• 제목/요약/키워드: Stripping process

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Mechanical Strength Characteristics of Fiber Bragg Gratings with Fabrication Process (광섬유 브래그 격자의 제작 방법에 따른 기계적 강도 특성)

  • Park S. O.;Kim C. G.;Kang D. H.
    • Composites Research
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    • v.18 no.1
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    • pp.16-22
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    • 2005
  • Application fields on structural health monitoring of fiber Bragg gratings (FBGs) are gradually expanded even to a primary structure as well as a secondary structure and a specimen. For the reason, verification for the reliability of FBGs such as signal characteristics and mechanical strength becomes much more important. In this study, mechanical strength characteristics of FBGs with their fabrication process and reflectivity are investigated with various grating lengths. From the results of tension tests, it is shown that the mechanical strength of optical fibers decreases about $50\%$ just by jacket stripping and the amount of decrease is dependent on stripping methods. About $55\%$ of mechanical strength of stripped optical fibers decreases if gratings are formed in the core and it is regardless of grating lengths and reflectivity. However, the width of strength distribution increases relative to increases in reflectivity.

Preparation of High Purity ZnO Powder from zinc-bearing waste by the Hydrometallurgical Process (함아연 폐기물로부터 습식법에 의한 고순도 ZnO 분말의 제조)

  • 이재천;이강인;유효신
    • Resources Recycling
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    • v.1 no.1
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    • pp.58-68
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    • 1992
  • A process development for direct synthesis of high pure ZnO powders from zinc-bearing waste was investigated. This waste contains a 55% of zinc and it was extracted by the sulfuric acid(leaching). After removal of iron ion by precipitation from the zinc solution, the purification through a solvent extraction by the use of D2EHPA as an extractant was carried out. Then, loaded zinc in organic solution was stripped and precipitated simultaneously using a precipitant such as oxalic acid. Then, loaded zinc in organic solution was stripped and precipitated simulataneously using a precipitant such as oxalic acid. The synthesized $ZnC_2O_4$ powders by the precipitation stripping method was calcined to obtain more than 99.9% of ZnO powders. The effect of sulfuric acid concentration, leaching time, pulp density on the extraction of zinc was studied and the optimum conditions for the solvent extraction were obtained through the investigation of purification of zinc solution. The size, morphology and size distribution of synthesized $ZnC_2O_4$ powders were studied in terms of oxalic acid concentration, temperature, surfactant added, precipitation time, etc.

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Separation of Co(II), Ni(II), and Cu(II) from Sulfuric Acid Solution by Solvent Extraction (황산용액에서 용매추출에 의한 코발트(II), 니켈(II) 및 구리(II) 분리)

  • Moon, Hyun Seung;Song, Si Jeong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.1
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    • pp.21-28
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    • 2022
  • The smelting reduction of spent lithium-ion batteries results in metallic alloys of cobalt, nickel, and copper. To develop a process to separate the metallic alloys, leaching of the metallic mixtures of these three metals with H2SO4 solution containing 3% H2O2 dissolved all the cobalt and nickel, together with 9.6% of the copper. Cyanex 301 selectively extracted Cu(II) from the leaching solution, and copper ions were completely stripped with 30% aqua regia. Selective extraction of Co(II) from a Cu(II)-free raffinate was possible using the ionic liquid ALi-SCN. Three-stage cross-current stripping of the loaded ALi-SCN by a 15% NH3 solution resulted in the complete stripping of Co(II). A process was proposed to separate the three metal ions from the sulfuric acid leaching solutions of metallic mixtures by employing solvent extraction.

Recovery of ammonia from wastewater by liquid-liquid membrane contactor: A review

  • Jang, Yoonmi;Lee, Wooram;Park, Jaebeom;Choi, Yongju
    • Membrane and Water Treatment
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    • v.13 no.3
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    • pp.147-166
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    • 2022
  • Liquid-liquid membrane contactor (LLMC), a device that exchanges dissolved gas molecules between the two sides of a hydrophobic membrane through membrane pores, can be employed to extract ammoniacal nitrogen from a feed solution, which is transported across the membrane and accumulated in a stripping solution. This LLMC process offers the promise of improving the sustainability of the global nitrogen cycle by cost-effectively recovering ammonia from wastewater. Despite recent technological advances in LLMC processes, a comprehensive review of their feasibility for ammonia recovery is rarely found in the literature. Our paper aims to close this knowledge gap, and in addition to analyze the challenges and provide potential solutions for improvement. We begin with discussions on the operational principles of the LLMC process for ammonia recovery and membrane types and membrane configurations commonly used in the process. We then assess the performance of the process by reviewing publications that demonstrate its practical application. Challenges involved in the implementation of the LLMC process, such as membrane fouling, membrane wetting, and chemical requirements, are presented, along with discussions on potential strategies to address each. These strategies, including membrane modification, hybrid process design, and process optimization based on cost-benefit analysis, guide the reader to identify key areas of future research and development.

