• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.220-222
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• 2008

가스하이드레이트는 물분자들의 수소결합에 의하여 입체 그물구조를 만들게 되면 그 그물구조의 공동(Cavity) 내에 크기가 작은 가스 분자들이 포획되면서 형성되는 결정체이다. 이러한 원리로 포획되어질 수 있는 가스는 130여종에 이른다. 포획가능한 가스 분자들 중 $SF_6$의 경우 보다 쉬운 조건에서 하이드레이트 형성이 되는 점을 이용하여 $SF_6$의 분리 회수에 하이드레이트의 형성 원리를 적용하고자 하였다. 이를 위하여 본 연구에서는 압력조건과 조성변화를 달리하여 $SF_6$ 하이드레이트 형성 특성을 관찰하였다. 본 연구에서 하이드레이트 결정 형성 특성 및 형성 속도에 대한 실험과 분석을 통한 결과를 확보함으로써 향후 $SF_6$ 하이드레이트의 생산, 저장, 회수, 분리 등의 설계의 기본자료로 사용될 수 있을 것으로 사료된다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2007년도 춘계학술대회 논문집
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• pp.167-168
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• 2007

• 한국결정성장학회지
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• 제20권2호
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• pp.85-92
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• 2010

$SF_6$ 가스는 아크방지능력과 절연 특성이 탁월하기 때문에 단열, 세척, 차폐등과 같은 여러 공업적인 영역에서 널리 사용되고 있다. 그러나 $SF_6$의 지구온난화지수는 $CO_2$의 23,900배에 달하며 3,200년 이상 공기중에 잔존한다. 이러한 이유로 하이드레이트 형성 원리를 이용하여 복합 가스에서 $SF_6$를 분리해 내는 방법이 기술적, 경제적인 면에 영향을 끼칠 것이다. 본 연구에서 $SF_6$ 하이드레이트 결정의 형성과 성장에 대한 이해를 위하여 형태학적 분석을 수행하였다. $SF_6$ 하이드레이트 필름은 용액과 기상의 계면에서 먼저 생성되었고, 이후에 수지상 가지의 형태로 성장하는 것이 관찰 되었다. 수지상 성장 결정은 기상의 방향으로 성장하였는데 이것은 객체 분자의 농도 차이에 근거한 것으로 사료된다. 본 연구에서는 기/액 계면에서의 핵생성, 유동, 성장과 같은 $SF_6$ 하이드레이트 결정의 형태학적 특성에 대하여 기술하였다.

• KEPCO Journal on Electric Power and Energy
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• 제8권2호
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• pp.111-118
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• 2022

SF₆ is used as an insulating gas because of its excellent electrical insulation properties, non-toxicity, and non-inflammability. On the other hand, the global warming potential of SF₆ is 23,900 times higher than that of CO₂. The Korea electric power cooperation (KEPCO) is responsible for 80% of the domestic SF₆ usage, and approximately 6,000 tons are currently charged in electrical and power facilities. KEPCO will gradually replace the insulating gas with SF₆-free gas from 2023. SF₆ decomposition facilities are required because more than 60 tons of SF₆ will need to be disposed of annually from existing equipment. This study developed a novel decomposition and pollution control system that can process 60 tons of SF₆ per year. This facility can decompose more than 97.7% of SF₆, with the emissions of hazardous and toxic materials below the legal limit.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2011년도 제42회 하계학술대회
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• pp.1262-1263
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• 2011

Sulfur hexafluoride is the most commly used insulation gas in electrical systems. Gas insulated systems are widely used in the electric power industry for transmission and distribution of electrical energy. When $SF_6$ was first discovered, the potential application was only considered for insulation because of good dielectric properties. But the widespread use of $SF_6$ gas by electric power and other industries has led to increase concentrations of $SF_6$ gas in the atmosphere. This concern as to possible effects on global warming because $SF_6$ is a potent greenhouse gas. That's why firstly we studied uniform and nonuniform field property by mixing $SF_6$ and N2 gas. This paper presents the dielectric strength and insulating property for particle contamination under $SF_6/N_2$ mixtures. Two types of mixed gases(50% $SF_6$_50%$N_2$, 20% $SF_6$_80%$N_2$) were applied. We performed tests for the length and shape of particle. Test gas pressure is from 0.3 to 0.7 Mpa. The study was conducted to develop environment-friendly insulating material for GIS that can reduce $SF_6$ gas and make a design criteria for mixtures.

