• Title/Summary/Keyword: Sulfur Dioxide

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Effect of of Sulfur dioxide gas on Soybean Plant (대두(大豆)에 대(對)한 아황산가스의 영향(影響))

  • Kim, B.Y.;Han, K.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.2
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    • pp.105-112
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    • 1979
  • A study was carried out to examine the effects of sulfur dioxide gas on soybean plants; at two concentrations(0.2mg/l and 0.5mg/l) and in different fumigation periods, The grain yield of soybeans, sulfur and chlorophyll contents in leaves, and ratios of destroyed leaf were investigated, 1) At the concentration of $SO_2$ 0.5mg/l, a) The yield decrease were 52% and 76.4% at 5 minutes and one houre fumigation period respectively, b) The sulfur contents in leaves were positively correlated with fumigation period and yield decrease, however the water soluble sulfur was superior than the total sulfur in correlation coefficient. 2) At the concentration of $SO_2$ 0.2mg/l; a) The most severe destruction of leaves were observed at noon exposure (10:00-11:00 O'clock) and no visible damage was observed at night exposure (22:00-23:00) b) The sulfur contents in leaves and stems were the highest at noon exposure and the lowest at evening exposure (18:00-19:00 O'clock) chlorophyll contents were the highest at night exposure but, the lowest at noon exposure, c) The ratio of destroyed leaf was positively correlated with the sulfur content of leaves, but negatively correlated with chlorophyll contents. d) Absorbance spectra of chlorophyll in the chlorolast were greatly decreased at noon exposure but slightly decreased at night exposure. The decrease of absorbance spectra was mainly at $456m{\mu}$ and $663m{\mu}$.

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Episodic Particulate Sulfate and Sulfur Dioxide on the Southwestern Japan Coast in March and April 2010

  • Nagatani, Tetsuji;Yamada, Maromu;Kojima, Tomoko;Zhang, Daizhou
    • Asian Journal of Atmospheric Environment
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    • v.6 no.1
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    • pp.41-52
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    • 2012
  • Particulate sulfate in $PM_{2.5}$, sulfur dioxide ($SO_2$) and size-segregated aerosol particle number concentrations were measured at a site ($32^{\circ}19'N$, $129^{\circ}59'E$) on the southwestern Japan coast from 5 March to 10 April, 2010. Results show frequent episodic increases of sulfate and $SO_2$. Compared to the average concentration of sulfate $4.4{\pm}2.7\;{\mu}g\;m^{-3}$ in the whole observation period, episodic sulfate reached $10.5-20.1\;{\mu}g\;m^{-3}$. The variation of sulfate always synchronized with aerosol particles in the size range of $0.1-0.5 {\mu}m$, indicating the episodic sulfate was a consequence of the increase of the sub-micron particles. $SO_2$ did not have remarkable increase in any episodes of sulfate increase. During the passage of low pressure systems which loaded Asian dust in postfrontal air, concentrated sulfate appeared right behind the front but before dust arrival, suggesting the dominance of dust-free particulate sulfate. Weather and backward trajectory analyses revealed that air parcels with high sulfate passed eastern and northeastern China or Korean peninsula before arriving at the site. In contrast, those with high $SO_2$ passed an active volcano, Mt. Sakurajima, about 100 km in the south, suggesting the $SO_2$ was more likely from the volcanic emission. The ratio of sulfate to total sulfur compounds $({SO_4}^{2-})/({SO_4}^{2-}+SO_2)$ was 0.31-0.89 in continentally originated air while was 0.25-0.43 in the air having passed the volcano, showing more efficient conversions of $SO_2$ to sulfate in the air from the continent. The close dependence of the conversion on humidity in the continentally originated air was confirmed.

MONNTORING AIR QUALITY AND ACIDDEPOSITION IN SOUTHERN U.S.

