• 제목/요약/키워드: Structure refinement

검색결과 321건 처리시간 0.022초

Synthesis and Characterization of Air Stable σ-Bonded ortho-carborane Manganese Metal Complexes $1-[Mn(CO)_5]-2-R-1,2-closo-(σ-C_2B_{10}H_{10}$ and Their Conversion to the Stable ortho-carborane Substituted Fischer-type Carbene Compexes 1-[(CO

  • 김세진;김유혁;고재정;강상욱
    • Bulletin of the Korean Chemical Society
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    • 제16권7호
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    • pp.634-641
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    • 1995
  • The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

융합 인덱싱 방법에 의한 조인 쿼리 성능 최적화 (Join Query Performance Optimization Based on Convergence Indexing Method)

  • 짜오티엔이;이용주
    • 한국전자통신학회논문지
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    • 제16권1호
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    • pp.109-116
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    • 2021
  • RDF(Resource Description Framework) 데이터 구조는 그래프로 모델링하기 때문에, 관계형 데이터베이스와 XML 기술의 기존 솔루션은 RDF 모델에 바로 적용하기 어렵다. 우리는 링크 데이터를 더욱 효과적으로 저장하고, 인덱스하고, 검색하기 위해 융합 인덱싱 방법을 제안한다. 이 방법은 HDD(Hard Disk Drive) 와 SSD(Solid State Drive) 디바이스에 기반한 하이브리드 스토리지 시스템을 사용하고, 불필요한 데이터를 필터하고 중간 결과를 정제하기 위해 분리된 필터 및 정제 인덱스 구조를 사용한다. 우리는 3개의 표준 조인 검색알고리즘에 대한 성능 비교를 수행했는데, 실험 결과 제안된 방법이 Quad와 Darq와 같은 다른 기존 방법들에 비해 뛰어난 성능을 보인다.

Mesh Stability Study for the Performance Assessment of a Deep Geological Repository Using APro

  • Hyun Ho Cho;Hong Jang;Dong Hyuk Lee;Jung-Woo Kim
    • 방사성폐기물학회지
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    • 제21권2호
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    • pp.283-294
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    • 2023
  • APro, developed in KAERI for the process-based total system performance assessment (TSPA) of deep geological disposal systems, performs finite element method (FEM)-based multiphysics analysis. In the FEM-based analysis, the mesh element quality influences the numerical solution accuracy, memory requirement, and computation time. Therefore, an appropriate mesh structure should be constructed before the mesh stability analysis to achieve an accurate and efficient process-based TSPA. A generic reference case of DECOVALEX-2023 Task F, which has been proposed for simulating stationary groundwater flow and time-dependent conservative transport of two tracers, was used in this study for mesh stability analysis. The relative differences in tracer concentration varying mesh structures were determined by comparing with the results for the finest mesh structure. For calculation efficiency, the memory requirements and computation time were compared. Based on the mesh stability analysis, an approach based on adaptive mesh refinement was developed to resolve the error in the early stage of the simulation time-period. It was observed that the relative difference in the tracer concentration significantly decreased with high calculation efficiency.

A CONSTRUCTION OF COMMUTATIVE NILPOTENT SEMIGROUPS

  • Liu, Qiong;Wu, Tongsuo;Ye, Meng
    • 대한수학회보
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    • 제50권3호
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    • pp.801-809
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    • 2013
  • In this paper, we construct nilpotent semigroups S such that $S^n=\{0\}$, $S^{n-1}{\neq}\{0\}$ and ${\Gamma}(S)$ is a refinement of the star graph $K_{1,n-3}$ with center $c$ together with finitely many or infinitely many end vertices adjacent to $c$, for each finite positive integer $n{\geq}5$. We also give counting formulae to calculate the number of the mutually non-isomorphic nilpotent semigroups when $n=5$, 6 and in finite cases.

구조물 주변의 Stokes 흐름에 대한 적응적 유한요소 해석을 위한 변절점 요소 (Variable-Node Element for Adaptive Finite Element Analysis of Stokes Flow around Structure)

  • 최창근;유원진;정근영
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1996년도 가을 학술발표회 논문집
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    • pp.168-175
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    • 1996
  • This paper deals with the variable-node element for fluid flow and the adaptive h-version mesh refinement algorithm. The transient element has been formulated by the Galerkin approach in which the pressure term is replaced with the penalty function. The present element having variable mid-side node and is suitable for constructing a locally refined mesh avoiding the use of the highly distorted elements. A modified Gauss quadrature is needed to integrate the element matrices to solve the trouble associated with the discontinuity of derivatives of shape functions. Several numerical examples show that the proposed element can be effectively used in the h-version adapt ive mesh refinement

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비정렬 격자계에서 고차정확도 불연속 갤러킨 기법을 이용한 블레이드-와류 간섭 현상 모사 (HIGH-ORDER ACCURATE SIMULATIONS OF BLADE-VORTEX INTERACTION USING A DISCONTINUOUS GALERKIN METHOD ON UNSTRUCTURED MESHES)

