• Journal of Sensor Science and Technology
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• v.29 no.4
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• pp.215-219
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• 2020

MnCo₂S₄/CoS₂ electrode with highly accessible electroactive sites is prepared using the hydrothermal method. The electrode exhibits an areal capacitance of 0.75 Fcm^-2 at 6 mAcm^-2 in 1 M KOH. The capacitance is further increased to 2.06 Fcm^-2 by adding K₃Fe(CN)₆ and K₄Fe(CN)₆ (a redox couple) to KOH. This increment is associated with the redox-active properties of cobalt and manganese transition metals, as well as the ion pair of [Fe(CN)₆]^-3/[Fe(CN)₆]^-4. The capacitance retention of the MnCo₂S₄/CoS₂ electrode is 87.5% for successive 4000 charge-discharge cycles at 10 mAcm^-2 in a composite electrolyte system of KOH and ferri/ferrocyanide. The capacitance enhancement is supported by the lowest equivalent series resistance (0.62 Ωcm^-2) of MnCo₂S₄/CoS₂ in the presence of redox additive couple compared with the bare KOH electrolyte.

• Journal of Institute of Control, Robotics and Systems
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• v.9 no.11
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• pp.868-873
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• 2003

$H_{\infty}$ control has been applied to the design of practical control systems widely because of its robustness. It can minimize $H_{\infty}$ norm of the transfer function between the desired output and the disturbances. The SMC(Sliding Mode Control) is more robust and give the better performance than the $H_{\infty}$ control if the matching condition is satisfied. A controller which can have the advantages of $H_{\infty}$ control and the SMC is proposed to add the robustness of the SMC to the $H_{\infty}$ controller. Its design is based on the augmented system of which dynamics have one higher order than that of the original system and has the same dynamic as the desired system in spite of uncertainties. The dynamic of proposed sliding surface is the same dynamic as the system controlled by $H_{\infty}$ controller without the uncertainties which satisfy the matching condition.

• Korean Journal of Materials Research
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• v.19 no.11
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• pp.613-618
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• 2009

We designed new compositions for lead free and low temperature sealing glass frit of $ZnO-V_2O_5-P_2O_5$ system, which can be used for PDP (Plasma Display Panel) or other electronic devices. The $ZnO-V_2O_5-P_2O_5$ system can be used as a sealing material at temperatures even lower than 430$^{\circ}C$. This system, however, showed lower bonding strength with glass substrate compared to commercialized Pb based sealing materials. So, we added $TiO_2$ as a promoter for bonding strength. We examined the effect of $TiO_2$ addition on sealing behaviors of $ZnO-V_2O_5-P_2O_5$ glasses with the data for flow button, wetting angle, temporary & permanent residual stress of glass substrate, EPMA analysis of interface between sealing materials and glass substrate, and bonding strength. As a result, sealing characteristics of $ZnO-V_2O_5-P_2O_5$ system glasses were improved with $TiO_2$ addition, but showed a maximum value at 5 mol% $TiO_2$ addition. The reason for improved bonding characteristics was considered to be the chemical interaction between glass substrate and sealing glass, and structural densification of sealing glass itself.

• Journal of Powder Materials
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• v.16 no.4
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• pp.291-295
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• 2009

The electromagnetic wave absorption sheets were fabricated by mixing of $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline soft magnetic powder, charcoal powder and polymer based binder. The complex permittivity, complex permeability, and scattering parameter have been measured using a network analyzer in the frequency range of 10 MHz$\sim$10 GHz. The results showed that complex permittivity of sheets was largely dependent on the frequency and the amount of charcoal powder : The permittivity was improved up to 100 MHz, however the value was decreased above 1 GHz. The power loss of electromagnetic wave absorption data showed almost the same tendency as the results of complex permittivity. However, the complex permeability was not largely affected by the frequency, and the values were decreased with the addition of charcoal powder. Based on the results, it can be summarized that the addition of charcoal powder was very effective to improve the EM wave absorption in the frequency range of 10 MHz$\sim$1 GHz.

• Korean Journal of Remote Sensing
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• v.40 no.1
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• pp.1-8
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• 2024

Busan is the 6th largest port city in the world, where nitrogen dioxide (NO₂) emissions from transportation and port industries are significant. This study aims to assess the NO₂ products of the Geostationary Environment Monitoring Spectrometer (GEMS) over Busan using ground-based instruments (i.e., surface in-situ network and Pandora). The GEMS vertical column densities of NO₂ showed reasonable consistency in the spatiotemporal variations, comparable to the previous studies. The GEMS data showed a consistent seasonal trend of NO₂ with the Korea Ministry of Environment network and Pandora in 2022, which is higher in winter and lower in summer. These agreements prove the capability of the GEMS data to monitor the air quality in Busan. The correlation coefficient and the mean bias error between the GEMS and Pandora NO₂ over Busan in 2022 were 0.53 and 0.023 DU, respectively. The GEMS NO₂ data were also positively correlated with the ground-based in-situ network with a correlation coefficient of 0.42. However, due to the significant spatiotemporal variabilities of the NO₂, the GEMS footprint size can hardly resolve small-scale variabilities such as the emissions from the road and point sources. In addition, relative biases of the GEMS NO₂ retrievals to the Pandora data showed seasonal variabilities, which is attributable to the air mass factor estimation of the GEMS. Further studies with more measurement locations for longer periods of data can better contribute to assessing the GEMS NO₂ data. Reliable GEMS data can further help us understand the Asian air quality with the diurnal variabilities.

