• Title/Summary/Keyword: Sub-stepping

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Electrodeposition of Gold on Fluorine-Doped Tin Oxide: Characterization and Application for Catalytic Oxidation of Nitrite

  • Rahman, Md. Mahbubur;Li, Xiao-Bo;Lopa, Nasrin Siraj;Lee, Jae-Joon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2072-2076
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    • 2014
  • Sub-micrometer size gold particles were electrodeposited on a transparent fluorine-doped tin oxide (FTO) from acetonitrile solution containing $AuCl_4{^-}$ and tetramethylammonium tetraflouroborate (TMATFB) for detecting $NO_2{^-}$. A series of two-electron ($2e^-$) and one-electron ($1e^-$) reductions of the $AuCl_4{^-}-AuCl_2{^-}-Au$ redox systems were observed at FTO and a highly stable and homogeneous distribution of Au on FTO (Au/FTO) was obtained by stepping the potential from 0 to -0.55 V (vs. Ag/$Ag^+$). The Au/FTO electrode exhibited sufficiently high catalytic activity toward the oxidation of $NO_2{^-}$ with a detection limit (S/N = 3) and sensitivity of 2.95 ${\mu}M$ and 223.4 ${\mu}A{\cdot}cm^{-2}{\cdot}mM^{-1}$, respectively, under optimal conditions. It exhibited an interference-free signal for $NO_2{^-}$ detection with excellent recoveries from real samples.

An Exploratory Study on Child Rearing Grandmothers: Based on the Interview of Grandmothers and Mothers (외조모의 손자녀 양육지원에 관한 탐색적 연구: 외조모와 어머니의 보고 중심으로)

  • Joo, EunSun;Kang, MyeongJin;Choi, MinJung
    • Korean Journal of Childcare and Education
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    • v.14 no.5
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    • pp.19-46
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    • 2018
  • Objective: The purpose this study is to explore the relationship between grandmothers and mothers when grandmothers take care of their grandchildren, and to understand the particular meaning of it. Methods: The Participants were 5 grandmothers who have supported or have experience in caring for their grandchildren, and their daughters(5 working mothers) who have entrusted their children to them. In-depth interviews were conducted and analysed by the phenomenological qualitative research method. Results: Seventeen sub-constructs and 5 constructs resulted in: (1) Motivation of grandmothers and mothers for taking care of grandchildren. (2) Pressure of grandmothers and satisfaction of mothers for the support. (3) Grandmothers stepping back and saying 'Not my child' and mothers saying 'It's my child' and thinking their influence is big. (4) Consistent sacrifice of grandmothers and mothers who cannot do the same. (5) Grandmothers feeling empty after caring for their grandchildren and mothers realizing their efforts. Conclusion/Implications: This study attempted to understand the relationship between grandmothers and mothers when grandmothers take care of their grandchildren from multi-perspectives. Through the findings, the need for developing healthy relationships and a caring environment for grandmothers and their grandchildren is stressed.

Frequency-Based Image Analysis of Random Patterns: an Alternative Way to Classical Stereocorrelation

  • Molimard, J.;Boyer, G.;Zahouani, H.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.3
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    • pp.181-193
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    • 2010
  • The paper presents an alternative way to classical stereocorrelation. First, 2D image processing of random patterns is described. Sub-pixel displacements are determined using phase analysis. Then distortion evaluation is presented. The distortion is identified without any assumption on the lens model because of the use of a grid technique approach. Last, shape measurement and shape variation is caught by fringe projection. Analysis is based on two pin-hole assumptions for the video-projector and the camera. Then, fringe projection is coupled to in-plane displacement to give rise to 3D measurement set-up. Metrological characterization shows a resolution comparable to classical (stereo) correlation technique ($1/100^{th}$ pixel). Spatial resolution seems to be an advantage of the method, because of the use of temporal phase stepping (shape measurement, 1 pixel) and windowed Fourier transform (in plane displacements measurement, 9 pixels). Two examples are given. First one is the study of skin properties; second one is a study on leather fabric. In both cases, results are convincing, and have been exploited to give mechanical interpretation.

Correlation Analysis on the Duration and CO2 Emission Following the Earth-work Equipment Combination (토공장비조합에 따른 공사기간 및 이산화탄소 배출량의 상관성 분석)

  • Kim, Byungsoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4D
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    • pp.603-611
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    • 2011
  • After Kyoto Protocol was adopted for green gas reduction, each nations are stepping up efforts to reduce $CO_2$ of a typical green gas. Construction industry also is trying $CO_2$ reduction with the techniques of two types which are software and hardware techniques. The software technique are Passive Design considered green gas emission and the environment impact assessment by LCA. The hardware techniques are adjustment of equipment system and development of eco- friendly material. But, it is nonexistent that a study related to $CO_2$ emission considered detail process in construction industry. This study analyzed the correlation of equipment combination, $CO_2$ emission and duration by calculate $CO_2$ emission follow to equipment combination on earth-work which is the process emitted most $CO_2$ among railway bedding construction.

