, and trimethylamine are high contribution of odor using OQ as well as odor intensity of grinding process is highest. As a result, sulfur compounds (e.g., methyl mercaptan and hydrogen sulfide) are highest for OQ and SOQ of grinding process is highest as 7,067. The removal efficiency of deodorization equipment was more than 90.00% in ammonia and amines, but the average efficiency of sulfur compounds was 53.51%. Thus, this facility is more higher contribution of acetaldehyde and trimethylamine than other treatment facilities. And food waste treatment in environmental area needs to consider appropriate capacity and refers to other bio-filter operating conditions.

Flame Retardant Treatment's Effects and Detection Method on Wooden Buildings' Pigment Layer (Dan-cheong) (국내 목조건축물 단청의 방염제 처리에 따른 영향 및 탐지방법 연구)

  • Kim, Dae Woon;Kim, Chul Woong;Han, Sung Hee;Chung, Yong Jae;Han, Gyu Seong
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.393-406
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    • 2014
  • To figure out the problems of flame retardant treatment (FRT) on wooden buildings, field investigation and analysis of statistical data are performed. After FRT on historical wooden building, efflorescence and exfoliation showed most often. These problems appeared especially on column, rafter and Ga-gu (Ingredients for supporting structure of a roof) which are liberally spreaded. To compare before and after FRT, analyzed 20 elements using P-XRF. In this process, found sulfur which informs FRT. This helped set up nondestructive assay. Through this process, confirmed field application by analysis residue component of Songgwang-sa Temple.

Work Environments and Exposure to Hazardous Substances in Korean Tire Manufacturing

  • Lee, Na-Roo;Lee, Byung-Kyu;Jeong, Si-Jeong;Yi, Gwang-Yong;Shin, Jung-Ah
    • Safety and Health at Work
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    • v.3 no.2
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    • pp.130-139
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    • 2012
  • Objectives: The purpose of this study is to evaluate the tire manufacturing work environments extensively and to identify workers' exposure to hazardous substances in various work processes. Methods: Personal air sampling was conducted to measure polycyclic aromatic hydrocarbons, carbon disulfide, 1,3-butadiene, styrene, methyl isobutyl ketone, methylcyclohexane, formaldehyde, sulfur dioxide, and rubber fume in tire manufacturing plants using the National Institute for Occupational Safety Health Manual of Analytical Methods. Noise, carbon monoxide, and heat stress exposure were evaluated using direct reading instruments. Past concentrations of rubber fume were assessed using regression analysis of total particulate data from 2003 to 2007, after identifying the correlation between the concentration of total particulate and rubber fume. Results: Workers were exposed to rubber fume that exceeded 0.6 mg/$m^3$, the maximum exposure limit of the UK, in curing and production management processes. Forty-seven percent of workers were exposed to noise levels exceeding 85 dBA. Workers in the production management process were exposed to $28.1^{\circ}C$ (wet bulb globe temperature value, WBGT value) even when the outdoor atmosphere was $2.7^{\circ}C$ (WBGT value). Exposures to other substances were below the limit of detection or under a tenth of the threshold limit values given by the American Conference of Governmental Industrial Hygienists. Conclusion: To better classify exposure groups and to improve work environments, examining closely at rubber fume components and temperature as risk indicators in tire manufacturing is recommended.

Comparison of Volatile Flavor Compounds in Commercial Crab-like Flavorants by Analyzing Methods (분석방법에 따른 시판 게향료의 휘발성 향기성분 비교)

  • Cha, Yong-Jun;Cho, Woo-Jin;Jeong, Eun-Jeong
    • Journal of Life Science
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    • v.16 no.7 s.80
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    • pp.1243-1249
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    • 2006
  • Volatile flavor compounds in commercial crab-like flavorants were compared by mean of solid phase microextraction(SPME) and liquid continuous extraction (LLCE)/GC/MSD methods. A total of 86 volatile flavor compounds were detected. Of these, 71 were positively identified consisting mainly of sulfur-containing compounds (13), aldehydes (3), ketones (2), esters (26), alcohols (5), aromatic compounds (3), terpenes (8), acids (2) and miscellaneous compounds (9). SPME method was more effective than LLCE method in detection of volatile components in commercial crab-like flavorants. Eight S-, N-containing compounds such as dimethyl sulfide, dimethyl disulfide, dipropyl disulfide, 3-(methylthio)propyl acetate, 3-(methylthio) propanal, 3-(methylthio) propanol, 2-methyl-3-(methylthio) pyrazine and 2-methyl-5-(methylthio) pyrazine, 8 esters such as styrallyl acetate, ethyl acetate, isoamyl acetate, benzyl acetate, ethyl pentanoate, butyl pentanoate, isoamyl pentanoate and furfuryl acetate were considered as major components in crab-like flavorants.