• Title/Summary/Keyword: Sulfur Dioxide

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Studies on the Behaviour of Ozone Concentration and the Influencing Factors (오존농도의 動態 및 影響因子에 關한 硏究)

  • 金旻永;姜熙坤;李完宗;李相七;張鳳勳;朴聖培
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.55-71
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    • 1989
  • This study was carried out to determine the ozone concentration to behaviour and the factors to be influenced the variation of its concentration in the ambient air in Seoul. Measurements of ozone concentrations were made at 10 monitoring station to take care of SIHE (Seoul Institute of Health & Environment) during December 1987 to November 1988, also measured the hourly average concentration of sulfur dioxide, total suspended particulate, nitrogen oxide $(NO & NO_2)$, carbon monoxide, hydro carbon $(n-CH_4 & THC)$ and meteorological factors, that is, temperature, humidity, wind velocity wind direction and ultraviolet intensity etc, for the same period at same place. The basis of the data obtained were analyzed statistically along with the various data. The results were as follows; 1. The annually arithmetic mean concentration of ozone for the 10 sites during one years was 10.0 ppb and ranged from 3.1 $\pm$ 4.5ppb at the Kuro industrial complex to 17.2 $\pm$ 18.7 ppb at the Ssangmun site. 2. The frequency of hours on which oxidant concentrations exceeded the present short term standard of ozone (100 ppb) were 78 times. 3. The diurnal patterns of hourly ozone concentrations in Seoul area was a typical bi-modal variation which have 4 to 5 a.m. peak and 3. to 4 p.m peak. 4. The time ozone of highest ozone concentration in a whole day and hight was 1 to 5 p.m and 90.9 percent of appearence rate. 5. The diurnal patterns of hourly ozone concentrations in Seoul were on the whole the order of daytime from 5.8ppb to 28.7 ppb evening from 1.7 to 18.7 ppb night time from 1.9 to 9.3 ppb daybreak from 1.4ppb according to measuring sites, and the highest that observed at the Ssangmun area while the lowest was the Kuro industrial complex monitor sites. 6. The weekly variation of ozone concentration was the higher level ozone concentration in the day of the week occured sunday-monday and weekend but the decrease were observed from wednesday to thursday.

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A Time-Series Study of Ambient Air Pollution in Relation to Daily Mortality Count in Yeosu (여수시의 대기오염과 일별 사망의 상관성에 관한 연구 - 미세먼지와 이산화황을 대상으로 -)

  • Park, Hee-Jin;Woo, Kyung-Sook;Chung, Eun-Kyung;Kang, Tack-Shin;Kim, Geun-Bae;Yu, Seung-Do;Son, Bu-Soon
    • Journal of Environmental Impact Assessment
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    • v.24 no.1
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    • pp.66-77
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    • 2015
  • The association between daily total/cardiovascular mortality and air pollution in Yeosu was investigated over 11-year period (January 2001 to December 2011). The purpose of this study was to evaluate th relative importance of the major air pollutants [particulate matter ($PM_{10}$), sulfur dioxide ($SO_2$)] as predictors of daily total/cardiovascular mortality. People aged 65 and older showed total mortality increase by 5.0% with $SO_2$ concentration increase by 11.67ppb(IQR) was found to raise mortality caused by circulatory diseases by 8.6%, exhibiting a statistically significant result.

Antimicrobial Treatment of Grapes Using Sodium Hypochlorite in Winemaking and Its Effects on the Chemical and Sensory Characteristics of Wines

  • Yoo, Ki-Seon;Ahn, Ji-Eun;Han, Jin-Soo;Seo, Eun-Young;Otgonbayar, Gan-Erdene;Han, Nam-Soo
    • Journal of Microbiology and Biotechnology
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    • v.21 no.12
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    • pp.1243-1249
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    • 2011
  • This study was performed to examine the use of NaOCl as an alternative antimicrobial compound in winemaking because of the potential health problems that may arise as a result of the use of $SO_2$. For this, the blank (non-treated), control ($SO_2$-added), and sample (NaOCl-treated) wines were made, and microbial and chemical changes including sensory characteristics were analyzed during the fermentation periods. Treatment of grapes with NaOCl decreased the initial contaminating microbial population in grape must, resulting in higher growth of yeast and lactic acid bacteria. After 200 days of fermentation, the chemical analysis of sample wine revealed that it had higher ethanol content, redness ($a^*$), and concentrations of fruity ester compounds and lower total acidity than the control. In the sensory analyses, the sample wine obtained a higher overall acceptability score (5.70) than the control (4.26). This result reveals that NaOCl can be used as an alternative to $SO_2$ in winemaking for inhibiting the growth of contaminating microorganisms.

