• Title/Summary/Keyword: Structural Conversion

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Structural Analysis and Characterization of PZT Fiber Fabricated by Electrospinning (Electrospinning법으로 제조된 PZT 섬유의 구조분석 및 특성평가)

  • Park, Chun Kil;Yun, Ji Sun;Jeong, Young Hun;Nam, Joong-Hee;Cho, Jeong Ho;Paik, Jong-Hoo;Jeong, Dae Young
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.466-469
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    • 2013
  • Currently, piezoelectric ceramics are being applied in various fields, such as ultrasonic sensors, vibration devices, sound filters, and various energy conversion devices. Flexible piezoelectric ceramics are widely studied in an effort to mitigate the disadvantages of their brittle and inductile properties. Structural damage to piezoelectric fibers is much less than that to thin films when piezoelectric fibers are twisted or bent. Therefore, stretchable devices can be fabricated if piezoelectric fibers are obtained using an elongated substrate. In this study, sintering processes of PZT ($Pb(Zr_{0.53}Ti_{0.47})O_3$) fibers prepared by electrospinning were optimized through the TGA and XRD analyses. The crystal structure and microstructure of the piezoelectric fibers were investigated by XRD, FE-SEM and TEM.

Structural Design of a 750kW Composite Wind Turbine Blade (750kW급 풍력발전기용 복합재 블레이드의 구조설계)

  • Jung C.K.;Park S.H.;Han K.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.18-21
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    • 2004
  • A GFRP based composite blade was developed for a 750kW wind energy conversion system of type class I. The blade sectional geometry was designed to have a general shell-spar structure. The load cases specified in the IEC61400-1 international specification were considered. For withstanding all relevant extreme loads, the structural analysis for the complete blade was performed using a commercial FEM code. The static load carrying capacity, buckling stability, blade tip deflection and natural frequencies at various rotational speeds were evaluated to satisfy the strength requirements in accordance with the IEC61400-1 and GL Regulations. For designing a lightweight blade, the thickness and the lay-up pattern of the skin-foam sandwich structures were optimized iteratively using the DOT program T-bolts were used for joining the blade root and the hub, which were modeled using a 3D FE volume model. In order to confirm the safety of the root connection, the static stresses of the thick root laminate and the steel. bolts were predicted by taking account of the bolt pretension and the root bending moments. The calculated stresses were compared with the material strengths.

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Crystal Structure and Molecular Mechanism of Phosphotransbutyrylase from Clostridium acetobutylicum

  • Kim, Sangwoo;Kim, Kyung-Jin
    • Journal of Microbiology and Biotechnology
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    • v.31 no.10
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    • pp.1393-1400
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    • 2021
  • Acetone-butanol-ethanol (ABE) fermentation by the anaerobic bacterium Clostridium acetobutylicum has been considered a promising process of industrial biofuel production. Phosphotransbutyrylase (phosphate butyryltransferase, PTB) plays a crucial role in butyrate metabolism by catalyzing the reversible conversion of butyryl-CoA into butyryl phosphate. Here, we report the crystal structure of PTB from the Clostridial host for ABE fermentation, C. acetobutylicum, (CaPTB) at a 2.9 Å resolution. The overall structure of the CaPTB monomer is quite similar to those of other acyltransferases, with some regional structural differences. The monomeric structure of CaPTB consists of two distinct domains, the N- and C-terminal domains. The active site cleft was formed at the interface between the two domains. Interestingly, the crystal structure of CaPTB contained eight molecules per asymmetric unit, forming an octamer, and the size-exclusion chromatography experiment also suggested that the enzyme exists as an octamer in solution. The structural analysis of CaPTB identifies the substrate binding mode of the enzyme and comparisons with other acyltransferase structures lead us to speculate that the enzyme undergoes a conformational change upon binding of its substrate.

Facile and Clean Synthetic Route to Non-Layered Two-Dimensional ZIF-67 Nanosheets

