• Title/Summary/Keyword: Subcritical water

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COMPUTATION OF FREE-SURFACE FLOWS DUE TO PRESSURE DISTRIBUTION

  • Jack Asavanant;Montri Maleewong;Choi, Jeong-Whan
    • Communications of the Korean Mathematical Society
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    • v.16 no.1
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    • pp.137-152
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    • 2001
  • Steady two-dimensional flows due to an applied pressure distribution in water of finite depth are considered. Gravity is included in the dynamic boundary condition. Gravity is included in the dynamic boundary condition. The problem is solved numerically by using the boundary integral equation technique. It is shown that, for both supercritical and subcritical flows, solutions depend on three parameters: (i) the Froude number, (ii) the magnitude of applied pressure distribution, and (iii) the span length of pressure distribution. For supercritical flows, there exist up to two solutions corresponding to the same value of Froude number for positive pressures and a unique solution for negative pressures. For subcritical flows, there are solutions with waves behind the applied pressure distribution. As the Froude number decreases, these waves when the Froude numbers approach the critical values.

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Effect of Extraction Methods on Flavoring Compounds and Antioxidant Activity of Extracts from Cinnamon (Cinnamomum cassia Blume) (추출방법이 육계피 추출물의 향기 성분과 항산화 활성에 미치는 영향)

  • Cha, Jaeyoon;Kim, Chong-Tai;Cho, Yong-Jin
    • Food Engineering Progress
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    • v.22 no.4
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    • pp.304-308
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    • 2018
  • The interest in and development of healthy foods and nutraceuticals have increased because of the trend for a health-oriented society. Cinnamon is used as a food ingredient as well as a herbal medicine because of its functional properties. In this study, flavoring compounds and antioxidative activities of cinnamon extracts were investigated with different extraction solvents and extraction methods. The contents of flavoring compounds such as coumarin, cinnamic acid, cinnamaldehyde, and cinnamyl alcohol were investigated. The contents of courmarin, cinnamic acid, and cinnamylaldehyde in 70% ethanol extract were higher than those in hot water and subcritical water extracts. The contents of courmarin, cinnamic acid, and cinnamaldehyde in subcritical water extract were higher than those in hot water extract, whereas the content of cinnamyl alcohol was lower. DPPH scavenging activity increased with increasing concentration of the extracts, and the 70% ethanol extract showed the highest antioxidant activity. The ascorbic acid content of the 70% ethanol extract was largest in the antioxidative activity measurement by FRAP analysis. The ascorbic acid contents of the hot water and subcritical water extracts were similar.

Saccharification of lignocellulosics by Supercritical Water (초임계수를 이용한 목질바이오매스의 당화 특성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Jo, Tae-Su;Han, Gyu-Sung;Choi, Don-Ha
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.38-45
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    • 2007
  • To characterize thermo-chemical feature of sugar conversion of woody biomass, poplar wood ($Populus\;alba{\times}glandulosa$) powder was treated with supercritical water system. Supercritical water treatment (SCWT) was performed for 60 seconds at different temperatures (subcritical zone 350; supercritical zone $300,\;400,\;425^{\circ}C$) under two pressures $230{\pm}10atm$ as well as $330{\pm}10atm$, respectively, using flow type system. After separation of solid residues from SCWT products, the monomeric sugars in aqueous part converted from poplar wood powder were quantitatively determined by high performance anionic exchange chromatography [HPAEC] equipped with PAD detector and Carbo Pac PA10 column. As the temperature treated increased, the degradation of poplar wood powder was enhanced and ca 83% of woody biomass was dissolved into the water at $425^{\circ}C$. However, the pressure didn't help the degradation of biomass components. At subcritical temperature range, xylose was first formed by degradation of xylan, which is main hemicellulose component in hardwood species, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical temperature. In the supercritical water system the maximum yield of monomeric sugars amounts to ca. 7.3% based on oven dried wood weight at $425^{\circ}C$.

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Wave Patterns Due to a Point Impulse Travelling over Free Surface of Water of Finite Depth

  • Lee, G.J.;Chung, Y.K.
    • Journal of Hydrospace Technology
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    • v.2 no.1
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    • pp.10-17
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    • 1996
  • If a point impulse travels over free surface of water of finite depth, surface waves consist of divergent waves. The crestlines of those divergent waves are short and end on the cusp line if the impulse travels at a subcritical speed. But the crestlines become infinitely long and there are no cusps if the impulse travels at a supercritical speed.

