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Interaction of NpO+2 with Cl- in Na-Ca-Cl-type solutions at ionic strength of 6M: Effect of presence of Ca ion on interaction

  • Nagasaki, Shinya;Saito, Takumi;Tsushima, Satoru;Goguen, Jared;Yang, Tammy
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1778-1782
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    • 2017
  • The interaction of $NpO^+_2$ with $Cl^-$ was studied using visible-near-infrared spectroscopy in $NaCl-Ca-Cl_2-NaClO_4$, $NaCl-NaClO_4$, and $CaCl_2-NaClO_4$ solutions with ionic strength (I) of 6M. The spectra of $NpO^+_2$ around 980 nm varied with $Cl^-$ concentration in the $NaCl-CaCl_2-NaClO_4$ and $NaCl-NaClO_4$ solutions at [$Cl^-$] ${\geq}3.5M$, but not in the $CaCl_2-NaClO_4$ solution. Assuming the 1:1 interaction between $NpO^+_2$ and $Cl^-$, the apparent equilibrium constants at I = 6M were evaluated. The presence of $Ca^{2+}$ was found to destabilize overall interaction between $NpO^+_2$ and $Cl^-$. The observations were consistent with the density functional theory calculation.

The Current Status and Tasks of Future Directions in Korean Society of Sport Biomechanics[1] (한국운동역학회 현황과 발전방향 과제[1])

  • Kim, Eui-Hwan
    • Korean Journal of Applied Biomechanics
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    • v.16 no.2
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    • pp.175-192
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    • 2006
  • The purpose of this study was to analyze the current status and suggest tasks of future directions for development of the Korean Society of Sport Biomechanics(KSSB). KSSB was established in the 22th of Oct.,1988. It is one of the great National Society recognized by the Korean Research Foundation, and consists of almost 350 members over national Sport Biomechanists. Two roles-functions of KSSB are as follows; one is an Independent Society by KSSB, the other is a sub-Society under Korean Alliance for Health, Physical Education, Recreation and Dance(KAHPERD) run by 15 sub-Societies. The 2 great strategies toward all over the world of KSSB were Localization and Globalization. The grand four projects of KSSB in $2005{\sim}2006yrs$ are as followers: 1) The rationalization of organization-operating and decentralization, 2) The international levels of society, 3) The internationalizaton of quality of Korean Journal of Sport Biomechanics, and 4) The presentation award by quarterly and double-movements of members of KSSB. The tasks of future direction for development of KSSB are as followers : The localization and globalization of KSSB( see above as figure 4, table 12, 13, 14).

The Existing Types of Public and Private Actors for Managing The Rural Development Programs & Facilities in Japan (일본에 있어서 농촌지역개발주체의 존재형태와 변화방향에 관한 연구)

  • Yoon, Won-Keun
    • Journal of Agricultural Extension & Community Development
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    • v.18 no.3
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    • pp.665-691
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    • 2011
  • The implementation of an place-based rural policy requires changes in the intra-governmental relations and between the public and private sectors and civil society. Over the past decades, Japan has been increasingly devolving and decentralizing public responsibilities and resources to sub-national government levels. There is assumption that such transfers produce more efficiency in terms of public management and create better conditions for economic development. At the same time, these transfer respond to new expectations of citizens and civil society to participate more closely in the democratic decision-making process. Coordination is also needed at the local level to integrate sectoral approaches, to involve private partners and to achieve the appropriate geographic scale. Local public and private actors join a partnership and pool knowledge and resources. This type of local partnership is characterized by the participation of different actors, including municipalities, sub-regional government institution and development agencies. The participation of private actors(private firms, cooperatives, associations, non-profit organizations, farm organizations, other categories organizations, etc,) is also important.