  • Choi, Chang-Ho
    • Clean Technology
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    • v.26 no.4
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    • pp.257-262
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    • 2020
  • Two-dimensional (2D) metal organic framework (MOF) nanosheets (NSs) have recently gained considerable interest owing to their structural advantages, such as large surface area and exposed active sites. Two different types of 2D MOF NSs have been reported, including inherently layered MOFs and non-layered ones. Although several studies on inherently layered 2D MOFs have been reported, non-layered 2D MOFs have been rarely studied. This may be because the non-layered MOFs have a strong preference to form three-dimensionality intrinsically. Furthermore, the non-layered MOFs are typically synthesized in the presence of the surfactant or modulator, and thus developing facile and clean synthetic routes is highly pursued. In this study, a facile and clean synthetic methodology to grow non-layered 2D cobalt-based zeolitic imidazolate framework (ZIF-67) NSs is suggested, without using any surfactant and modulator at room temperature. This is achieved by directly converting ultrathin α-Co(OH)2 layered hydroxide salt (LHS) NSs into non-layered 2D ZIF-67 NSs. The comprehensive characterizations were conducted to elucidate the conversion mechanism, structural information, thermal stability, and chemical composition of the non-layered 2D ZIF-67. This facile and clean approach could produce a variety of non-layered 2D MOF NS families to extend potential applications of MOF materials.

A Study on the Development of a Rapid Safety Assessment System for Buildings Using Seismic Accelerometers (지진가속도 계측기를 이용한 건축물의 긴급 안전성 평가 알고리즘 개발에 대한 연구)

  • Jeong, Seong-Hoon;Jang, Won-Seok;Park, Byung-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.161-170
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    • 2020
  • In this study, develop the seismic acceleration measurement data conversion and signal processing algorithms for improve the operational efficiency of the seismic acceleration measurement system installed for public facilities. Through the analysis of the seismic acceleration time history data, the evaluation methods and criteria and evaluating the safety of buildings were proposed. The system was applied to the test bed building to verify its operation and usability. It is expected to be used as a decision making support data and determining the direction and priority of disaster response in the event of an earthquake.

Joining and Performance of Alkali Metal Thermal-to-electric Converter (AMTEC) (알칼리금속 열전기변환장치의 접합과 출력성능)

  • Suh, Min-Soo;Lee, Wook-Hyun;Woo, Sang-Kuk
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.665-671
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    • 2017
  • The alkali-Metal Thermal-to-electric Converter (AMTEC) is one of the promising static energy conversion technologies for the direct conversion of thermal energy to electrical energy. The advantages over a conventional energy converter are its high theoretical conversion efficiency of 40% and power density of 500 W/kg. The working principle of an AMTEC battery is the electrochemical reaction of the sodium through an ion conducting electrolyte. Sodium ion pass through the hot side of the beta"-alumina solid electrolyte (BASE) primarily as a result of the pressure difference. This pressure difference across the BASE has a significant effect on the overall performance of the AMTEC system. In order to build the high pressure difference across the BASE, hermeticity is required for each joined components for high temperature range of $900^{\circ}C$. The AMTEC battery was manufactured by utilizing robust joining technology of BASE/insulator/metal flange interfaces of the system for both structural and electrical stability. The electrical potential difference between the anode and cathode sides, where the electrons emitted from sodium ionization and recombined into sodium, was characterized as the open-circuit voltage. The efforts of technological improvement were concentrated on a high-power output and conversion efficiency. This paper discusses about the joining and performance of the AMTEC systems.

Proteomic Changes by Acupuncture Stimulation at HT7 in the Hippocampus of Rat Pups (신문혈 자침이 어린 백서 해마의 단백질 발현에 미치는 영향)

  • Bae, Chang-Hwan;Kim, Dong-Soo;Kim, Seung-Tae
    • Korean Journal of Acupuncture
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    • v.29 no.2
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    • pp.260-270
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    • 2012
  • Objectives : Hippocampus, a region of temporal lobe, plays an important role in the pathogenic mechanisms of brain diseases such as Alzheimer's disease, depression and temporal lobe epilepsy. This research is designed to investigate hippocampal changes after acupuncture stimulation at Shinmun(HT7) using 2-dimensional gel electrophoresis(2-DE). Methods : On postnatal-day 15, rat pups were randomly devided into Normal(NOR) or HT7 group. All of Pups kept with their mothers for 7 days, but pups in HT7 group received acupuncture stimulation at HT7 daily. On postnatal-day 21, hippocampus of each rat pup was dissceted 30 minutes after last acupuncture stimulation and the protein expressions were investigated using 2-DE. Results : After acupuncture stimulation at HT7, expression of 20 proteins were significantly increased. Succinate semialdehyde dehydrogenase, glyceraldehyde-3-phosphate dehydrogenase-like, transketolase, aconitate hydratase and phosphoglucomutase-1 were related to glucose methabolism. Eukaryotic initiation factor(eIF) 4A-II, eIF 4A-III, mitochondrial Tu translation elongation factor and chain A of crystal structure of the 70-Kda heat shock cognate protein involve in the protein synthesis in ribosome. Tubulin ${\beta}$-4 chain, tubulin T ${\beta}$-15 and tubulin ${\alpha}$-1B chain comprise cytoskeleton. Glutathione S-transferase(GST) ${\omega}$-1, GST P and GST Yb-3 can reduce oxidative stress. ${\beta}$-soluble N-ethylmaleimide-sensitive fusion protein attachment protein is required for vesicular transport between the endoplasmic reticulum and the Golgi apparatus, glycerol-3-phosphate dehydrogenase plays a major role in lipid biosynthesis, creatine kinase U-type catalyses the conversion of creatine and consumes adenosine triphosphate to create phosphocreatine and adenosine diphosphate. Platelet-activating factor acetylhydrolase IB subunit alpha and voltage depedent anion-selective channel protein 2 were also increased. Conclusions : The results suggest that acupuncture stimulation at HT7 may enhance glucose and lipid metabolism, protein synthesis, cytoskeletal substance and anti-oxidative stress in hippocampus.