Development of Automatic Optical Fiber Alignment System and Optimal Aligning Algorithm (자동 광 정렬시스템 및 최적 광 정렬알고리즘의 개발)

  • Um, Chul;Kim, Byung-Hee;Choi, Young-Seok
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.4
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    • pp.194-201
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    • 2004
  • Optical fibers are indispensable fer optical communication systems that transmit large volumes of data at high speed. But the aligning technology under the sub-micron accuracy is required for the precise axis adjustment and connection. For the purpose of precise alignment of the optical arrays, in this research, we have developed the 12-axis(with 8 automated axis and 4 manual axis) automatic optical fiber alignment system including the image processing-based searching system, the automatic loading system using the robot and the suction toot and the automatic UV bonding system. In order to obtain the sub-micron alignment accuracy, two 4-axis PC-based motion controllers and the two 50nm resolution 6-aixs micro-stage actuated by micro stepping motors are adopted. The fiber aligning procedure consists of two steps. Firstly, the optical wave guide and an input optical array are aligned by the 6-axis input micro-stage with the IR camera. The image processing technique is introduced to reduce primary manual aligning time and result in achieving the 50% decrease of aligning time. Secondly, the IR camera is replaced by the output micro-stage and a wave guide and two optical arrays are aligned simultaneously before the laser power intensity delivered to the optical powermeter reached the threshold value. When the aligning procedure is finished, the wave guide and arrays are W bonded. The automatic loading/unloading system is also introduced and the entire wave guide handing time is reduced significantly compared to the former commercial aligning system.

The New X-ray Induced Electron Emission Spectrometer

  • Yu.N.Yuryev;Park, Hyun-Min;Lee, Hwack-Ju;Kim, Ju-Hwnag;Cho, Yang-Ku;K.Yu.Pogrebitsky
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.5-6
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    • 2002
  • The new spectrometer for X-ray Induced Electron Emission Spectroscopy (XIEES) .has been recently developed in KRISS in collaboration with PTI (Russia). The spectrometer allows to perform research using the XAFS, SXAFS, XANES techniques (D.C.Koningsberger and R.Prins, 1988) as well as the number of techniques from XIEES field(L.A.Bakaleinikov et all, 1992). The experiments may be carried out with registration of transmitted through the sample x-rays (to investigate bulk samples) or/and total electron yield (TEY) from the sample surface that gives the high (down to several atomic mono-layers in soft x-ray region) near surface sensitivity. The combination of these methods together give the possibility to obtain a quantitative information on elemental composition, chemical state, atomic structure for powder samples and solids, including non-crystalline materials (the long range order is not required). The optical design of spectrometer is made according to Johannesson true focusing schematics and presented on the Fig.1. Five stepping motors are used to maintain the focusing condition during the photon energy scan (crystal angle, crystal position along rail, sample goniometer rail angle, sample goniometer position along rail and sample goniometer angle relatively of rail). All movements can be done independently and simultaneously that speeds up the setting of photon energy and allows the using of crystals with different Rowland radil. At present six curved crystals with different d-values and one flat synthetic multilayer are installed on revolver-type monochromator. This arrangement allows the wide range of x-rays from 100 eV up to 25 keV to be obtained. Another 4 stepping motors set exit slit width, sample angle, channeltron position and x-ray detector position. The differential pumping allows to unite vacuum chambers of spectrometer and x-ray generator avoiding the absorption of soft x-rays on Be foil of a window and in atmosphere. Another feature of vacuum system is separation of walls of vacuum chamber (which are deformed by the atmospheric pressure) from optical elements of spectrometer. This warrantees that the optical elements are precisely positioned. The detecting system of the spectrometer consists of two proportional counters, one scintillating detector and one channeltron detector. First proportional counter can be used as I/sub 0/-detector in transmission mode or by measuring the fluorescence from exit slit edge. The last installation can be used to measure the reference data (that is necessary in XANES measurements), in this case the reference sample is installed on slit knife edge. The second proportional counter measures the intensity of x-rays transmitted through the sample. The scintillating detector is used in the same way but on the air for the hard x-rays and for alignment purposes. Total electron yield from the sample is measured by channeltron. The spectrometer is fully controlled by special software that gives the high flexibility and reliability in carrying out of the experiments. Fig.2 and fig.3 present the typical XAFS spectra measured with spectrometer.

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Railbed Evaluation by using In-situ Penetration Test (원위치 관입실험기를 활용한 철도 노반 평가)

  • Kim, Ju-Han;Park, Jung-Hee;Yoon, Hyung-Koo;Koh, Tae-Hoon;Lee, Jong-Sub
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.261-267
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    • 2011
  • The test fit has commonly used for the evaluation of the railbed condition, and indirect methods by using the compressional wave are also studied. the direct evaluation method by penetration test has not been studied. For the measurement of in-situ cone tip resistance of the railbed with minimizing the disturbance of the upper railbed. the cone penetrometer with the helical type outer rod(CPH) was developed. The outer rod, which has helical screw, is penetrated through the gravel layer and provides the reaction force for cone penetration testing. the cone tip resistances are measured by the mini cone penetrometer, where diameter is 15mm. For the developing the mini cone, strain gauge installation, circuit configuration, penetration rates and calibration process are considered. For the easy penetration of the screw rod in the field, the reaction force stepping plate and guide column are arranged. The screw rod are penetrated through the gravel layer. And the mini cone was pushed into the subgrade railbed at the penetration rate of 1mm/sec. The penetration test shows that the cone tip resistance increases along the depth. In addition, the subgrade condition is evaluated. This study demonstrates that the CPH may be effectively used for the evaluation of subgrade method any damage of the gravel layer.