  • Allen, Eric R.
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1997.10a
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    • pp.1.1-32
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    • 1997
  • Atmospheric monitoring capabilities were established in 1988 by the University of Florida at Duke forest, near Durham. NC: Cary forest, near Gainesville, FL: and Austin forest, near Nacogdoches, TX. Continuous (hourly averaged) measurements of air quality (ozone, nitrogen oxides and sulfur dioxide) and meteorological variables were made at these three low elevation (< 200 meters), rural locations in the southeastern U.S. for more than three years. During the same period at these sites wet and dry acid deposition samples were collected and analyzed on an event and weekly basis, respectively The monitoring locations were selected to determine actual atmospheric exposure indices for southern pine species in support of on-site surrogate exposure chamber studies conducted by Southern Commercial Forest Research Cooperative (SCFRC) investigators. Daily and quarterly averaged ozone maxima were higher (55 ppb) at the northernmost site in the network (Duke forest) in the second and third quarters (spring and summer seasons) and lower (35 ppb) in the first and fourth quarters (winter and fall seasons), when compared to ozone levels at the two southernmost sites (Cary and Austin forests). Seasonal ozone levels at the latter two sites were similar Nitrogen oxieds and sulfur dioxide levels were insignificant (< 5 ppb) most of the time at all sites, although soil emissions of NO at two sites were found to influence nighttime ozone concentrations. Typical maximum quarterly and annual aggregate ozone exposure indices were significantly higher at Duke forest (92.5/259 ppm-hr) than those values observed at the two southern sites (65.6/210 ppm-hr). Acid deposition (wet and dry) components concentrations and deposition fluxes observed at the Duke forest, NC piedmont site, were generally greater, dependent on site and season, than corresponding variables measured at either of the two southern coastal plain sites (Cary and Austin forests). Acid deposition variables observed at the latter two sites were remarkably similar, both qualitatively and quantitatively, although the sites were located 1300 km apart. A comparison of deposition fluxes of elemental nitrogen (NO3, NH4') and sulfur (5042-, SO3) components in wet and dry forms indicated that wet deposition accounts for approximately 70% of the total nitrogen and 73% of the total sulfur input on an annual equivalent basis at all sites.

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Absorption of sulfur dioxide gas with various crops and it's relation to leaf injury (아황산가스에 의(依)한 작물별파해엽율(作物別破害葉率) 및 가스흡수량조사(吸收量調査))

  • Kim, B.Y.;Han, K.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.13 no.1
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    • pp.39-44
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    • 1980
  • To study the effects of sulfur dioxide on the plant; Barly, wheat, soybean sweet potato, cucumber, egg plant, red pepper, tomato, lettuce, water melon, castor bean, grape and lily were exposed to the different levels of sulfur dioxide gas(0.1, 0.25, 0.50, $1.0mg/{\ell}/hr$) The symptoms of damage, ratios of destroyed leaf, sulfur content and absorption amounts of the gas by leaves were investigated 1. According to the increasing concentration of the gas ratios of destroyed leaf were increased in all plants. The ratios of destroyed leaf were shown by egg plant at $0.1mg/{\ell}/hr$ of $SO_2$ were 30 percent, and no visible injuries were shown by the wheat potato, castor bean, water melon, lily at $0.25mg/{\ell}/hr$. 2. Gray and red brown spots between the vein nerve shown by barly and wheat leaf; leaf burn by soybean, potato, sweat potato, castor bean, egg plant, red pepper, tomato and grape; leaf withering from the leaf tips by the lettuce, water melon, lily. 3. The volums of the gas absorption by cucumber, egg plant, red peper, castor he an were more than $10{\ell}/hr$, however less than $2{\ell}/hr$, be lettuce, water melon, grape, barly and wheat. 4. According to the increasing concentration of sulfur dioxide gas, sulfur contents in leaf were increased in all plants, however volums of absorption gas were decreaed. 5. According to the increase of sulfur content in leaf, ratios of destroyed leaf were increased. 6. Positive correlation was shown between total and water soluble sulfur content in leaf.

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Emission factors based estimation of exhaust emissions with biodiesel blended fuel from naval vessel propulsive diesel engine (바이오디젤 혼합연료를 사용하는 함정추진디젤기관의 배출계수를 이용한 배기가스 배출량 예측)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.4
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    • pp.332-337
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    • 2013
  • National investment was performed in the research and development of renewable energy because of climate change by air pollution, exhaustion of energy sources, energy security, and so on. Biodiesel fuel of the renewable energy is highlighted as friendly environment energy, it is possible to operate in regular diesel engines when it is blended with invariable ratios without making any changes. Emission factors have been estimated for commercial ship from various research institutes; however, it is difficult to develop emission factors for military vessels. In this work, biodiesel blended fuel emission factors for sulfur dioxide and carbon dioxide were quantitatively estimated from propulsive diesel engine installed on naval vessel using fuel property analysis. In addition, exhaust emissions were quantitatively calculated on the basis of fuel consumption rate with biodiesel content by percentage.