A Toxicity Evaluation for the Toxic Gases of Building Finish Materials (건축물 마감재료 연소가스에 의한 독성평가)

  • Cho, Nam-Wook;Cho, Dong-Ho;Oh, Eun-Ha
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.129-140
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    • 2012
  • Smoke toxicity is the test for the toxicity evaluation of smoke and hazardous gas, caused by combustion of building materials and finishing materials. Smoke toxicity can be evaluated by the mean incapacitation time of mice. This test result can be influenced by the health status of mice and test condition. In acute inhalation toxicity test of hazardous gas, no typical clinical findings and histopathologic abnormalities were observed. Tracheitis and bronchitis as well as acute lung inflammation around terminal bronchiole in some mouse of the highest dose group. Through this study, we established the method for inhalation toxicity test of hazardous gas as well as the SOP of inhalation toxicity test. However, in the future studies, the concentration control methods for inhalation technologies on hazardous gas will be needed to improve continuously and also further studies on other gas inhalation toxicity will be needed to conduct.

Air Pollutants Control Technique Trends for Transportation Sources in Korea (우리나라 이동오염원의 제어기술의 동향과 발전방안)

  • Kim, Jeong-Soo;Eom, Myung-Do
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.4
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    • pp.477-485
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    • 2013
  • The major source of harmful air pollutants in Korea have been shifted as economy grows. Particulate matter(PM) and Sulfur dioxide ($SO_2$) emitted from industries and coal-fired domestic sectors were important pollutants in 1970's and later industrializing period of Korea. Then the characteristic of pollution was changed into so-called "developed country type pollution". Vehicles have been responsible for significant amount of Nitric oxide ($NO_x$) pollution and consequent Ozone formation in urban area since 1990's. Variety of control measures have been introduced to deal with the vehicle emissions in Seoul Metropolitan Area (SMA). Emission control technologies have successfully reduced pollutants from vehicles. Three-way catalyst for vehicles fueled by gasoline and liquefied petroleum gas (LPG), for example, has achieved large amount of pollutants. Compressed natural gas (CNG) urban bus have penetrated existing diesel bus market and reduces PM and $NO_x$ emissions in many Korean cities. However, diesel vehicles are still reaming as a critical emission source of urban area. Diesel vehicles gain more popularity than ever because of their better fuel efficiency and driving power. Unfortunately, it is widely known that the pollutant emissions of diesel vehicles are much larger than those of gasoline and LPG vehicles. In this note, we briefly introduce the trends of emission control strategies which are accomplished by automotive industries for about last ten years. Emission regulation, cleaner fuel, diesel particulate filter (DPF) and other measures are discussed from technical as well as legislative perspectives.

Environmental Policy Comparison under Various Potential Forms of Health Response Function (건강반응함수를 고려한 환경정책의 비교)

  • Hlasny, Vladimir
    • Environmental and Resource Economics Review
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    • v.19 no.4
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    • pp.915-961
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    • 2010
  • This study is concerned with health damages from $SO_2$ under different assumptions on the relationship between air concentrations and their marginal health impacts. $SO_2$ concentration profiles resulting under emission caps, and a system of tradable emission allowances are compared. Using slopes and curvatures of the health response function consistent with evidence in medical literature, emission caps are shown to lead to lower aggregate damages under all considered parameters, an advantage of $26~452 million. The benefit of emission caps over tradable allowances increases with the curvature of the response function, but falls with its slope. The advantage of emission caps in terms of environmental damages is never overturned completely for the considered functional forms. The marginal damage function would have to be steeper than what the current medical evidence suggests for price instruments to outperform emission caps in terms of aggregate damages. With other welfare consequences included-emission abatement costs, consumer and producer surpluses, and government revenue-emission caps always lead to a $3.7~4.1 billion greater measure of social welfare.

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The Improvement of Corn Starch Isolation Process by Gamma Irradiation (옥수수 전분추출 공정개선을 위한 감마선 이용)

  • Byun, Myung-Woo;Kang, Il-Jun;Kwon, Joong-Ho;Lee, Soo-Jeong;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.27 no.1
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    • pp.30-35
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    • 1995
  • Gamma irradiation was applied to non-glutinous and glutinous corns for improving starch isolation process. No significant changes in proximate composition of corn grains were observed by gamma irradiation. Irradiation at 1 and 5 kGy was effective for sterilizing all contaminated microorganisms of non-glutinous and glutinous corns, respectively. The moisture-uptake rate constants were increased in proportional to the steeping temperature and applied irradiation dose level. The irradiation efficacy on water absorption properties was also recognized in the corns stored for six months at room temperature. The combined use of gamma irradiation with sulfur dioxide solution was very effective for reducing steeping time. The starch yield gradually increased as irradiation dose levels increased. At 2 kGy, the sarch yield of non-glutinous and glutinous corns increased by 38% and 27%, respectively. No significant difference in Hunter's color value was observed between the starches isolated from nonirradiated and irradiated corn grains.

