• Title/Summary/Keyword: Sulfur

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Reinforcement of Concrete Structure by Impregnation of Molten Sulfur (용융황 침투에 의한 콘크리트 구조물의 물성 증진에 관한 연구)

  • 김종국;오준택;설용건;김우식
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.729-736
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    • 1989
  • This study aims to reinforce concrete structure by impregnation of molten sulfur. The improved properties of sulfur impregnated concerete were confirmed by compressive strength test and water proof effect. Following variables were adopted to evaluate impregnation parameters ; 1) the effect of water content in concrete structure (0-8%) 2) impregnation time of molten sulfur(0-22hr) 3) impregnation temprature of molten sulfur(13$0^{\circ}C$, 14$0^{\circ}C$). In partial ponding experiments, the concrete specimen of sulfur impregnated by 2wt% yields 1.5 times higher value of compressive strength than that of control one(non-impregnated concerte). In complete ponding experiments, the mortar specimen of slufur impregnated by 12-14wt% yields 2-3 times higher value of compressive strength than that of control one (non-impregnated mortar). From the examination of X-ray diffractions, $\alpha$-sulfur was found in concrete pores. Homogeneous impregation of molten sulfur into concrete pores was also identified with poresize analysis and micrographs of SEM.

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Study on the Sulfide Corrosion to the Internal Surface of Transportation Pipeline

  • Zhang, Yiling;Qi, Ping;Kong, Dehong
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.193-196
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    • 2008
  • This article briefly tests and analyzes the sulfur content and the distribution of active sulfur in the crude oil of Kurkow Kazakhstan and Siberian Russian, and discusses the relationship between active sulfur content and total sulfur content, active sulfur and corrosion. At the same time, it measures the open circuit potential of X70 steel and X60 steel witch have been immerged in the above two kind of crude oil for a period of time, discusses the sulfur corrosion to metal.

Bio-Sulfur Pre-Treatment Suppresses Anthracnose on Cucumber Leaves Inoculated with Colletotrichum orbiculare

  • Ko, Eun Ju;Shin, Yong Ho;Hyun, He Nam;Song, Hyo Soon;Hong, Jeum Kyu;Jeun, Yong Chull
    • Mycobiology
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    • v.47 no.3
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    • pp.308-318
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    • 2019
  • Bio-sulfur can be produced in the process of desulfurization from a landfill and collected by some microorganism such as Thiobacillus sp. as a sulfur element. In order to investigate practical use of bio-sulfur as an agent for controlling plant disease, in vitro antifungal activity of bio-sulfur was tested against Colletotrichum orbiculare known to cause cucumber anthracnose. Efficacy of bio-sulfur for suppressing anthracnose disease was also evaluated in vivo using cucumber leaves. Mycelial growth of C. orbiculare on medium containing bio-sulfur was inhibited. Disease severity of cucumber leaves pre-treated with bio-sulfur was significantly decreased compared to that of untreated ones. To illustrate how bio-sulfur could suppress anthracnose disease, structures of cucumber leaves infected with C. orbiculare were observed under a fluorescent microscope and a scanning electron microscope (SEM). Cucumber leaves pre-treated with bio-sulfur showed a low rate of appressorium formation whereas untreated ones showed abundant appressoria. Shrunk fungal hyphae were mostly observed on bio-sulfur-pretreated leaves by SEM. Similar results were observed on leaves pre-treated with a commercial fungicide Benomyl(R). These results suggest that inhibition of appressorium formation of C. orbiculare by bio-sulfur may contribute to its suppression of cucumber anthracnose.

Effect of Soil Sulfur treatment on Apple Valsa Canker (유황토분 처리가 사과 부란병에 미치는 영향)

  • Chun, Ik-Jo;Park, Seung-Min
    • Korean Journal of Organic Agriculture
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    • v.25 no.1
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    • pp.125-134
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    • 2017
  • This study was carried out to examine the effects of soil sulfur mixture on the control apple valsa canker in apple orchard for two years. In organic apple orchard, The recovery percentages of apple valsa canker were compared among control (no treatment), lime sulfur, and soil sulfur in organic orchards. In conventional apple orchards, those of recovery percentages were compared among control, neoasozin, lime sulfur, and soil sulfur. Compared with control, soil sulfur treatments significantly improved the recovery percentages of apple valsa canker infected trees in organic orchard. However, there were no differences between lime sulfur and soil sulfur treatment in organic apple orchard, except BongHyun orchard experiment in 2013. Compared with control fruit qualities, fruit skin red color and fruit firmness were improved in lime sulfur and soil sulfur treatment, respectively. In conventional orchard, apple trees treated with lime sulfur, soil sulfur or neoasozin improved recovery percentages, compared with those of control trees. Soil sulfur treatments recovered 87.5~97.5% of infected 'Fuji'/MM106 apple trees in organic and conventional apple orchards. The trees applied with neoasozin showed significant lower shoot growth than those of soil sulfur treatment in conventional orchard. Soli sulfur treatment improved fruit red color, but did not affected fruit weight, fruit firmness, soluble solids concentrations, and titratable acidity.

