• Title/Summary/Keyword: Sulfur Dioxide

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Implementation of Differential Absorption LIDAR (DIAL) for Molecular Iodine Measurements Using Injection-Seeded Laser

  • Choi, Sungchul;Baik, Sunghoon;Park, Seungkyu;Park, Nakgyu;Kim, Dukhyeon
    • Journal of the Optical Society of Korea
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    • v.16 no.4
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    • pp.325-330
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    • 2012
  • Differential absorption LIDAR (DIAL) is frequently used for atmospheric gas monitoring to detect impurities such as nitrogen dioxide, sulfur dioxide, iodine, and ozone. However, large differences in the on- and off-line laser wavelengths can cause serious errors owing to differential aerosol scattering. To resolve this problem, we have developed a new DIAL system for iodine vapor measurements in particular. The suggested DIAL system uses only one laser under seeded and unseeded conditions. To check the detection-sensitivity and error effects, we compared the results from a system using two seeded lasers with those from a system using a seeded and an unseeded laser. We demonstrate that the iodine concentration sensitivity of our system is improved in comparison to the conventional two seeded or two unseeded laser combinations.

Study on Accelerated Aging Characteristics of Paper-Records by Air Pollutants (종이 기록물의 대기 중 유해물질에 의한 가속 열화 특성 연구)

  • Park, Mi-Seon;Jeong, So-Yoon;Hwang, Ji-Hyun;Kim, Hyoung-Jin;Kim, Shin-Do
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.76-84
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    • 2014
  • Preventive conservation is one of most important issues in the field of conservation for paper-records. Many researchers have been studied environmental factors such as effects of humidity, temperature, biological attack and air pollutants. Air pollutants strongly associated with oxidative and hydrolytic degradation of cellulose. It is important to control air pollutants in storage environment to improve stabilities of conservation environment. Four paper samples have been analyzed for their accelerated aging characteristics by air pollutants, sulfur dioxide, nitrogen dioxide, ozone, carbon monoxide. Physical and optical properties and weight molar masses(Mw) showed that interactions between air pollutants and paper sample. Nitrogen dioxide, ozone caused severe damage to cellulose in paper by hydrolytic and oxidative decompositions during aging.

Impact of High Temperature on the Maillard Reaction between Ribose and Cysteine in Supercritical Carbon Dioxide

  • Xu, Honggao;He, Wenhao;Liu, Xuan;Gao, Yanxiang
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.66-72
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    • 2009
  • An aqueous ribose-cysteine model system (initial pH 5.6) was conventionally heated to the same browning at varying temperatures ($120-180^{\circ}C$), supercritical carbon dioxide (SC-$CO_2$, 20 MPa) was also applied on the same matrices for same periods at each temperature and about 20% reduction of the absorbance at 420 nm was observed as compared with sole thermal treatment. The headspace volatiles from Maillard reaction mixtures were analyzed by solid-phase microextraction (SPME) in combination with gas chromatography and mass spectrometry (GC-MS), and predominated with sulfur containing compounds, such as thienothiophenes, polysulfur alicyclics, thiols, and disulfides. Reaction temperature exhibited complex effects on volatiles formation and those effects became further complicated by the SC-$CO_2$ treatment. The formation of noncarbonyl polysulfur heterocyclic compounds and thienothiophenes was generally favored at high temperatures. Most volatiles were inhibited in SC-$CO_2$ as compared with thermal treatment alone, however, the well-known meaty aromatic compounds, such as thiols and disulfides, were obviously enhanced.

INTEGRATED LIFE-CYCLE COST ANALYSIS CONSIDERING ENVIRONMENTAL COSTS: A HIGHWAY PROJECT CASE

  • Woo-Sik Jang;Heedae Park;Sungmin Kim;Seung Heon Han;Jong Seo Jeon
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.273-279
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    • 2011
  • Concerns over the environment have spawned a number of research studies in the construction industry, as the construction of built environments and large infrastructures involves diverse environmental impacts and loads of hazardous emissions. Many researchers have attempted to quantify these environmental loads, including greenhouse gases, carbon dioxide, nitrogen dioxide, and sulfur dioxide, to name a few. However, little research has been conducted regarding integrating the life-cycle assessment (LCA) of environmental loads with the current life-cycle cost analysis (LCCA) approach. This study aims to estimate the environmental loads as a monetary value using the European Climate Exchange (ECX) rate and, then, to integrate those impacts with the pure construction cost. Toward this end, this study suggests an integrated approach that takes into account the environmental effect on the evaluation of the life-cycle cost (LCC). The bill of quantity (BOQ) data of a real highway project are collected and analyzed for this purpose. As a result, considering the environmental loads in the pavement process, the total LCC increased 16% from the traditional LCC cost. This study suggests an integrated approach that will account the environmental effect on the LCC. Additionally, this study is expected to contribute to better decision-making, from the perspective of more sustainable development, for government as well as for contractors.

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The Study on Foam Formation in Waterslag-Bentonite System (수광재와 백토조합물에서의 기포형성에 관한 연구)

  • 김종희;송한식
    • Journal of the Korean Ceramic Society
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    • v.14 no.4
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    • pp.248-255
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    • 1977
  • The effect of firing temperature, soaking time and batch composition upon the glass phase and pore formation as well as their distribution in slag foamed glass was investigated. Sulfur dioxide gas produced by the oxidation and reduction of metal sulfide in waterslag was attributed to foam forming agent. Slag foamed glass matrix was mainly composed of 35~60% glas phase and melilite crystalline phase. The increment of bentonite addition in batch lowered the foam forming temperature in studied system. The result showed also that the foam size distribution was broadened as th firing temperature wa inbereased.