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Effects of Sulfuric Acid Concentration and Alloying Elements on the Corrosion Resistance of Cu-bearing low Alloy Steels

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.154-165
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    • 2018
  • During the process of sulfur dioxide removal, flue gas desulfurization equipment provides a serious internal corrosion environment in creating sulfuric acid dew point corrosion. Therefore, the utilities must use the excellent corrosion resistance of steel desulfurization facilities in the atmosphere. Until now, the trend in developing anti-sulfuric acid steels was essentially the addition of Cu, in order to improve the corrosion resistance. The experimental alloy used in this study is Fe-0.03C-1.0Mn-0.3Si-0.15Ni-0.31Cu alloys to which Ru, Zn and Ta were added. In order to investigate the effect of $H_2SO_4$ concentration and the alloying elements, chemical and electrochemical corrosion tests were performed. In a low concentration of $H_2SO_4$ solution, the major factor affecting the corrosion rate of low alloy steels was the exchange current density for $H^+/H_2$ reaction, while in a high concentration of $H_2SO_4$ solution, the major factors were the thin and dense passive film and resulting passivation behavior. The alloying elements reducing the exchange current density in low concentration of $H_2SO_4$, and the alloying elements decreasing the passive current density in high concentration of $H_2SO_4$, together play an important role in determining the corrosion rate of Cu-bearing low alloy steels in a wide range of $H_2SO_4$ solution.

Work Environments and Exposure to Hazardous Substances in Korean Tire Manufacturing

  • Lee, Na-Roo;Lee, Byung-Kyu;Jeong, Si-Jeong;Yi, Gwang-Yong;Shin, Jung-Ah
    • Safety and Health at Work
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    • v.3 no.2
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    • pp.130-139
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    • 2012
  • Objectives: The purpose of this study is to evaluate the tire manufacturing work environments extensively and to identify workers' exposure to hazardous substances in various work processes. Methods: Personal air sampling was conducted to measure polycyclic aromatic hydrocarbons, carbon disulfide, 1,3-butadiene, styrene, methyl isobutyl ketone, methylcyclohexane, formaldehyde, sulfur dioxide, and rubber fume in tire manufacturing plants using the National Institute for Occupational Safety Health Manual of Analytical Methods. Noise, carbon monoxide, and heat stress exposure were evaluated using direct reading instruments. Past concentrations of rubber fume were assessed using regression analysis of total particulate data from 2003 to 2007, after identifying the correlation between the concentration of total particulate and rubber fume. Results: Workers were exposed to rubber fume that exceeded 0.6 mg/$m^3$, the maximum exposure limit of the UK, in curing and production management processes. Forty-seven percent of workers were exposed to noise levels exceeding 85 dBA. Workers in the production management process were exposed to $28.1^{\circ}C$ (wet bulb globe temperature value, WBGT value) even when the outdoor atmosphere was $2.7^{\circ}C$ (WBGT value). Exposures to other substances were below the limit of detection or under a tenth of the threshold limit values given by the American Conference of Governmental Industrial Hygienists. Conclusion: To better classify exposure groups and to improve work environments, examining closely at rubber fume components and temperature as risk indicators in tire manufacturing is recommended.

Reaction of Natural Manganese Dioxide with Hydrogen Sulfide at High-Temperature (고온에서 천연산 망간광석과 황화수소의 반응특성)

  • Shon, Byung-Hyun;Oh, Kwang-Joong;Kim, Young-Sick
    • Clean Technology
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    • v.2 no.1
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    • pp.69-79
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    • 1996
  • Sulfur emission control in coal gasification plants implies the removal of $H_2S$ from the fuel gas in the gas clean-up system. In this study, the effects of particle size of sorbents, temperature of sulfidation and sorbent characteristics on the $H_2S$ removal efficiency of manganese ore were investigated. Experimental results showed that the removal efficiency of $H_2S$ was optimum when the temperature was about $700^{\circ}C$. And that the smaller particle size, the higher the $H_2S$ removal efficiency, but that was not effective very much. As the temperature increases, the reactivity of sorbents has lowered because agglomeration of sorbents increased the intraparticle transport resistance. This phenomenon was confirmed by SEM photographs. The equilibrium ratio ($P_{H_2O}/P_{H_2S}$) obtained by experiments is represented as a ${\log}(P_{H_2O}/P_{H_2S})=5653/T-3.7909$. It was showed that the natural manganese ore could be used as a sorbent because its capacity for $H_2S$ removal is equivalent to the eariler developed sorbents.

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