Monitoring of Residual Sulfur Dioxide in Herbal Medicines (유통 한약재의 잔류이산화황에 대한 모니터링)

  • Kim, Mi-Kyeong;Hur, Moon-Hye;Lee, Chang-Hee;Jin, Jong-Seong;Jin, Sun-Kyung;Lee, Young-Ja
    • Korean Journal of Pharmacognosy
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    • v.35 no.4 s.139
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    • pp.276-282
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    • 2004
  • This study has been conducted to investigate the amount of residual sulfur dioxide for herbal medicines of 30 species which are purchased in 13 different regions (Bonghwa, Busan, Chunju, Jecheun, Kwangiu, Keumsan, Seoul, Taeku, Cheungdu, Xian, Beijing, Tokyo and Osaka). The sulfur dioxide residues were determined in the collected 386 samples by the modified Monier-Williams method. The residues of sulfur dioxide in 386 samples ranged from ND (under detection limit) to 2808 ppm. The sulfur dioxide in Cassiae Semon, Cinnamomi Ramulus, Cervi Cornu, Hoelen, Crataegi Fructus, Artemisiae Argyi Herba, Scolopendrae Corpus, Schizandrae Fructus and Cyperi Rhizoma were detected under the detection limit regardless of the collected regions. The sulfur dioxide residues in herbal medicines collected in domestic regions were relatively lower than those in foreign regions. There are no standards for sulfur dioxide residual limits of herbal medicines in Korea. This results will provide the scientific basis for the standardization of sulfur dioxide residues in Korea Pharmacopoeia.

Discharge Properties of Sodium-sulfur Batteries at Room Temperature (상온용 나트륨/유황전지의 방전 특성)

  • Kim, T.B.;Ahn, H.Y.;Hur, H.Y.
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.193-197
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    • 2006
  • The sodium/sulfur(Na/S) battery has many advantages such as high theoretical specific energy(760Wh/kg), and low material cost based on the abundance of electrode material in the earth. It has been reported that the electrochemical properties of sodium/sulfur cell above $300^{\circ}C$, utilized a solid ceramic electrolyte and liquid sodium and sulfur electrodes. A lot of researches have been performed in this field. Recently, Na/S battery system was applied for electricity storage system for load-leveling. One of severe problems of sodium/sulfur battery was high operating temperature above $300^{\circ}C$, which could induce the explosion and corrosion by molten sodium, sulfur and polysulfides. In order to develop sodium battery operated at low temperature, sodium ion battery has been studied using carbon anode, and sodium oxides cathodes. However, the energy densities of the sodium ion batteries were much lower than high temperature sodium/sulfur cell. In this study, the sodium/sulfur battery with 1M $NaCF_3SO_3$ is tested at room temperature. The charge-discharge mechanism was discussed based on XRD, DSC, SEM and EDS results.

Inorganic sulfur reduces the motility and invasion of MDA-MB-231 human breast cancer cells

  • Kim, Jin-Joo;Ha, Hwa-Ae;Kim, Hee-Sun;Kim, Woo-Kyoung
    • Nutrition Research and Practice
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    • v.5 no.5
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    • pp.375-380
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    • 2011
  • This study investigated the effects of inorganic sulfur on metastasis in MDA-MB-231 human breast cancer cells. MDA-MB-231 cells were cultured in the absence or presence of various concentrations (12.5, 25, or 50 ${\mu}mol$/L) of inorganic sulfur. Cell motility, invasion, and the activity and mRNA expression of matrix metalloproteases (MMPs) were examined. Numbers of viable MDA-MB-231 cells did not differ by inorganic sulfur treatment from 0 to 50 ${\mu}mol$/L within 48 h. Inorganic sulfur significantly decreased cell motility and invasion in the MDA-MB-231 cells in a dose-dependent manner (P<0.05), as determined using a Boyden chamber assay and a Matrigel chamber. The activities of MMP-2 and MMP-9 were significantly reduced by inorganic sulfur in a dose-dependent manner (P<0.05). The inorganic sulfur also significantly inhibited MMP-2 and MMP-9 expression in the cells (P<0.05). These data suggest that inorganic sulfur can suppress cancer cell motility and invasion by inhibiting MMP-2 and MMP-9 activity and gene expression in MDA-MB-231 cells.

