• Title/Summary/Keyword: Sulfate ability

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THE PHYSICAL PROPERTIES AND HEALING EFFECT OF CALCIUM SULFATE-HYDROXYAPATITE COMPOUND ON ROOT PERFORATION (Calcium sulfate-Hydroxyapatite 혼합재의 물성 및 치근천공 치유효과에 관한 연구)

  • Lee, Seung-Jong;Kim, Kyoung-Nam
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.739-750
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    • 1997
  • Treatment of root perforation elicits special considerations due to its blood-contaminated circumstances. It is known that conventional dental restorative materials are all leaking. Calcium sulfate is the material which react with water to become chemically set. This study, therefore, was performed to develop a new compound containing calcium sulfate and to evaluate its physical and biological characteristics. Three materials were used, IRM, calcium sulfate, calcium sulfate-hydroxyapatite compound. The composition of the calcium sulfate-hydroxyapatite compound was basically 50 % of calcium sulfate and 50 % of hydroxyapatite mixed with guajacol. The materials were mixed in conventional way and underwent four physical test procedures, setting time, solubility test, compressive strength, and marginal leakage test. All materials were evaluated under the scanning electron microscope to examine the marginal sealing ability. Animal experiment was also performed to test the materials' tissue response. Twenty-four dog's premolars were tested with either furcation perforations or apical retro-fillings. From the results, we found that calcium sulfate possess the good marginal sealing ability. However, calcium sulfate creates many voids which is caused by crystal thrusting action when it reacts with water. It seemed that the voids caused disintegration of the material which eventually lead to tissue reaction. By compounding calcium sulfate and hydroxyapatite, we were able to obtain the better physical properties but it showed larger marginal gap between the material and the root surface. Within the six weeks observation period, both IRM and calcium sulfate-hydroxyapatite compound showed good tissue responses in animal experiment. It is concluded that calcium sulfate would be the material of choice in root perforation repair, but the physical property needs to be further improved.

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Development and Performance Comparison of Silicon Mixed Shielding Material (실리콘 혼합 차폐체의 개발과 성능비교)

  • Hoi-Woun Jeong;Jung-Whan Min
    • Journal of radiological science and technology
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    • v.46 no.3
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    • pp.187-195
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    • 2023
  • A shield was made by mixing materials such as bismuth(Bi) and barium(Ba) with silicon to evaluate its shielding ability. Bismuth was made into a shield by mixing a bismuth oxide(Bi2O3) colloidal solution and a silicon base and applied to a fibrous fabric, and barium was made by mixing lead oxide(PbO) and barium sulfate(BaSO4) with a silicon curing agent and solidifying it to make a shield. The test was conducted according to the lead equivalent test method for X-ray protective products of the Korean Industrial Standard. The experiment was conducted by increasing the shielding body one by one from the test condition of 60 kVp, 200 mA, 0.1sec and 100 kVp, 200 mA, 0.1 sec. At 60 kVp, 2 lead oxide-barium sulfate shields, 2 bismuth oxide 1.5 mm shields, and 5 bismuth oxide 0.3 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. At 100 kVp, 2 lead oxide-barium sulfate shields and 2 bismuth oxide 1.5 mm shields showed shielding ability equal to or higher than that of lead 0.5 mm. It was confirmed that when using 2 pieces of lead oxide-barium sulfate and 1.5 mm of bismuth oxide, respectively, it has shielding ability equivalent to that of lead. Bismuth oxide and lead oxide-barium sulfate are lightweight and have excellent shielding ability, thus they have excellent properties to be used as an apron for radiation protection or other shielding materials.

Microbial Subversion of Heparan Sulfate Proteoglycans

  • Chen, Ye;Gotte, Martin;Liu, Jian;Park, Pyong Woo
    • Molecules and Cells
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    • v.26 no.5
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    • pp.415-426
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    • 2008
  • The interactions between the host and microbial pathogen largely dictate the onset, progression, and outcome of infectious diseases. Pathogens subvert host components to promote their pathogenesis and, among these, cell surface heparan sulfate proteoglycans are exploited by many pathogens for their initial attachment and subsequent cellular entry. The ability to interact with heparan sulfate proteoglycans is widespread among viruses, bacteria, and parasites. Certain pathogens also use heparan sulfate proteoglycans to evade host defense mechanisms. These findings suggest that heparan sulfate proteoglycans are critical in microbial pathogenesis, and that heparan sulfate proteoglycan-pathogen interactions are potential targets for novel prophylactic and therapeutic approaches.

