• Nuclear Engineering and Technology
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• 제53권7호
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• pp.2289-2294
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• 2021

In the present study, an original spark plasma sintering-reactive synthesis (SPS-RS) method for minerallike ceramic materials based on SrAl₂Si₂O₈ feldspar-like skeleton structure was used for the first time, promising solid-state matrices for reliable immobilization of high-energy ⁹⁰Sr. The method is based on the "in-situ" reaction of a mixture of SrO, Al₂O₃ and SiO₂ oxides when heated by a unipolar pulsed current under compacting pressure. The phase and elemental composition structure were studied. The dynamics of the consolidation of the reaction mixture of oxides was studied in the range of 900-1200 ℃. The study found the temperature of the high-speed (minutes) SPS-RS formation of single-phase SrAl₂Si₂O₈ composition ceramic in the absence of intermediate reaction products with a relative density of up to 99.2% and compressive strength up to 145 MPa and a strontium leaching rate of 10^-4g/cm²·day.

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.635-636
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• 2006

• Nuclear Engineering and Technology
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• 제54권2호
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• pp.653-660
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• 2022

The interaction between UN and CdCl₂ in the LiCl-KCl molten eutectic was studied at 1023 K. The chlorination was monitored by sampling and recording the redox potential of the medium. At 1023 K the chlorination of UN with cadmium chloride in the molten LiCl-KCl eutectic proceeds completely and results in the formation of uranium chlorides. The melts of the LiCl-KCl-UCl₃ or LiCl-KCl-UCl₄ compositions can be obtained by the end of experiment depending on the presence of metallic cadmium in the reaction zone. The higher the concentration of the chlorinating agent, the faster the reaction rate. At [CdCl₂]/[UN] = 1.65 (10% excess) the reaction proceeds to completion in about 7.5 h. At [CdCl₂]/[UN] = 7 the complete chlorination takes 2.5-3 h.

• Nuclear Engineering and Technology
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• 제52권8호
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• pp.1756-1763
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• 2020

The paper studies spark plasma sintering (SPS) of industrially used UO₂-based fuel containing integral fuel burnable absorber (IFBA) of neutrons Gd₂O₃. Densification dynamics of pristine UO₂ powder and the one added with 2 and 8 wt% of Gd₂O₃ under ultrasonication in liquid has been studied under SPS conditions at 1050, 1250, and 1450 ℃. Effect of sintering temperature on phase composition as well as on O/U stoichiometry has been investigated for UO₂ SPS ceramics. Sintering of uranium dioxide added with Gd₂O₃ yields solid solution (U,Gd)O₂, which is isostructural to UO₂. SEM with EDX and metallography were implemented to analyze the microstructure of the obtained UO₂ ceramics and composite UO₂-Gd₂O₃ one, particularly, open porosity, defects, and Gd₂O₃ distribution were studied. Microhardness, compressive strength and density were shown to reduce after addition of Gd₂O₃. Obtained results prove the hypothesis on formation of stable pores in the system of UO₂-Gd₂O₃ due to Kirkendall effect that reduces sintering efficiency. The paper expands fundamental knowledge on pros and cons of fuel fabrication with IFBA using SPS technology.

• Nuclear Engineering and Technology
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• 제52권6호
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• pp.1164-1171
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• 2020

T-junction structures play an important role in nuclear power plant systems. Research on liquid entrainment is mostly based on small-scale branch pipes (d/D ≤ 0.2) and attention paid to large-scale branch pipes (0.33 < d/D < 1) is insufficient. Accordingly, this study implements a series of experiments on the liquid entrainment of T-junction with different angles (32.2°,47.9°,62.3°,90°) through a large-scale branch (d/D = 0.675). The onset liquid entrainment is related to the gas phase Froude number Fr_g, the dimensionless gas chamber height h_b/d and the branch pipe angle 𝜃. As Fr_g increases, h_b/d also rises. With a constant h_b/d, the onset liquid entrainment changes from droplets entrainment by the gas phase to that by the rising liquid film. The steady-state liquid entrainment is related to w_3g, h/d and 𝜃. With constant w_3g and h/d, the branch quality grows as the branch angle increases. With a certain h/d, the branch quality increases, as the w_3g number increases.

• Nuclear Engineering and Technology
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• 제52권1호
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• pp.123-134
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• 2020

The interaction between UN and CdCl₂ in the LiCl-KCl molten eutectic was studied at 773 K. The reaction was controlled by sampling the melt, as well as by analysis of the resulting precipitate. The process was shown to proceed according to several parallel reactions. The summary reaction was determined to have two stages: a fast one and a slow one. The 19-53% UN → UCl₃ conversion was obtained for the molar ratio of CdCl₂/UN = 1.22-14.9. The rest of UN converts into the precipitate of complex composition (UNCl + U₂N₃ + U₄N₇ + UN₂). The increase in the CdCl₂/UN molar ratio from 1.22 to 14.9 resulted in the decrease in duration of the first "fast" stage of the process from 18 h to 1 h.

• 한국재료학회지
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• 제32권5호
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• pp.258-263
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• 2022

Porous ceramics have the advantages of low density, low thermal conductivity, and excellent mechanical properties. Among porous ceramic manufacturing methods, the replica template method allows the easy manufacturing of porous filters with the highest porosity and pores of the desired size, but it also has the disadvantage that the resulting filters have low mechanical strength. To overcome this shortcoming, mullite (3Al₂O₃·2SiO₂) whiskers, which have excellent thermal stability and high mechanical strength, were introduced in porous ceramic structure. The mullite whiskers were synthesized using a composition of Al₂O₃, flyash and MoO₃. The morphologies and crystal structures of the mullite whiskers with MoO₃ contents were investigated in detail. When the porous ceramic with mullite whiskers was fabricated using 20 wt% MoO₃ catalyst the most uniform microstructure was obtained, and the mullite whiskers showed the highest aspect ratio of 47.03. The porosity and compressive strength of the fabricated porous ceramic were 82.12 % and 0.83 MPa, respectively.

• 호남수학학술지
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• 제42권1호
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• pp.37-48
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• 2020

We first define a new multiplication on triangular Banach algebras. Then we study amenability, weak amenability, biflatness and biprojectivity of these algebras.

• 대한화학회지
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• 제54권5호
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• pp.579-581
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• 2010

Solid silica supported ferric chloride ($SiO_2-FeCl_3$) 촉매를 이용하여 다양한 benzimidazoles의 one-step 합성을 수행하였으며, 합성 방법이 간단하며, 화합물의 분리가 용이하며, 반응시간이 짧다.

• Bulletin of the Korean Chemical Society
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• 제27권6호
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• pp.939-940
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• 2006