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A Study on the Classification and Application Element of Outdoor Biotop for Environment-friendly Community (친환경 주거를 위한 외부공간의 비오톱 유형 분류 및 적용 항목에 관한 연구)

  • Cho, Dong-Gil;Cho, Tong-Buhm
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.10 no.1
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    • pp.57-71
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    • 2007
  • While a concept on biotop or the urgency of its classification systems have been under discussion recently, this study aims to examine outdoor biotop classification systems for environment-friendly community. To this end, the feasibility of creating a biotop in the community and application elements were generated and biotops were classified and categorized. Then, elements that can be applied in consideration of traditional Korean techniques were generated and biotop classification systems and specific components in residential areas were reviewed. As for the result of this study, based on a preliminary draft prepared through literature review, considerations for biotop classification systems were taken into account. Then, based on classification criteria for biotop formats, biotop functions and biotop types, a second-tier classification system was developed. Criteria for biotop formats included surfaces, lines and points while criteria for biotop functions were large cores, small bases, corridors, stepping stones and ecological islands. Criteria for habitat types were divided to include natural forest, developed green areas, lacustrine wetland, palustrine wetland, shrubs, grasslands, linear habitats, vacant plots and practical green areas, which were sub-categorized. As for the biotop classification system, macro-classification divided biotops into three types-space, line and point-based on biotop formats. Meso-classification had five groups and micro-classification had 21 groups based on habitat types. Future studies should focus on the ecological features of each biotop categories generated in this study and their creation and management techniques to find many practical methods to create, protect and manage outdoor biotop for environment-friendly community.

A Study of Nitrous Oxide Decomposition using Calcium Oxide (Calcium Oxide를 이용한 N2O 분해에 관한 CO2의 영향 연구)

  • Paek, Jin-Young;Park, Yeong-Sung;Shun, Dowon;Bae, Dal-Hee
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.746-751
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    • 2002
  • Fluidized bed combustion is a coal combustion technology that can reduce both SOx and NOx emission; SOx is removed by limestone that is fed into the combustion chamber and the NOx is reduced by low temperature combustion in a fluidized bed combustor and air stepping, but $N_2O$ generation is quite high. $N_2O$ is not only a greenhouse gas but also an agent of ozone destruction in the stratosphere. The calcium oxide(CaO) is known to be a catalyst of $N_2O$ decomposition. This study of $N_2O$ decomposition reaction in fixed bed reactor packed over CaO bed has been conducted. Effects of parameters such as concentration of inlet $N_2O$ gas, reaction temperature, CaO bed height and effect of $CO_2$, NO, $O_2$ gas on the decomposition reaction have been investigated. As a result of the experiment, it has been shown that $N_2O$ decomposition reaction increased with the increasing fixed bed temperature. While conversion of the reaction was decreased with increasing $CO_2$ concentration. Also, under the present of NO, the conversion of $N_2O$ decomposition is decreased. From the result of kinetic study gained the heterogeneous reaction rate on $N_2O$ decomposition. In the case of $N_2O$ decomposition over CaO, heterogeneous reaction rate is. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$. In this study, it is found that the calcium oxide is a good catalyst of $N_2O$ decomposition.

Reforming Business Classification Systems of Merchants: A Case of S-Card's Customer Segmentation Strategy (S카드사의 가맹점 분류체계 정비를 통한 고객세분화 전략)

  • Park, Jin-Soo;Chang, Nam-Sik;Hwang, You-Sub
    • Information Systems Review
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    • v.10 no.3
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    • pp.89-109
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    • 2008
  • Korean card firms suffered harsh setbacks due to high credit defaults in 2002 and 2003, after issuing cards recklessly. Their key principle is changed to grow without damaging profitability and financial soundness. However, competition in the credit card market is heating up rapidly. Bank-affiliated card firms, having stronger sales networks and more capital than independent issuers, have increased their investments in card affiliates in a bid to develop new cash cows. Moreover, newly emerging independent card firms have waged fiercer campaigns to raise their credit card market share. In order to overcome these business conditions, S-card has settled on a strategy that focuses on stepping up marketing aimed at increasing charge card spending rather than credit card loans or cash lending services. Accordingly, S-card reformed the current business classification system of merchants, which was out-of-dated and originally built for the purpose of deciding merchant service fees only. They also drove customer segmentation planning to deliver the right customers to the right merchants. In this paper, we emphasize the problems of business classification systems of merchants with which most credit card firms have faced, and the need for reforming them not only to provide customer-tailored services but also to raise their business promotion excellence by reviewing S-card's process of customer segmentation.