An Experimental Study on the Mechanical Properties of Ductile Outline Form and Fire Resistance of High Strength RC Column (고인성 외곽 거푸집의 역학성능 및 이를 활용한 고강도 RC기둥의 내화성능에 관한 실험적 연구)

  • Rho, Hyoung-Nam;Kim, Jae-Hwan;Kim, Yong-Ro;Kim, Wook-Jong;Kwon, Young-Jin;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.199-203
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    • 2008
  • With recent trend in domestic and global market requiring architectures' conversion into skyscrapers seasoned with the features of landmarks, structural problems in relation with explosive spatting during fire emergencies are arising as controversial issues. Accordingly, many productive researches have been made in relation to the reinforcement techniques for improving fire resistance and the number of applications in the field is gradually increasing. In this study, a ductile outline form using ECC (Engineered Cementations Composites) was made with improvements on the structure and fire resistance to examine its applicability. Also, currently in Japan, the number of studies and applications is increasing focusing on reduction of construction time and improvement of workability with application of Half-PCa method. However, using such method of construction, large structural members decrease the utilization of space and architecture-wise, there is a disadvantage of the weight increase. Therefore, in such context, it would be worth reducing the weight of the structural members by reducing the size using ECC. In addition, its excellent pseudo strain-hardening due to fiber may have great effects on seismic designs. In the mean time, this study planned 3 equal conditions for mix water, PVA fiber and additives excluding binder and refractory to evaluate the mechanical properties of resistance against pressure and internal force. Finally, an evaluation was executed on the fire resistance of the newly made ductile outline form. As a result, from ECC-I to ECC-III, all showed excellent mechanical properties due to pseudo strain-hardening and in the fire resistance test conducted with ISO 834 heating curve, most of them tended to be in the range of the reference temperature (538℃-180min), so there was no occurrence of any explosive spatting.

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'Plastic' Axial Flux Machines: Design and Prototyping of a Multi-Disc PM Synchronous Motor for Aircraft Applications

  • Cerchio M.;Griva G.;Profumo F.;Tenconi A.
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.3
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    • pp.207-214
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    • 2005
  • After more than 100 years of development, rotating electric machines are a mature industrial product. Nevertheless, improvements are still possible for specific applications, and it is likely that the major evolution will be promoted by new materials and unconventional structures. Till now, plastic materials are an infrequent choice for the electric machines structural parts, but pioneering applications, such as aeronautical components, let some technological scouting: a low-weight/high-efficiency plastic axial flux motor for a solar flying platform is presented as an example of combined new-material/new-geometry development. The basic design aspects and the prototyping choices are presented and discussed together with the first experimental results.

Characteristics of Ti Thin films and Application as a Working Electrode in TCO-Less Dye-Sensitized Solar Cells

  • Joo, Yong Hwan;Kim, Nam-Hoon;Park, Yong Seob
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.2
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    • pp.93-96
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    • 2017
  • The structural, electrical and optical properties of Ti thin films fabricated by dual magnetron sputtering were investigated under various film thicknesses. The fabricated Ti thin films exhibited uniform surfaces, crystallinity, various grain sizes, and with various film thicknesses. Also, the crystallinity and grain size of the Ti thin films increased with the increase of film thickness. The electrical properties of Ti thin films improved with the increase of film thickness. The results showed that the performance of TCO-less DSSC critically depended on the film thickness of the Ti working electrodes, due to the conductivity of Ti thin film. However, the maximum conversion efficiency of TCO-less DSSC was exhibited at the condition of 100 nm thickness due to the surface scattering of photons caused by the variation of grain size.