• Title/Summary/Keyword: Substitution Effect

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Effect of Tungsten-Substitution on the Corrosion Resistance of 2205 Duplex Stainless Steel (2205 2상 스테인리스강의 내식성에 미치는 텅스텐 치환의 영향)

  • 김기엽;안용식;정병호
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.6
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    • pp.704-713
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    • 2003
  • The effect of partial substitution of tungsten for molybdenum on the microstructure and corrosion resistance in 22Cr-5Ni-3Mo duplex stainless steel(DSS) aging heat treated in a temperature range of 600~$1000^{\circ}C$ has been investigated. Electrochemical tests were carried out for the evaluation of corrosion resistance. Aging treatment had hardly influenced the general corrosion resistance. With the increase of aging time, the pitting corrosion resistance of the DSS had decreased, After aging for 2min at 700~$900^{\circ}C$, the pitting potential of the 3Mo steel decreased remarkably, while that of the W-substituted steel hardly changed. During aging. the intermetallic $\sigma$ and secondary austenite ($\gamma_2$) phases were precipitated. and the pitting corrosion and intergranular corrosion resistance were significantly decreased after aging at 700~$750^{\circ}C$ for 10 h, which could be caused by the $\gamma_2$ formation. The ${\gamma}$$_2$ phase could affect the depletion of molybdenum and chromium in the $\gamma_2/\alpha and \gamma_2/\sigma$ boundaries.

Synthesis of $\textrm{TiB}_2$ Powder by Mechanical Alloying and the Effect of Zr and Ta Substitution for Ti (기계적합금법에 의한 $\textrm{TiB}_2$ 분말의 제조 및 Zr과 Ta이 합성에 미치는 영향)

  • Hwang, Yeon;Kang, Eul-Son
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.787-791
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    • 1999
  • TiB$_2$powders were prepared by mechanical alloying, and the effect of Zr and Ta substitution for Ti was investigated. It was possible to produce titanium diboride phase by mechanical alloying titanium and boron elemental powders for 280 hours. The amorphization reaction, a common process which occurs during mechanical alloying, has not been found. When zirconium of which atomic radius was larger than that of titanium was substituted for Ti, the alloying time was greatly reduced. On the contrary, substitution of tantalum for titanium prolonged the alloying time because of the less negative heat of formation of tantalum diboride than that of titanium diboride.

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HDDR Characteristics and Magnetic Properties of Nd15(Fe1-xCox)77B8(x=0-0.6) Alloys

  • Kwon, H.W.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.127-131
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    • 2002
  • HDDR characteristics and magnetic properties of $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys were investigated. The effect of applying magnetic field during the recombination step on the anisotropic nature of the HDDR-treated material was also examined. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$ phase in the Nd-Fe-B alloys with high Co-substitution alloy had remarkably enhanced phase stability. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution could be HDDR-treated successfully by only using high pressure hydrogen. However, these alloys had no appreciable coercivity. The poor coercivity of the HDDR-treated $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution was attributed to the $Nd{(Fe,Co)}_2$ phase in the alloys. The magnetic filed applied during the recombination step had little effect on the anisotropic nature of the HDDR-treated powder.

Cage Link and the Effect of Cross-Link Breakdown (Cross-Link Breakdown 효과와 Cage Link)

  • Oh, Teresa;Kim, Kyung-Sik
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.517-520
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    • 2004
  • Organosilicate films are promising porous low-dielectric materials, which can replace the silicon dioxide films. It was researched that organosilicate films have two different chemical shifts according to the increase of the flow rate ratio. There are the red shift due to the electron deficient substitution group, and the blue shift of the electron rich substitution group. Among these chemical shifts, the blue shift from $1000 cm^{-1}$ to $1250 cm^{-1}$ was related with the formation of pores. The methyl radicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the Si-O-C cage-link near $1057 cm^{-1}$ is originated from the cross-link breakdown due to much methyl radicals.

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An Experimental Study on the Improvement of Durability for Face Slab Concrete in CFRD (CFRD 표면 차수벽 콘크리트의 내구성 향상에 관한 실험 연구)

  • 우상균;송영철;원종필;윤영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.1017-1022
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    • 2001
  • Dam concrete for pumped storage power plants should have sufficient durability in repetitive wet and dry conditions and abrasion due to water level fluctuation and also in freezing and thawing resistance as well as permeability capacity. This study presents various experimental results to enhance the durability of face slab concrete in CFRD(concrete faced rockfill dam) by varying the fly ash substitution such as 0%, 15%, 20% and 25% and polypropylene such as 0%, 0.1%. The effect on durability of concrete corresponding to the increasing amount of fly ash and polypropylene was evaluated and the optimum quantity of fly ash and polypropylene substitution was recommended. The results show that 20% of fly ash substitution and 0% of polypropylene were found out to be an optimum quantity to achieve excellent performances in durability for face slab concrete in CFRD.