The Effect of the Gypsum Application on the Composition of Nitrogen and Sulfur Compounds in Mixed Pasture and on the Sulfur Balance in Soil (혼파초지에서 Gypsum 처리가 목초의 질소 및 황화합물조성과 토양중 황균형에 미치는 영향)

  • 윤순강;황석중;김재규
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.8 no.3
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    • pp.152-157
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    • 1988
  • The effect of gypsum application was tested on dry matter yield, sulfur uptaken, composition of Ritrogen compound and sulhr compound and sulfur balance in mixed pasture. Total dry matter yields and sulfur uptake by grasses increased with the increasing of gypsum application rates. The ratios between total nitrogen and total sulfur in masses decreased with the increase of sulfur uptake at 2nd and 3rd cutting times. Cysteine content was little affected by gypsum while methionine content slightly increased an 4.0, 6.0 kg3 per 10a levels at 2nd and 3rd cutting times. The uptake of nitrate nitrogen decreased with gypsum application and dry matter digestibility increased about 1.1 to 3.3%. The soil pHs after experiment become high in surface and subsoil till 6.0 kg.S per 10a, but low at 10.0 kg.S per 10a. The content of sulfur in surface soil was 19.9 ppm after experiment, but very high in subsoi1,ranging from 94 to 143 ppm.S. Sulfur leached from the surface soil by 0.69, 2.39, and 6.24 kg.S per 10a in the plots of 4.0, 6.0, and 10.0 kg.S per 10a, respectively.

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Effects of Sulfur Segregation on Tertiary Recrystallization Kinetics in Thin-gauged 3% Si-Fe Electrical Strip

  • Chai, K.H.;Na, J.G.;Heo, N.H.;Kim, J.C.;Lee, S.R.;Woo, J.S.
    • Journal of Magnetics
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    • v.4 no.1
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    • pp.5-9
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    • 1999
  • Effect of sulfur segregation on tertiary recrystallization and magnetic induction during final annealing was investigated in a 3% Si-Fe electrical strip containing 6 ppm(LS) and 15 ppm(HS) sulfur. During final annealing, Auger peak height of segregated sulfur on the surface of the strips reached a maximum, and then decreased to low level with increasing annealing time, which is attributed to sulfur segregation and evaporation. The magnetic induction of the thin-gauged 3% Si strip was inversely proportional to the Auger peak height of segregated sulfur on the surface. The overall profile for surface segregation of sulfur and B10 was observed, irrespective of sulfur content in Si-Fe strips, but the peaks of LS strips appeared earlier than those of HS strips. The grain growth rate of the LS strips during final annealing was faster than that of the HS strips, which may be attributed to the pinning effects of segregated sulfur. With increasing final annealing temperature, B10 value increased rapidly and the saturation level in B10 increased.

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The Effect of Sulfur Dioxide by Burn out on Enzyme Activity and Lipid Content in Rats (소환시 발생되는 아황산 가스가 흰쥐 혈청 중의 효소 활성도 및 지질 함량에 미치는 영향)

  • Kim, Hae-Dong;Kim, Byung-Hak;Ha, Hun;Cho, Soo-Yeul;Yoon, Soo-Hong
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.61-66
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    • 1997
  • Recently, incidences of pulmonary-related diseases are increasing and natural ecosystem is destroyed year by year owing to air pollutions by industrial noxious gases such as sulfur dioxide and carbon dioxide, etc. Sulfur dioxide produced by oxidation of sulfur compounds is water soluble and causes several kinds of pulmonary diseases, damaging on plants and animals. This study was undertaken to investigate effects of acute exposure of rats to sulfur dioxide using biochemical parameters. The sAST (aspartate transaminase) activity was not significantly affected but sALT (alanine transaminase), sLDH (lactate dehydrogenase) and sALP (alkaline phosphatase) activities were significantly increased by acute sulfur dioxide gas exposure. Also sulfur dioxide gas treatment significantly diminished serum cholinesterase activity. The total lipid, triglyceride, total-, HDL- and LDL-cholesterol contents were significantly increased by sulfur dioxide gas exposures. But the body and liver weight were generally diminished in comparison with control group. Our results' showed increased enzyme activities and lipid contents, but body and liver weight were all diminished by sulfur dioxide gas treatment.

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