A Meta-Analysis of the Correlation Effects between Coaching Leadership and Organizational Effectiveness (코칭리더십과 조직유효성과의 상관관계에 관한 메타분석)

  • Yoon, Sun-Young;Chae, Myung-Sin
    • Asia-Pacific Journal of Business
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    • v.9 no.3
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    • pp.117-137
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    • 2018
  • Lots of the studies about the relationship between coaching leadership and organizational effectiveness have been conducted and reported that coaching leadership is one of the main factors which impact organizational effectiveness. The purpose of this study was to synthesize the relationship between coaching leadership and organizational effectiveness. For that purpose, 32 correlation effect sizes from 25 studies were analyzed by the CMA (Comprehensive Meta-analysis) Program. The study calculated the overall effect size of the relationship between coaching leadership and organizational effectiveness. Then, it also calculated the effect size of the relationship between coaching leadership and each sub-variable of organizational effectiveness. The analysis results are as follows: First, the overall effect size about the relationship between coaching leadership and organizational effectiveness was .519, which means that coaching leadership has over lager relationship with organizational effectiveness. In addition, the effect sizes of sub-variables of the organization are .556 (organizational commitment) .542 (job satisfaction), 509 (organizational citizen behavior), and .401 (innovative behavior). The study tested the mediating effects of measurements, organizational size, types of publication, and published year. The result showed that only the measurement made significant differences among effect sizes of studies.

Bio-guided Isolation of Natural Iron Chelators from Mangifera indica Leaves and their Comparative Study to Desferal®

  • Suliman, Sara N.;ElNaggar, Mai H.;Elsbaey, Marwa;El-Gamil, Mohammed M.;Badria, Farid A.
    • Natural Product Sciences
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    • v.27 no.2
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    • pp.78-85
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    • 2021
  • Through bio-guided isolation, two natural iron chelators were isolated from Mangifera indica L. leaves, identified as mangiferin (1) and iriflophenone-3-C-𝛽-D-glucoside (2). Their iron-chelating activity was compared to that of Desferal® using bipyridyl assay and EDTA as a standard. Mangiferin showed the highest activity with IC50 value of 0.385 mM (162.85 ㎍/mL). Furthermore, two combinations of mangiferin with Desferal® (M-D) and iriflophenone-3-C-𝛽-D-glucoside (M-I) were evaluated. The results showed that mangiferin potentiated the iron chelation activity of Desferal® about 46%, also that M-I combination is a promising candidate formula for iron chelation therapy. In addition, mangiferin and Desferal-iron complexes were prepared and characterized by IR, UV, and Mass spectra to compare their mode of chelation to iron. Their structural stability was studied by DFT calculations. Furthermore, they displayed increased ABTS antioxidant activity when bound to iron as compared to their free form, which enhances their pharmacological importance.

Spanwise growth of coherent structures in turbulent pipe flow (난류 파이프 유동 내 응집 구조의 횡 방향 성장)

  • Ahn, Junsun;Lee, Jinyoung;Hwang, Jinyul
    • Journal of the Korean Society of Visualization
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    • v.19 no.2
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    • pp.26-31
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    • 2021
  • The spanwise growth of turbulence structures in turbulent pipe flow was investigated using the direct numerical simulation data of Re𝜏 = 544, 934 and 3008. Two-point correlations and pre-multiplied energy spectra of streamwise velocity fluctuations were examined along the spanwise direction. The arclength direction is defined as r𝛳, which is useful for an analogy with the spanwise direction for channels or boundary layers; here, r and 𝛳 are the radial distance from the core and the azimuthal angles, respectively. Both analyses showed that the arclength scales increased with increasing the wall-normal distance. It showed that the coherent structures were confined in the core region due to the crowding effect of a circular pipe geometry. The pipe flow simulation could describe a realistic geometrical flow along the azimuthal direction, unlike the simulations of turbulent channel or boundary layer flow using periodic boundary conditions along the spanwise direction. The present results provided the spanwise organization of energy-containing motions over a broad range of scales in turbulent pipe flow.