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Establishment and Application of Nuclear Criticality Safety Validation Methodology (핵임계 안전성 검증 방법론 정립 및 적용)

  • Lee, Seo Jeong;Cha, Kyoon Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.315-330
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    • 2018
  • A subcritical facility must ensure nuclear criticality safety under all circumstances. For this purpose, it is essential to have a procedure to validate that calculated values do not exceed upper subcritical limit (USL), determined by quantifying the bias and uncertainty. However, there are several validation methodologies of nuclear criticality safety and these can yield different USL. Therefore, it is necessary to analyze the validity of the methodologies to establish one methodology that can provide the most appropriate USL. In this study, two documents, a guide for validation of nuclear criticality safety calculational methodology (NUREG/CR-6698) and a criticality benchmark guide for light water reactor fuel in transport and storage package (NUREG/CR-6361), are compared and analyzed. In particular, the methodology in NUREG/CR-6361 is applied to the USLSTATS code. However, the analysis results show that the methodology in NUREG/CR-6698 is more appropriate, for several reasons. This is applied to decision of USL to design casks using SCALE code version 6.1.

Numerical anslysis of Transcritical Flow in Open Channels Using High-Resolution scheme I. : Model Development (고정확도 수치기법을 이용한 하천 천이류 해석 I. : 모형 개발)

  • Kim, Won;Han, Kun-Yeun
    • Journal of Korea Water Resources Association
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    • v.34 no.1
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    • pp.45-55
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    • 2001
  • Transcritical flow is a term intended to denote the existence of both supercritical and subcritical flows within a computational domain. The major problems that need to be addressed while modeling transcritical flows include handling the differing features of signal propagation in subcritical and supercritical flow regions and maintaining conservation. The present study proposes the implicit ENO method as a high-resolution scheme for transcritical flow. This implicit ENO scheme is based on the ENO method, a new class of uniformly high-order-accurate essentially non-oscillatory implicit scheme, which has the advantage of unconditional stability. The implicit ENO scheme has not been used for the transcritical flow in open channel until now. As a result of application to the hypothetical dam-break flow, the implicit ENO scheme was ploved to produce accurate results with good robustness even though in the case of verb strong shock wave.

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DESTRUCTION OF HUMIC MATTERS AND AMMONIA IN THE LANDFILL LEACHATE BY SUPERCRITICAL WATER OXIDATION

  • Kim, Y.K.;Ahn, J.S.;Leung, W.
    • Environmental Engineering Research
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    • v.11 no.6
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    • pp.311-317
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    • 2006
  • Feasibility of destroying synthetic and actual leachate containing humic acids and ammonia compounds by supercritical water oxidation (SCWO) was evaluated. In this study, destruction efficiencies of humic acids and ammonia respectively were investigated at various reaction temperatures and residence times under pressure a supercritical pressure (280 atm). To lower reaction temperature, chemical oxidants were used. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 that can withstand high temperature and pressure. Concentrations of humic acids and ammonia were measured using a $COD_{Cr}$ method and an ammonia selective electrode, respectively. The optimal destructive condition of humic acids in the presence of stoichiometric oxygen(air) was 3 min at $380^{\circ}C$, but the temperature could be lowered to subcritical region ($360^{\circ}C$) along with $H_2O_2$ as an oxidant. For ammonia, the optimal destructive condition with air was 5 min at $660^{\circ}C$, but it was possible to operate the process for 3 minutes at $550^{\circ}C$ or 2 min at $600^{\circ}C$ along with $H_2O_2$ as an oxidant. At 2 min and $550^{\circ}C$ along with $H_2O_2$ as an oxidant, humic and ammonia compounds in the actual leachate were easily destructed and the effluent quality met the Korea Standard Leachate Quality.