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Adsorption and Oxidation Reaction Rate of $SO_2$ in Slurries of Activated Carbon (활성탄 슬러리를 이용한 $SO_2$ 가스의 흡착 및 산화반응 속도)

  • 최용택;신창섭;이태희
    • Journal of Korean Society for Atmospheric Environment
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    • v.3 no.1
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    • pp.41-46
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    • 1987
  • Adsorption and reaction studies were made for the catalytic oxidation in aqueous slurries of activated carbon at room temperature and atmospheric pressure. In order to analyze the reaction rate, the mechanism was assumed by the steps of nonhomogeneous catalytic reaction. The experimental result show that oxidation rate was controlled by the reaction between adsorbed molecular oxygen and sulfur dioxide on the catalyst surface. Ar room temperature, the equat5ion of reaction rate was given as $ro_2 = 2.49 \times 10^{-7} P_O_2^{0.604}$.

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Monitoring of Residual Sulfur Dioxide in Herbal Medicines

  • Kim, Mi-Kyeong;Hur, Moon-Hye;Jin, Jong-Seong;Shin, Myoung-Hee;Jin, Sun-Kyung;Doh, Hea-Jeong;Sin, Yeong-Min;Kim, Jae-I;Lee, Chang-Hee;Leem, Dong-Gil;Lee, Young-Ja;Choi, Soo-Young
    • Proceedings of the Korean Society of Food Hygiene and Safety Conference
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    • 2004.05a
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    • pp.229-229
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    • 2004
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Abrief study on the corrosion of bronze roofing tile (납(Pb)도금(동개와)의 부식 연구)

  • Kim, Sa-Dug
    • 보존과학연구
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    • s.15
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    • pp.52-58
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    • 1994
  • To protect corrosion of bronze roofing tile for Choson Royal Historic Museum, lead coating on tile was performed by electroplating method with thickness of $35\mum$. Lead coated tile samples were inverstigated what corrosion products were formed with color changes on them by testing Accelerated Weathering. No sulfides were formed on samples contacting with 300ppm sulfur dioxide and any color changes were not found. In Accelerated Weathering test, White hydrocerussite, basic lead carbonate($2PbCO_3Pb(OH)_2$) having protective structure made of compact adhering crystals.

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Growth Responses of Lettuce Seeds Germinated in Aqueous Solutions of Sulfur Dioxide (아황산 수용액에서 발아시킨 상치 종자의 생장반응)

  • 이미순
    • Journal of Plant Biology
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    • v.18 no.4
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    • pp.155-160
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    • 1975
  • Growth responses of lettuce seeds germinated in aqueous solutions of $SO_2$ were investigated for mode of action studies of this gas. The concentration and pH of $SO_2$ solution greatly affected the growth of germinating seeds. Root growth was more sensitive to $SO_2$ than hypocotyl growth. The sensitivity of total seedling growth lay between root and hypocotyl growth. Growth inhibition of germinating seeds appeared more serioius when $SO_2$ was added during the early stage of germination.

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Effect of Aeration Rates on Emissions of Oxygen and Sulfur compound gases during Composting of Dairy Manure (우분(牛糞) 퇴비화시(堆肥花時) 공기주입률(空氣注入率)이 산소 및 황화합물 가스 배출(排出)에 미치는 영향(影響))

  • Kang, Hang-Won;Zhang, Ruihong;Rhee, In-Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.472-481
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    • 2000
  • This experiment used the enclosed bench-scale reactors was conducted to find out optimal aeration rate for reducing the emission of odors and producing the good-quality compost with the mixture of dairy manure and rice straw. The reactors with gas sampler were aerated at four different rates of 0.09, 0.18, 0.90 and $1.79l\;min^{-1}kg^{-1}$dry solids for 574 hours. The oxygen content within composting pile instantly decreased after aeration. Oxygen limitation(below 15%) in the treatments of $0.90l\;min^{-1}kg^{-1}$ and less was exponentially negative relationship with aeration rates and in the range of 35 to 300 hours after aeration. However, the treatment of $1.79l\;min^{-1}kg^{-1}$ didn't show the oxygen limitation. The oxygen consumption rate and the cumulative amount of oxygen consumed by different aeration rates was ranged in $0.80{\sim}1.57O_2g\;h^{-1}\;kg^{-1}VS^{-1}$, $460{\sim}900O_2g\;kg^{-1}VS^{-1}$, respectively, and they were high in the order of 0.90, 1.79, 0.18, $0.09l\;min^{-1}kg^{-1}$. The maximum oxygen consumption rate was estimated in the range of $1.2{\sim}1.3lmin^{-1}kg^{-1}$. The emission concentrations of sulfur compounds such as hydrogen sulfide, sulfur dioxide and methylmercaptan were remarkably high in the initial composting time. Then they were rapidly decreased with the passing of composting time and clearly with increasing aeration rates. Their average concentrations were in the range of 0.03~2.18, 0~0.50, $0.07{\sim}3.38mg\;kg^{-1}$, respectively and high in the order of methylmercaptan, hydrogen sulfide, and sulfur dioxide. Concentrations of sulfur compounds emitted from composting showed exponentially negative relationship at 1% statistically with the oxygen concentration. It was estimated that hydrogen sulfide and methylmercaptan suddenly increased in the level of 5% oxygen concentration and below, that they were little emitted in 15% and over but sulfur dioxide was emitted in the level of 20% oxygen.

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