Combustion Emission Gas Analysis & Hazard Assessment to the Litter Layer in Forest (임내 낙엽층의 연소 방출가스 분석 및 건강 위험성 평가)

  • Kim, Dong-Hyun;Lee, Myung-Bo
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.358-364
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    • 2009
  • 본 연구에서는 우리나라 주요 침엽수종인 소나무(Pinus densiflora)와 활엽수종인 굴참나무(Quercus variabilis)의 낙엽에 대해 FTIR(Fourier Transform Infrared) 분광계를 이용하여 배출 연소가스 종류 및 농도를 측정하였다. 실험결과 소나무와 굴참나무 낙엽에서 Carbon monoxide, Carbon dioxide, Acetic acid, Butyl acetate, Ethylene, Methane, Methanol, Nitrogen dioxide, Ammonia, Hydrogen Fluoride, Sulfur dioxide, Hydrogen bromide 등 13개 연소가스가 검출되었고 굴참나무 낙엽에서는 Nitrogen monoxide가 추가로 검출되었다. 방출된 연소가스의 전체 농도는 소나무 낙엽이 굴참나무 낙엽에 비해 4.5배 많이 검출되었다. 특히, 시간가중평균가스농도(TWA : Time-weighted average, ppm) 기준을 초과하는 연소가스는 Carbon monoxide, Carbon dioxide, Butyl acetate가 검출되었고 단시간노출기준(STEL : Short Term Exposure Limit, ppm) 기준을 초과하는 연소가스는 Carbon monoxide, Carbon dioxide로 소나무 및 굴참나무 모두에서 나타났다. 이에 산불에서의 낙엽층 지표화 연소시 전체 가스 방출량의 99% 이상을 차지하고 있는 Carbon monoxide, Carbon dioxide의 건강 위험성이 높은 것으로 나타났다. 하지만, 검출된 다른 건강 위험성 가스의 경우에도 연소물질의 양이 증가할수록 연소가스의 농도가 높아져 건강안정성에 해가 있을 것으로 판단되며 또한 검출된 연소가스 중 나무의 주요구성 원소가 아닌 Bromide, Fluoride 화합물에 대해서는 토양으로부터의 오염 또는 분석과정에서의 노이즈로 인한 검출 등에 대한 보다 면밀한 검토가 필요할 것으로 판단된다.

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SO2 Concentrations and Health Damages under Alternative US-EPA Policies (US-EPA 정책하에서의 SO2 농도와 건강피해)

  • Hlasny, Vladimir
    • Environmental and Resource Economics Review
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    • v.18 no.3
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    • pp.393-430
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    • 2009
  • This study uses a computable partial-equilibrium model of the U.S. energy industry to evaluate sulfur dioxide concentrations under two environmental policies. The policies, generator-level emission caps and tradable allowances, are selected to yield identical aggregate emissions. Regional concentrations are found to vary across the two policies significantly. These variations translate into different losses for individual states, and, nationwide, to differences of hundreds of millions of dollars in aggregate health damages. Emission caps outperform allowances by $452 million. Caps favor the southwestern, south-central and southeastern states, where they deliver $840 million lower damages than the other policies, while they deliver $390 million higher damages In northern and northeastern states.

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Correlation between Carbon Steel Corrosion and Atmospheric Factors in Taiwan

  • Lo, C.M.;Tsai, L.H.;Hu, C.W.;Lin, M.D.
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.37-44
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    • 2018
  • Taiwan has a typical marine climate featuring perennial high-temperature and dampness. This climate, together with the emission of various industrial corrosive waste gases in recent years, contributes a lot to the corrosion of metal materials. In this study, samples of carbon steel exposed to various atmospheres in Taiwan were analyzed to investigate the impacts of atmospheric factors on carbon steel corrosion. Carbon steel samples were collected from 87 experimental stations between 2009 and 2012. Statistical analysis was employed to investigate the correlations between the carbon steel corrosion situations and the atmospheric factors such as concentrations of sulfur dioxide or chloride, exposure time, rainfall, etc. The results indicate that for samples from industrial areas, the sulfur dioxide concentration and exposure time during fall and winter are significantly correlated to the condition of the carbon steel corrosion. However, for samples from coastal zones, the significant correlated factors are chloride concentration and wetting time during winter. The results of this study are useful for the development of carbon steel corrosion prediction models.