Greenhouse Gas Emission Analysis by LNG Fuel Tank Size through Life Cycle

  • Park, Eunyoung;Choi, Jungho
    • Journal of Ocean Engineering and Technology
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    • v.35 no.6
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    • pp.393-402
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    • 2021
  • As greenhouse gas emissions from maritime transport are increasing, the International Maritime Organization is continuously working to strengthen emission regulations. Liquefied natural gas (LNG) fuel is less advantageous as a point of CO2 reduction due to the methane leakage that occurs during the bunkering and operation of marine engines. In this study, greenhouse gas emissions from an LNG-fueled ship were analyzed from the perspective of the life cycle. The amount ofmethane emission during the bunkering and operation procedures with various boil-off gas (BOG) treatment methods and gas engine specifications was analyzed by dynamic simulation. The results were also compared with those of other liquid fuel engines. As a result, small LNG-fueled ships without a BOG treatment facility emitted 32% more greenhouse gas than ships utilizing marine gas oil or heavy fuel oil. To achieve a greenhouse gas reduction via a BOG treatment method, a gas combustion unit or re-liquefaction system must be mounted, which results in a greenhouse gas reduction effect of about 25% and 30%. As a result of comparing the amount of greenhouse gas generated according to the BOG treatment method used with each tank size from the perspective of the operating cycle with the amounts from using existing marine fuels, the BOG treatment method showed superior effects of greenhouse gas reduction.

Corrosion Characteristics of St37.4 Carbon Steel for Ship Fuel Pipe with Ammonia Concentration (선박 연료배관용 St37.4 탄소강의 암모니아 농도에 따른 부식 특성)

  • Do-Bin, Lee;Seung-Jun, Lee
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.514-524
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    • 2022
  • Carbon emissions from fuel consumption have been pointed by scientists as the cause of global warming. In particular, fossil fuels are known to emit more carbon when burned than other types of fuels. In this regard, International Maritime Organization has announced a regulation plan to reduce carbon dioxide emissions. Therefore, recently, Liquefied Natural Gas propulsion ships are responding to such carbon reduction regulation. However, from a long-term perspective, it is necessary to use carbon-free fuels such as hydrogen and ammonia. Nitrogen oxides might be generated during ammonia combustion. There is a possibility that incompletely burned ammonia is discharged. Therefore, rather than being used as a direct fuel, Ammonia is only used to reduce NOX such as urea solution in diesel vehicle Selective Catalyst Reduction. Currently, LPG vehicle fuel feed system studies have evaluated the durability of combustion injectors and fuel tanks in ammonia environment. However, few studies have been conducted to apply ammonia as a ship fuel. Therefore, this study aims to evaluate corrosion damage that might occur when ammonia is used as a propulsion fuel on ships.

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

  • Kharistya Rozana;Ariyani Kusuma Dewi;Herry Poernomo;Won-Chun Oh;Karna Wijaya
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.247-253
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    • 2024
  • The separation of zirconium and hafnium using tributyl phosphate (TBP)-Dodecane extractants in nitric acid medium was performed. Zirconium oxychloride, used as extraction feed, was obtained from the synthesis of Kalimantan zircon sand concentrate smelted using NaOH. The extraction process was carried out by dissolving chloride-based metals in nitric acid media in the presence of sodium nitrate using TBP-Dodecane as an extractant. Some of the extraction parameters carried out in this study include variations in organic phase and aqueous phase (O/A), variations in contact time, and variations in nitric acid concentration. Extraction was carried out using a mechanical shaker according to the parameter conditions. X-ray fluorescence (XRF) was used for elemental (Zr and Hf) composition analysis of the aqueous solution. The results showed that zirconium was separated from hafnium at optimum conditions with an organic/aqueous ratio of 1:5, contact time of 75 min, and an HNO3 concentration of 7 M. The resulting separation factor of zirconium and hafnium using TBP-Dodecane was 14.4887.

Current Status of Air Pollutants from Ships and Reduction Technologies (선박 기인 대기오염물질 현황 및 저감 기술 소개)

  • Jun-Seong Park;Seung-Ho Ham;Da-yeong Kang;Hee-Yeon Park;Jongkwan Park
    • Journal of the Society of Naval Architects of Korea
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    • v.61 no.2
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    • pp.135-142
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    • 2024
  • There is a lot of concern around the world about air pollution from ships. The majority of air pollution from ships comes from fuel combustion. The combustion process produces various air pollutants such as carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM), each of which has adverse effects on people and is a major environmental problem. To prevent this, the International Maritime Organization (IMO) has strengthened the regulation of pollutant emissions through the Convention for the Prevention of Marine Pollution. This paper discusses the types of air pollutants emitted by ships, their current status, and the latest technologies to reduce emissions of NOx and SOx.