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Linear Motion Perception under Additional Somatosensation (추가된 체성 감각에 의한 선형 운동 지각 변화)

  • Yi, Yong-Woo;Park, Su-Kyung
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.6
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    • pp.678-686
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    • 2011
  • When one sensor cannot provide information by sensory deficit or loss, the sensory information can be provided by substituting other sensors for the defected sensor. This sensory substation might be influence on the deteriorated motion perception that consists of multi-sensory information such as visual, vestibular and somatosensory information. In this study, to investigate whether the additional sensation by sensory substitution could be integrated into the motion perception, we examined the effect of substituted postural sway sensation on the directional perception of body movement. Deteriorated motion perception by the reduced plantar sensation was enhanced under sensory substitution condition that provided the body sway information as the plantar vibratory stimulus. These results imply that the additional sensation might be integrated into and improve the motion perception.

The effect of PCN substitution on dielectric and piezoelectric properties of PMN-PZT Ceramics (PCN 치환이 PMN-PZT 세라믹스에 유전 및 압전특성에 미치는 영향)

  • Nam, Seung-Hyon;Yoo, Ju-Hyun;Lee, Su-Ho;Jeong, Yeong-Ho;Park, Chang-Yub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.161-164
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    • 2004
  • In this study, to develop the composition ceramics for the Ultrasonic vibrator, $Pb(Mn_{1/3}Nb_{2/3})O_3Pb(Zr.Ti)O_3$ system ceramics were manufactured as a function of PCN substitution. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of PCN substitution, electromechanical coupling factor(kp) were increased until 3mol% PCN and that after decreased. mechanical quality factor(Qm) showed the maxinum value at 2mol% PCN. Eletromechanical coupling factor, mechanical quality factor and dielectric constant were showed optimum value at PCN 2mol% as 0.58, 1630 and 1407, respectively for ultrasonic vibrator applications.

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Effect of CBS-dust replacement rate on the Qualities of High Volume GGBFS Cement Bricks (CBS-dust 치환에 따른 고로슬래그 다량치환 시멘트 벽돌 품질에 미치는 영향)

  • Han, Jun-Hui;Han, Soo-Hwan;Kim, Su-Hoo;Yoon, Chi-Whan;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.105-106
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    • 2021
  • This study examines the performance of CBS-Dust for the utilization of cement bricks as alkali stimulants for furnace slag replacement binders. It converts the CBS-Dust substitution rate and the excess slag substitution rate. According to the analysis, when replacing CBS-Dust with 65~70 % of BS substitution rate and 7.5~10 % of CBS-Dust, it shows excellent performance as an alkali stimulant of BS' potential hydrophobic reaction, and it is expected to be effective for secondary products of BS replaced in large quantities.

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Catalytic Combustion of Methane over Perovskite-Type Oxides

  • Hong, Seong-Soo;Sun, Chang-Bong;Lee, Gun-Dae;Ju, Chang-Sik;Lee, Min-Gyu
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.2
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    • pp.95-102
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    • 2000
  • Methane combustion over perovskite-type oxides prepared using the malic acid method was investigated. To enhance the catalytic activity, the perovskite oxides were modified by the substitution of metal into their A or B site. In addition, the reaction conditions, such as the temperature, space velocity, and partial pressure of the methane were varied to understand their effect on the catalytic performance. With the LaCoO3-type catalyst, the partial substitution of Sr or Ba into site A enhanced the catalytic activity in the methane combustion. With the LaBO3(B=Co, Fe, Mn, Cu)-type catalyst, the catalytic activities were exhibited in the order of Co>Fe Mn>Cu. Futhermore, the partial substitution of Co into site B enhanced the catalytic activity, whereas an excess amount of Co decreased the activity. The surface area and catalytic activity of the perovskite catalysts prepared using the malic acid method showed higher values than those prepared using the solid reaction method. The catalytic activity was enhanced with decreased methane concentration and with a decrease in the space velocity.

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Superconductivty and magnetic properties of $(Ru_{1-x}Nb_x)Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$

  • Lee, H.K.;Bae, S.M.;Lee, J.M.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.3
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    • pp.1-4
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    • 2013
  • We investigated the effect of Nb substitution for Ru on the structural and magnetic properties of $(Ru_{1-x}Nb_x)\;Sr_2(Sm_{1.4}Ce_{0.6})Cu_2O_z$ Samples. X-ray diffraction measurements indicated that nearly single-phase samples are formed in the range from x = 0 to 1.0. The superconducting transition temperature determined from the inflection in the field-cooled magnetic susceptibility decreased only slightly from $T_c$ = 25 K for x = 0 to $T_c$ = 22 K for x = 1.0, in consistent with the change in room temperature thermopower of the samples. However, the Nb substitution for Ru above x = 0.25 significantly suppressed the weak ferromagnetic component of the field-cooled magnetic susceptibility. It was also found that the Nb substitution for Ru results in an enhanced diamagnetic susceptibility with Nb content above x = 0.5 in both zero field-cooled and field-cooled magnetization measurements, in contrast to the behavior of the samples with $x{\leq}0.5$ in which the diamagnetic susceptibility decreases as the Nb content increases.