Studies on the Spectrophotometric Determination of Gentamicin Sulfate and its Preparations (분광광도법에 의한 제제중 Gentamicin Sulfate의 정량에 관한 연구)

  • 이진호;양호석;이윤중
    • YAKHAK HOEJI
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    • v.27 no.1
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    • pp.45-52
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    • 1983
  • The ability of gentamicin to form a stable coloured complex with copper (II) in a sodium carbonate buffer solution, which had a maximum absorption at 694nm, was used for the spectrophotometric quantitative determination of gentamicin sulfate. The calibration curve obtained was linear over the range of 200~2,000mcg per ml of the sample and the analysis was very well agreed with the microbiological method.

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Effect of Sodium Sulfate on Ramie Fabrics Treated with Pectinase (저마직물의 펙티나제 정련 시 황산나트륨의 영향)

  • Park, So-Young;Song, Wha-Soon;Kim, In-Young
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.220-228
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    • 2010
  • This study examines the scouring effect of pectinase on ramie fabric and influence of sodium sulfate as an activator for pectinase. The scouring effects were measured by the weight loss and pectin contents. SEM, weight loss, stiffness, moisture regain and dye ability of ramie fabric teated with pectinase/sodium sulfate were also measured. When ramie fabrics were desized with $\alpha$-amylase, the optimum conditions were pH 6.5 at $60^{\circ}C$ for 80 min with 1%(o.w.f) $\alpha$-amylase concentration. When ramie fabrics were scoured with pectinase, the optimum conditions were pH 8.5 at $55^{\circ}C$ for 30 min with 10%(o.w.f) pectinase concentration. Addition of sodium sulfate improved enzyme activity significantly, which increased proportionally with increasing sodium sulfate concentration. When 50 g/l of sodium sulfate was added, the surface became cleaner compared to the enzyme treatment without salt: weight and tensile loss, moisture regain and dyeability of the treated fabrics increased, while pectin contents and stiffness decreased. Therfore, sodium sulfate was effective activator for the pectinase treatment of flax fiber.

Competitive Adsorption and Subsequent Desorption of Sulfate in the Presence of Various Anions in Soils

  • Hong, Byeong-Deok;Lee, Kyo-seok;Lee, Dong-Sung;Rhie, Ja-Hyun;Bae, Hui-Su;Seo, IL-Hwan;Song, Seung-Geun;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.541-547
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    • 2016
  • In this experiment we investigated the influence of various anions including oxalic acid encountered as solution phase in soil on the adsorption and desorption of sulfate in Chungwon Bt soil. The effect of chloride and nitrate on the adsorption of sulfate was not significant, suggesting that sulfate was better able to compete for adsorption sites at concentrations studied, in contrast to the large reduction in the amount of chloride adsorbed in the presence of sulfate. The results of competition for sorption sites between sulfate and anion showed that the simultaneous presence of two anions in solution was effective in reduction of competing anion at a maximum value of adsorption, due to the similar adsorption mechanism for anion competition. Therefore, the variation in the buffer power of the acids will produce a change in the strength and amount of adsorption and the competitive ability.

Isolation and Characterization of a Dibenzothiophene Degrading Sulfate-Reducing Soil Bacterium

  • Kim, Hae-Yeong;Kim, Tae-Sung;Kim, Byung-Hong
    • Journal of Microbiology and Biotechnology
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    • v.1 no.1
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    • pp.1-5
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    • 1991
  • Sulfate-reducing bacteria have been isolated from soil and their abilities to degrade dibenzothiophene (DBT) were compared with those of type cultures. Among the strains tested a soil isolate M6 showed the highest ability to degrade DBT. Isolate M6 was characterized as a mesophilic obligatory anaerobe. The morphology of the bacterium was vibrioid with the size of $0.4-0.7{\;}\mu\textrm{m}{\;}by{\;}1.0-1.5{\;}\mu\textrm{m}$. Gram reaction was negative and nonsporulating. Desulfoviridin is present. Lactate, pyruvate, ethanol and malate supported growth of the bacterium in the presence of sulfate. Sulfate, sulfite, thiosulfate and sulfur served as electron acceptors for growth. Hydrogenase was present. The mol% of guanine and cytosine of DNA was determined as 56%. The bacterium produced viscous material. From these results, the isolate M6 was identified as Desulfovibrio desulfuricans.