Permeability of anion-exchange membrane for Cl- ions. Dialysis of hydrochloride acid in the presence of nickel chloride

  • Palaty, Zdenek;Bendova, Helena
    • Membrane and Water Treatment
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    • v.1 no.1
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    • pp.39-47
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    • 2010
  • Using a conventional two-compartment cell with stirrers the separation of an aqueous solution of HCl-$NiCl_2$ by an anion-exchange membrane Neosepta-AFN was investigated. The dialysis process was characterized by the permeability coefficient of the membrane towards to $Cl^-$ ions. This quantity was determined by the numerical integration of equations, which describe the time dependence of the total concentration of $Cl^-$ ions in compartment initially filled with stripping agent (water), combined with an optimizing procedure. The analysis of the experimental results showed that this permeability coefficient is a satisfactory characteristic for the process studied. It can be graphically correlated with the initial acid and initial salt concentrations in the compartment initially filled with acid+salt mixture.

Recovery of Cobalt from the Wastewater produced during Malonate Process by Solvent Extraction (말로네이트 제조 공정 폐수로부터 코발트 회수: 용매추출법 적용)

  • 문영환
    • Journal of Environmental Science International
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    • v.6 no.2
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    • pp.133-139
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    • 1997
  • The solvent extraction method was applied on the wastewater produced during malonate(malonic acid esters) process to recover cobalt. DEHPA and PC88A were used as organic solvent From separation funnel experiment(batch experiment), the effects of vari- ous parameters (pH, cobalt concentration, reaction rate, and stripping temperature) on solvent extraction were examined and these data were used to derive equilibrium curve. A mixer-settler experiment (continuous experiment) of bench scale was also carried out for the plant construction and a Mccabe-Thiele diagram was obtained. The results of these experiments indicate that cobalt is recoverable above 99 oyo and that its purity as cobalt sulfate Is higher than 99.9 wt%.

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Vibration Analysis of Spin Etcher (Spin Etcher의 진동 분석)

  • 임경화;이은경;조중근
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.1
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    • pp.15-19
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    • 2003
  • Spin etcher can process frontside and backside on the wafer, which is used for etching, stripping, cleaning and wafer reclamation. A new generation of spin etchers has been designed to meet 300mm wafer processing. The larger header and higher spin speed make vibration problem a severe problem in developing equipments. This study shows schematic process of solving practical vibration problems, where it is required to analyze the principal ca uses of vibration problem and find out the method of vibration reduction in spin etcher. The vibration under normal operation is measured in time domain and is analyzed in frequency domain. And modal parameters are obtained through modal test. Using the modal parameters from experiments, the model of finite element method is formulated. From diagnosis using many measurements and analyses, it can be shown that main cause of vibration is unbalance of head.

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Mass transfer in adiabatic rectifier of ammonia-water absorption system (암모니아-물 흡수식 시스템에서 단열정류기의 물질 전달)

  • 김병주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.414-421
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    • 1999
  • Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.

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Mass Transfer in an Adiabatic Rectifier of Ammonia-Water Absorption System

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.8 no.2
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    • pp.69-79
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    • 2000
  • Falling film rectification involves simultaneous heat and mass transfer between vapor and solution film. In the present work, the adiabatic rectification process of ammonia-water vapor by the falling solution film on the vertical plate was investigated. The continuity momentum, energy and diffusion equations for the solution film and the vapor mixture were formulated in integral forms and solved numerically, The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer coefficient in each phases were investigated. The stripping of water in vapor mixture occurred near the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer coefficient in falling film.

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The Optimum Condition Analysis of Vanadium Solvent Extraction by Alamine336 from the Synthetic Vanadium Sulfate Solution. (황산바나듐 모의용액으로부터 Alamine336에 의한 바나듐 용매추출의 최적조건 연구)

  • Ahn, Jong-Gwan;Ahn, Jae-Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.823-829
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    • 2008
  • The solvent extraction process for the recovery of vanadium from leaching solution of SCR(selective catalytic reduction) spent catalyst was investigated by using Alamine336 as an extractant. The effects of experimental conditions, such as initial pH and concentration of sulfate ion, and ammonia concentration of stripping solution were studied. The extraction percentage of vanadium were increased with the increase of initial pH of leaching solution and decreased with the increase of sulfate ion. More than 99% of vanadium in leaching solution were extracted and stripped at the A/O ratio of 1.0 in 2 stages. On the basis of these results, an optimum solvent extraction process which vanadium was effectively recovered from SCR spent catalyst was proposed.