Optimum Conditions for Extracting Flavanones from Grapefruit Peels and Encapsulation of Extracts (자몽껍질 유래 플라바논의 최적 추출 및 기능성 소재 캡슐화)

  • Ko, Min-Jung;Kwon, Hye-Lim;Chung, Myong-Soo
    • Korean Journal of Food Science and Technology
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    • v.46 no.4
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    • pp.465-469
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    • 2014
  • The extraction of flavanones such as naringin, narirutin, naringenin, hesperidin, and hesperetin from grapefruit peels was performed using subcritical water extraction (SWE), hot water extraction, and conventional methods such as methanol and ethanol extraction. We analyzed the total flavanone content using high-performance liquid chromatography (HPLC) for each extracting method. Among the three methods, SWE was the optimal method with optimal operating conditions of $170^{\circ}C$ temperature and 10 min operating time. The maximum total flavanone extracted was $86.539{\pm}3.52mg/g$ grapefruit peels. Moreover, we treated the extracts with 60% ${\beta}$-cyclodextrin and then analyzed the surface structure of the encapsulated compounds by field emission-scanning electron microscopy (FE-SEM). The results indicated that the encapsulation in ${\beta}$-cyclodextrin improved solubilization, and the inclusion complex could serve as food supplements.

Protective effect of Capsosiphon fulvescens on oxidative stress-stimulated neurodegenerative dysfunction of PC12 cells and zebrafish larva models

  • Laxmi Sen Thakuri;Jung Eun Kim;Jin Yeong Choi;Dong Young Rhyu
    • Fisheries and Aquatic Sciences
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    • v.26 no.1
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    • pp.24-34
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    • 2023
  • Reactive oxygen species (ROS) at high concentrations induce oxidative stress, an imbalanced redox state that is a prevalent cause of neurodegenerative disorders. This study aimed to investigate the protective effect of Capsosiphon fulvescens (CF) extract on oxidative stress-induced impairment of cognitive function in models of neurodegenerative diseases. CF was extracted with subcritical water and several solvents and H2O2 (0.25 mM) or aluminum chloride (AlCl3; 25 µM) as an inducer of ROS was treated in PC12 neuronal cells and zebrafish larvae. All statistical analyses were performed using one-way analysis of variance and Dunnett's test using GraphPad Prism. H2O2 and AlCl3 were found to significantly induce ROS production in PC12 neuronal cells and zebrafish larvae. In addition, they strongly affected intracellular Ca2+ levels, antioxidant enzyme activity, brain-derived neurotrophic factor (BDNF) and tropomyosin receptor kinase B (TrkB) signaling, acetylcholinesterase (AChE) activity, and hallmarks of Alzheimer's disease. However, treatment of H2O2-induced PC12 cells or AlCl3-induced zebrafish larvae with CF subcritical water extract at 90℃ and CF water extract effectively regulated excessive ROS production, intracellular Ca2+ levels, and mRNA expression of superoxide dismutase, glutathione peroxide, glycogen synthase kinase-3 beta, β-amyloid, tau, AChE, BDNF, and TrkB. Our study suggested that CF extracts can be a potential source of nutraceuticals that can improve the impairment of cognitive function and synaptic plasticity by regulating ROS generation in neurodegenerative diseases.

Quantitative analysis method for zingiber officinale water extract using high-performance liquid chromatography

  • Mohd S. Md Sarip;Nik M.A. Nik Daud;Mohd A. Mohd Zainudin;Lokman H. Ibrahim;Syahrul A. Saidi;Zuhaili Idham;Adilah Anuar
    • Advances in materials Research
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    • v.13 no.3
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    • pp.233-241
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    • 2024
  • Quantitative analysis of the Zingiber Officinale sample using subcritical water extraction (SWE) was developed employing High-Performance Liquid Chromatography (HPLC) to bolster the advancement of this innovative green extraction process. This research focuses on three principal ginger bioactive compounds: 6-gingerol, 6-shagoal, and 10-gingerol. Various stages were undertaken to establish the quantitative analysis method, encompassing the optimisation of HPLC operating conditions and the formulation of standard calibration curves, yielding individual compound equations. A robust correlation within the calibration curve was achieved, exhibiting an r2 value of 0.9814 and an RSD of 5.00%. A simultaneous, swift, and dependable method was established with an injection time of 20 minutes and an 8-minute delay between injections, in contrast to the previous HPLC analysis requiring a 45-minute injection time for detecting and quantifying all components. Notably, no post-treatment was applied after the SWE process. This advancement allows for potential future online measurement of Zingiber Officinale bioactive compounds extracted using subcritical water extraction through this technology.