  • 이희동;권오준
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.57-70
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    • 2008
  • A high-order accurate Euler flow solver based on a discontinuous Galerkin finite-element method has been developed for the numerical simulations of blade-vortex interaction phenomena on unstructured meshes. A free vortex in freestream was investigated to assess the vortex-preserving property and the accuracy of the present flow solver. Blade-vortex interaction problems in subsonic and transonic freestreams were simulated by adopting a multi-level solution-adaptive dynamic mesh refinement/coarsening technique. The results were compared with those of other numerical and experimental methods. It was shown that the present discontinuous Galerkin flow solver can preserve the vortex structure for significantly longer vortex convection time and can accurately capture the complex unsteady blade-vortex interaction flows, including generation and propagation of acoustic waves.

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비정렬 격자계에서 고차정확도 불연속 갤러킨 기법을 이용한 블레이드-와류 간섭 현상 모사 (HIGH-ORDER ACCURATE SIMULATIONS OF BLADE-VORTEX INTERACTION USING A DISCONTINUOUS GALERKIN METHOD ON UNSTRUCTURED MESHES)

  • 이희동;권오준
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.57-70
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    • 2008
  • A high-order accurate Euler flow solver based on a discontinuous Galerkin finite-element method has been developed for the numerical simulations of blade-vortex interaction phenomena on unstructured meshes. A free vortex in freestream was investigated to assess the vortex-preserving property and the accuracy of the present flow solver. Blade-vortex interaction problems in subsonic and transonic freestreams were simulated by adopting a multi-level solution-adaptive dynamic mesh refinement/coarsening technique. The results were compared with those of other numerical and experimental methods. It was shown that the present discontinuous Galerkin flow solver can preserve the vortex structure for significantly longer vortex convection time and can accurately capture the complex unsteady blade-vortex interaction flows, including generation and propagation of acoustic waves.

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고강도 엔진밸브 스프링강 선재 저온조직 발생방지 선재압연 기술 (Controlled Cooling Technical of High Tensile Valve Spring Wire Rod)

  • 김경원;장용권;임규환;서일권
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1999년도 제3회 압연심포지엄 논문집 압연기술의 미래개척 (Exploitation of Future Rolling Technologies)
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    • pp.172-179
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    • 1999
  • As the martensite structure cause fracture failure during drawing from 5.5mm rod to 3.05mm dia. wire without additional heat treatment, the optium cooling condition to inhibit the occurrence of martensite was investigated. In order to get SAE9254+V quality, the effects of alloying element, vanadium on the mechanical properties were investigated. Based upon CCT and TTT curves and the results form cooling test in mill, optimun cooling was found in the condition of the laying head temp of 780$^{\circ}C$ and of the conveyor speed at 0.15m/sec with the whole cover closed. The wire rods produced under the condition showed the best mechanical properties of 120kg/$\textrm{mm}^2$ in TS and 50% in RA, having an excellent drawability. In vanadium added steels, tensile strength was improved without degrading elongation and charpy impact value. That means the strengthening by vanadium is mainly due to the grain refinement by the fine precipitates during tempering process.

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Al-7Si 합급의 결정립 미세화에 미치는 TiC 첨가의 영향 (Study on Grain Refinement of Al-7Si Based Alloys with TiC)

  • 한윤성;최창옥
    • 한국주조공학회지
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    • 제23권2호
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    • pp.63-68
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    • 2003
  • Al-Ti-C grain refiner form a relatively new alternative to the existing class of Al-Ti-B type grain refiners for achieving fine equiaxed structures in aluminum alloys during casting and solidification. The present study was carried out to investigate the influence of Al-Ti-C master alloys on the grain structure of Al-7Si alloys. The present study also investigates the relationship between grain refining efficiency and concentrations of Fe and Si in hypo-eutectic Al-Si alloys using Al-3Ti-0.13C master alloys. It is found that several parameters affect significantly the grain refining performance in silumin alloys. The present study reports the influence of various parameters such as alloy content, master alloy addition level, melt holding time and superheat on the grain refining efficiency in Al-7Si alloys.

적응적 유한요소를 이용한 박스형 구조물의 좌굴해석 (Buckling Analysis of Box-typed Structures using Adaptive Finite Elements)

  • 송명관;김선훈
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2007년도 정기 학술대회 논문집
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    • pp.271-274
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    • 2007
  • The finite element linear buckling analysis of folded plate structures using adaptive h-refinement methods is presented in this paper. The variable-node flat shell element used in this study possesses the drilling D.O.F. which, in addition to improvement of the element behavior, permits an easy connection to other elements with six degrees of freedom per node. The Box-typed structures can be analyzed using these developed flat shell elements. By introducing the variable node elements some difficulties associated with connecting the different layer patterns, which are common in the adaptive h-refinement on quadrilateral mesh, can be overcome. To obtain better stress field for the error estimation, the super-convergent patch recovery is used. The convergent buckling modes and the critical loads associated with these modes can be obtained.

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