• 전기학회논문지
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• 제57권4호
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• pp.635-640
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• 2008

New gas mixtures are now finding applications such as interrupting media for high-voltage circuit breakers. These mixtures consist of a high content of carbon tetrafluoride($CF_4$) added to sulfur hexafluoride($SF_6$). Nowdays $SF_6$ has been established for the use in gas insulated substations due to its high insulation withstand level and good arc quenching capability. At this paper Breakdown characteristics were investigated for $SF_6/CF_4$ mixtures when AC voltage and standard lightning impulse voltage(LI) was applied in a needle-plane electrodes. And partial discharge(PD) experiments were carried out in the test chamber which was made in needle-plane electrode. And ${\Phi}$-Q-N distribution of partial discharge signals was analyzed. The total pressure of the $SF_6/CF_4$ mixtures was varied within the range of 0.1-0.5 Mpa in the test chamber. The breakdown voltage in needle-plane electrode displayed N shape characteristics for increasing the content of $SF_6$ at positive impulse voltage and the PD inception voltage was increased slightly when pressure of $SF_6/CF_4$ Mixtures was increased. Maximum PD inception voltage is showed in 80% SF6/20%$CF_4$.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.73-76
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• 2003

SF$_{6}$ (Sulfur Hexafluoride) is a gaseous compound whose use is being greatly increased recently. The compound has a negligible background concentration from natural sources and is stable in most of groundwater environments. Therefore, SF$_{6}$ has potential for a dating tool for young groundwater. It has many advantages over chlorofluorocarbons (CFCs) for groundwater investigation that sampling procedure is much simpler than CFCs and its growth is continued up to at least near future in the atmosphere. However, solubility of SF$^{6}$ is so low that excess air causes large uncertainties in recharge date of groundwater. To compensate the limitation, $N_2$/Ar method can be employed to estimate excess air content. A groundwater study is currently carrying out in Jeju Island using SF$_{6}$ as an environmental tracer, Well waters and spring waters were sampled for SF$_{6}$ and $N_2$/Ar. To establish SF$_{6}$ input history in the study area, air sampling is being conducted in the area near the center of the island on a monthly and weekly basis. Based on the present data, the level of SF$_{6}$ concentration in the atmosphere of the Island is corresponding to the trend of the Northern Hemisphere.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.223-225
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• 2008

하이드레이트는 저온.고압에서 저분자량의 게스트(guest)가 호스트(host)인 물분자 속에 포획되어 만들어지는데 일련의 과정은 물리적 반응을 통해 생성된다.본 연구에서는$CO_2$보다 지구온난화지수(Global Warming Potential)가 23,900배 높은 $SF_6$의 회수 및 정제기술로써 하이드레이트화를 이용하는 신기술 개발의 일환으로 분광학적 접근을 통해 $SF_6$ 혼합 하이드레이트의 정성 및 정량분석을 수행하였다. Raman Shift 분석 결과 $SF_6$의 $770cm^{-1}$에서 $v_1$ 진동주파수를 확인함으로써 하이드레이트 내 $SF_6$가 안정적으로 포집됨을 확인하였고 혼합가스 내 $SF_6$ 농도별로 만들어진 샘플의 Raman Shift를 통해서 $SF_6$의 하이드레이트 전환율을 가늠할 수 있었다.

• Tribology and Lubricants
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• 제20권5호
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• pp.231-236
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• 2004

Sulfur Hexafluoride, S $F_{6}$ is widely used for leak detection and as a gaseous dielectric in transformers, condensers and circuit breakers. S $F_{6}$ gas is also effective as a cleanser in the semiconductor industry. This paper presents a numerical study of the sealing force of disk type seal in S $F_{6}$ gas safety valve. The sealing force on the disk seal is analyzed by the FEM method based on the Taguch's experimental design technique. Disk seals in S $F_{6}$ gas safety valve are designed with 9 design models based on 3 different contact length, compressive ratio and gas pressure. The calculated results of Cauchy stress and strain showed that the sealing characteristics of Teflon $^{ }$PTFE is more effective compared to that of FKM(Viton), which is related to the stiffness of the materials. And also, the contact length of the disk seal is important design parameter for sealing the S $F_{6}$ gas leakage in the safety valve.afety valve.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2004년도 학술대회지
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• pp.237-240
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• 2004

Sulfur Hexafluoride, SF6 is widely used for leak detection and as a gaseous dielectric in transformers, condensers and circuit breakers. SF6 gas is also effective as a cleanser in the semiconductor industry. This paper presents a numerical study of the sealing force of disk type seal in SF6 gas safety valve. The sealing force on the disk seal is analyzed by the FEM method based on the Taguch's experimental design technique. Disk seals in SF6 gas safety valve are designed with 9 design models based on 3 different contact length, compressive ratio and gas pressure. The calculated results of Cauchy stress and strain showed that the sealing characteristics of Teflon PTFE is more effective compared to that of FKM(Viton), which is related to the stiffness of the materials. And also, the contact length of the disk seal is important design parameter for sealing the SF6 gas leakage in the safety valve.