• Bulletin of the Korean Chemical Society
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• 제14권4호
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• pp.425-427
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• 1993

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1310-1314
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• 2006

Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.

• 디지털융복합연구
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• 제15권11호
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• pp.199-207
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• 2017

기술 진보 및 융합과 함께 매우 빠르게 변화하는 사업 환경은 기업의 성공에 있어서 연구개발(R&D)의 역할을 더욱 더 중요하게 하고 만들고 있다. 본 연구는 기업 수준의 683개 중소 벤처기업 데이터를 대상으로 최소 자승 회귀분석을 실시하여 다음과 같은 4가지 주요 사항을 새롭게 조명한다. 첫째, 중소 벤처기업의 외부 R&D 협력 네트워크의 다양성은 기술 개발로 인한 수입 대체에 정(+)의 영향을 준다. 둘째, 기업 부설 연구소의 존재는 중소 벤처기업의 외부 R&D 협력 네트워크의 다양성이 기술 개발로 인한 수입 대체에 주는 양(+)의 영향을 조절한다. 셋째, 중소 벤처기업의 외부 R&D 정보 네트워크의 다양성은 기술 개발로 인한 수입 대체에 정(+)의 영향을 미친다. 넷째, 기업 부설 연구소의 존재는 중소 벤처기업의 외부 R&D 정보 네트워크의 다양성이 기술 개발로 인한 수입 대체에 주는 양(+)의 영향을 조절한다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.75-80
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• 2002

This study is to investigate the characteristic on the resistance of chloride infiltration concrete containing limestone powder The variables are the substitution ratio of slag powder and limestone powder. In order to study the effect slag powder and limestone powder, all mixtures were prepared at a fixed water/cement ratio, slump, and entrained air quantity. As results show that the strength and the resistance of chloride infiltration in concrete substitution 10%, 20% limestone powder, and 30%, 40% slag powder are positive.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.233-238
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• 1998

For substitution for crushed sand, high strength aggregate for cement and concrete using coal ash as a main material was prepared and then compared its physical properties with those of crushed sand. Effect of mix proportion change of raw materials on the property of aggregate was checked. On the basis of these experimental results we are going to comprehend the reutilization of coal ash and utilize a basic data for judging possibility the substitution of crushed sand.

• Bulletin of the Korean Chemical Society
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• 제6권3호
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• pp.162-164
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• 1985

Nucleophilic substitution reaction of dansyl chloride with anilines in various solvents have been investigated. The Bronsted ${\beta}$ and Hammett ${\rho}_N$ values indicated that the bond formation is advanced more than the bond breaking at the transition state. Solvatochromic correlations also predicted the importance of bond formation at the TS, showing a greater contribution of polarity (${\pi}^{\ast}$) compared to hydrogen bond donor acidity (${\alpha}$). The effect of solvent on rate was found to violate the reactivity-selectivity principle.

• 한국산업융합학회 논문집
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• 제7권3호
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• pp.299-303
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• 2004

A systematic investigation for the reactivity and solvent effect was studied on the reaction of optical resolving agents with the optically active assistant compounds. The reaction rate constants of the nucleophillic substitution reactions were determined by means of conductometric method The linear solvent energy relationship based on the solvent parameters and the thermodynamic parameters was discussed on the reactions of various physiological active compounds and optical resolving agents The reaction mechanism was discussed from the kinetic results compared with the optical purity.

• 한국축산시설환경학회지
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• 제3권1호
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• pp.19-26
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• 1997

Composting has recently become popular as a means of recycling swine manure into products for sale off the farm, but bulking agent(usually sawdust) are expensive and availability is limited. This experiment was conducted to investigate the effect of fly ash as a bulking agent on the composting of swine manure and to analyze the effective substitution rate of fly ash mixed with swine manure for sawdust. Fly ash was able to be substituted for sawdust and the most effective substitution rate are 50% of sawdust. According to the results the advanced research and development are required, the effect of swine manure with fly ash on the soil properties, forage composition and animal performance.

• 한국축산식품학회지
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• 제38권1호
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• pp.123-134
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• 2018

The effects of pork back fat (PBF) substitution with various concentrations of rice bran oil (RBO) (50%, 45%, 40% and 35%) on the physicochemical characteristics and sensory attributes of emulsion-type pork sausages were studied. The modified pork sausages were compared with control sausages produced using PBF only. The sausages with RBO had significantly lower (p<0.05) moisture content than the control sausages. Sausages made from PBF substituted with 40% RBO showed the lowest cooking loss. Substitution of PBF with RBO had no significant effect on the emulsion stability of pork sausages. All sausages with RBO showed significantly lower (p<0.05) hardness values than control sausages. Sausages with RBO also had significantly higher values (p<0.05) of unsaturated fatty acid and polyunsaturated to saturated fatty acid contents than the controls. RBO substitution had no effect on the flavor intensity of sausages, but it improved the tenderness and produced a softer texture.

• Transactions on Electrical and Electronic Materials
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• 제12권2호
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• pp.64-67
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• 2011

The effect of Ta substitution on the crystal structure, ferroelectric, and piezoelectric properties of $Bi_{0.5}(Na_{0.82}K_{0.18})_{0.5}Ti_{1-x}Ta_xO_3$ ceramics has been investigated. The Ta doping resulted in a transition from coexistence of ferroelectric tetragonal and rhombohedral phases to an electrostrictive pseudocubic phase, leading to degradations of the remnant polarization, coercive field, and piezoelectric coefficient $d_{33}$. However, the electricfield-induced strain was significantly enhanced by the Ta substitution-induced phase transition and reached a highest value of $S_{max}/E_{max}$ = 566 pm/V under an applied electric field 6 kV/mm when 2% Ta was substituted on Ti sites. The abnormal enhancement in strain was attributed to the pseudocubic phase with high electrostrictive constants.