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A Microbial Consortium for the Bioremediation of Sulfate-Rich Wastewater Originating from an Edible Oil Industry

  • Pascual, Javier;Rodriguez, Alejandro;Delgado, Clara Elena;Rizo-Patron, Alejandra;Porcar, Manuel;Vilanova, Cristina
    • Microbiology and Biotechnology Letters
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    • v.50 no.1
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    • pp.110-121
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    • 2022
  • The effluents from industries processing vegetable oils are extremely rich in sulfates, often exceeding the maximum concentration allowed to release them to the environment. Biological sulfate reduction is a promising alternative for the removal of sulfates in this type of wastewater, which has other particularities such as an acidic pH. The ability to reduce sulfates has been widely described for a particular bacterial group (SRB: sulfate-reducing bacteria), although the reports describing its application for the treatment of sulfate-rich industrial wastewaters are scarce. In this work, we describe the use of a natural SRB-based consortium able to remove above 30% of sulfates in the wastewater from one of the largest edible oil industries in Peru. Metataxonomic analysis was used to analyse the interdependencies established between SRB and the native microbiota present in the wastewater samples, and the performance of the consortium was quantified for different sulfate concentrations in laboratory-scale reactors. Our results pave the way towards the use of this consortium as a low-cost, sustainable alternative for the treatment of larger volumes of wastewater coming from this type of industries.

Chemical Coagulation Conditions and Efficiency of Sewage with Al(III) and Fe(III) Coagulants (하수의 화학적 응집조건 및 응집제별 응집효율 분석)

  • Park, June-Gue;Tian, Dong-Jie;Park, Noh-Back;Jun, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.4
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    • pp.463-474
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    • 2010
  • In this study, chemical coagulation conditions for treating combined sewer overflow(CSO) occurred during rainy season were evaluated by jar tests with aluminum sulfate[$Al_2(SO_4)_3{\cdot}17H_2O$] and ferric chloride[$FeCl_3{\cdot}6H_2O$]. The raw domestic sewage sampled from the primary sedimentation tank at a local sewage treatment plant was filtered through $150{\mu}m$ sieve before using. Point of zero charge(PZC) for various dose of aluminum sulfate occurred at pH 5.8-6.5, while for ferric chloride occurred at pH 5.3-6.0 in term of streaming current(SC) values. Charge neutralization ability of aluminum sulfate was bigger than that of ferric chloride. Optimum pH and dose of aluminum sulfate and ferric chloride were 6.2, 0.438mM and 5.8, 0.925mM, respectively. Removal efficiencies of TCOD, turbidity, SS and TP were 75, 97, 95, 96% with aluminum sulfate and 74, 96, 98, 99% with ferric chloride at their optimum coagulation conditions. More efficient removal of SS, TP and small particles was possible with ferric chloride at optimum coagulation conditions. Both SC values and COD removal started to increase where soluble phosphorus was completely removed.

An Experimental Study on the Chloride Attack Resistibility of Alkali-Activated Ternary Blended Cement Concrete (알칼리 활성화 3성분계 혼합시멘트의 염해 저항성에 관한 실험적 연구)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Jeon, Chan-Soo;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.321-329
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    • 2016
  • The use of ternary blended cement consisting of Portland cement, granulated blast-furnace slag (GGBFS) and fly ash has been on the rise to improve marine concrete structure's resistance to chloride attack. Therefore, this study attempted to investigate changes in chloride attack resistibility of concrete through NT Build 492-based chloride migration experiments and test of concrete's ability to resist chloride ion penetration under ASTM C 1202(KS F 2271) when 1.5-2.0% of alkali-sulfate activator (modified alkali sulfate type) was added to the ternary blended cement mixtures (40% ordinary Portland cement + 40% GGBFS + 20% fly ash). Then, the results found the followings: Even though the slump for the plain concrete slightly declined depending on the use of the alkali-sulfate activator, compressive strength from day 2 to day 7 improved by 17-42%. In addition, the coefficient from non-steady-state migration experiments for the plain concrete measured at day 28 decreased by 36-56% depending on the use of alkali-sulfate. Furthermore, total charge passed according to the test for electrical indication of concrete's ability to resist chloride ion penetration decreased by 33-62% at day 7 and by 31-48% at day 28. As confirmed in previous studies, reactivity in the GGBFS and fly ash improved because of alkali activation. As a result, concrete strength increased due to reduced total porosity.