• Korean Journal of Remote Sensing
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• v.38 no.6_1
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• pp.1191-1205
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• 2022

Particulate matter(PM) among air pollutants with complex and widespread causes is classified according to particle size. Among them, PM_2.5 is very small in size and can cause diseases in the human respiratory tract or cardiovascular system if inhaled by humans. In order to prepare for these risks, state-centered management and preventable monitoring and forecasting are important. This study tried to predict PM_2.5 in Seoul, where high concentrations of fine dust occur frequently, using two ensemble models, random forest (RF) and extreme gradient boosting (XGB) using 15 local data assimilation and prediction system (LDAPS) weather-related factors, aerosol optical depth (AOD) and 4 chemical factors as independent variables. Performance evaluation and factor importance evaluation of the two models used for prediction were performed, and seasonal model analysis was also performed. As a result of prediction accuracy, RF showed high prediction accuracy of R² = 0.85 and XGB R² = 0.91, and it was confirmed that XGB was a more suitable model for PM_2.5 prediction than RF. As a result of the seasonal model analysis, it can be said that the prediction performance was good compared to the observed values with high concentrations in spring. In this study, PM_2.5 of Seoul was predicted using various factors, and an ensemble-based PM_2.5 prediction model showing good performance was constructed.

• Journal of Powder Materials
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• v.29 no.2
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• pp.110-117
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• 2022

The grain growth behavior in the (1-x)K_0.5Na_0.5NbO₃-xCaZrO₃ (KNNCZ-x) system is studied as a function of the amount of CZ and grain shape. The (1-x)K_0.5Na_0.5NbO₃-xCaZrO₃ (KNNCZ-x) powders are synthesized using a conventional solid-state reaction method. A single orthorhombic phase is observed at x = 0 - 0.03. However, rhombohedral and orthorhombic phases are observed at x = 0.05. The grain growth behavior changes from abnormal grain growth to the suppression of grain growth as the amount of CaZrO₃ (CZ) increases. With increasing CZ content, grains become more faceted, and the step-free energy increases. Therefore, the critical growth driving force increases. The grain size distribution broadens with increasing sintering time in KNNCZ-0.05. As a result, some large grains with a driving force larger than the critical driving force for growth exhibit abnormal grain growth behavior during sintering. Therefore, CZ changes the grain growth behavior and microstructure of KNN. Grain growth at the faceted interface of the KNNCZ system occurs via two-dimensional nucleation and growth.

• Journal of Advanced Engineering and Technology
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• v.6 no.2
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• pp.125-129
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• 2013

In the pyrochemcial process of spent nuclear fuel, it is necessary to separate rare earth nuclides from LiCl-KCl eutectic waste salt for radioactive waste reduction. This paper presents the phosphorylation of neodymium chloride in LiCl-KCl-NdCl₃ system using Li₃PO₄-K₃PO₄ as a phosphorylation agent in a chemical reactor with pitched blade impellers. The phosphorylation test was performed changing operation temperature, stirring rate, and amount of phosphorylation agent. Neodymium chloride was effectively converted into neodymium phosphate (NdPO₄). It was confirmed that more than 99 wt% of neodymium can be separated from LiCl-KCl-NdCl₃ system using a phosphorylation method l

• Korean Journal of Remote Sensing
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• v.35 no.6_3
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• pp.1187-1195
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• 2019

We, for the first time, developed a Raman lidar system which can remotely detect surface CO₂ volume mixing ratio (VMR). The Raman lidar system consists of the Nd: YAG laser of wavelength 355 nm with 80 mJ, an optical receiver, and detectors. Indoor CO₂ cell measurements show that the accuracy of the Raman lidar system is calculated to be 99.89%. We carried out the field measurement using our Raman lidar at Pukyong National University over a seven-day period in October 2019. The results show good agreement between CO₂ VMRs measured by the Raman lidar (CO₂ Raman Lidar) and those measured by in situ instruments (CO₂ In situ) which located 300 m and 350 m away from the Raman lidar system. The correlation coefficient (R), mean absolute error (MAE), and root mean square error (RMSE) between CO₂ In situ and CO₂ Raman Lidar are 0.67, 2.78 ppm, and 3.26 ppm, respectively.

• Journal of Environmental Health Sciences
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• v.47 no.5
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• pp.410-424
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• 2021

Background: Subway stations have the characteristics of being located underground and are a representative public-use facility used by an unspecified number of people. As concerns about indoor air quality (IAQ) increase, various management measures are being implemented. However, there are few systematic studies and cases of long-term continuous measurement of underground station air quality. Objectives: The purpose of this study is to analyze changes and factors influencing IAQ in subway stations through real-time continuous long-term measurement using IoT-based IAQ sensing equipment, and to evaluate the IAQ improvement effect of a bio-filter system. Methods: The IAQ of a subway station in Seoul was measured using IoT-based sensing equipment. A bio-filter system was installed after collecting the background concentrations for about five months. Based on the data collected over about 21 months, changes in indoor air quality and influencing factors were analyzed and the reduction effect of the bio-filter system was evaluated. Results: As a result of the analysis, PM₁₀, PM_2.5, and CO₂ increased during rush hour according to the change in the number of passengers, and PM₁₀ and PM_2.5 concentrations were high when a PM warning/watch was issued. There was an effect of improving IAQ with the installation of the bio-filter system. The reduction rate of a new-bio-filter system with improved efficiency was higher than that of the existing bio-filter system. Factors affecting PM_2.5 in the subway station were the outdoor PM_2.5, platform PM_2.5, and the number of passengers. Conclusions: The IAQ in a subway station is affected by passengers, ventilation through the air supply and exhaust, and the spread of particulate matter generated by train operation. Based on these results, it is expected that IAQ can be efficiently improved if a bio-filter system with improved efficiency is developed in consideration of the factors affecting IAQ and proper placement.