• Toxicological Research
• /
• v.26 no.3
• /
• pp.233-236
• /
• 2010

The analytical in vivo chromium ion was searched for using a voltammetric hollow-fiber dialysis sensor via square wave stripping voltammetry (SW), cyclic voltammetry (CV), and chronoamperometry. Under optimum parameters, the analytical results indicated linear working ranges of 50~400 mg/l CV and $10{\sim}80\;{\mu}g/l$ SW within a 30-sec accumulation time. The analytical detection limit (S/N) was $6.0\;{\mu}g/l$. The developed method can be applied to in vivo tissues and in ex vivo toxicity assay, as well as to other materials that require chromium analysis.

• Journal of Environmental Science International
• /
• v.21 no.11
• /
• pp.1333-1338
• /
• 2012

In order to measure the minute amount of Cu(II) in our environment, cyclic voltammetry (CV) and square-wave stripping voltammetry (SWSV) were performed for a trace copper assay using bismuth immobilized on a carbon nanotube paste electrode. An analytical working range of 30 to $240{\mu}g/L$ Cu(II) was obtained for CV and SWSV. The SWSV precision obtained was 0.47 % (n = 15) RSD in $30.0{\mu}g/L$ Cu(II). The detection limit obtained was 3.1 ng/L Cu(II) using SWSV, while the CV yielded the nano-range detection limit through the pre-concentration step. By using this research method, Cu(II) value could be determined in the urine of human sample and in the brain of fish sample. This research can be effectively applied to other cases of measuring minute amount of Cu(II) in living organisms.

• 제어로봇시스템학회:학술대회논문집
• /
• 1988.10a
• /
• pp.466-470
• /
• 1988

A tunable reduced-order distillation model is proposed for real-time applications. To develop the model, a binary distillation column with MaCabe-Thiele assumptions was considered first and then the governing equations for the column were reduced to a simplified vector differential equations using the collocation method combined with cubic spline interpolation function. The final reduced-order model has four tuning parameters, relative volatilities and liquid holdups for rectifying and stripping sections, respectively. To assess the applicability of the developed model,the real-time adjustment of the model was tried by recursively updating the tuning parameters using the BKF algorithm. As a result, it was found that the reduced-model follows the simulated distillation process very closely as the parameters are improved.

• Journal of Korean Society of Water and Wastewater
• /
• v.25 no.6
• /
• pp.989-994
• /
• 2011

Nitrate contamination of groundwater is a common problem throughout intensive agriculture areas (non-point source pollution). Current processes (e.g. ion exchange and membrane separation) for nitrate removal have various disadvantages. The objective of this study was to evaluate electrochemical method such as electroreduction using bipolar ZVI packed bed electrolytic cell to remove nitrate from groundwater at field pilot. In addition ammonia stripping tower continuously removed up to 77.0% of ammonia. Bipolar ZVI packed bed electrolytic cell also removed E.coli. In the field pilot experiment for groundwater in 'I' city (average nitrate 30~35 mg N/L, pH 6.4), maximum 99.9% removal of nitrate was achieved in the applied 600 V.

• Membrane and Water Treatment
• /
• v.4 no.4
• /
• pp.223-236
• /
• 2013

The paper presents an experimental set-up for osmotic membrane distillation, which can be operated continuously for several weeks. NaCl solutions were used as an osmotic solution. The influence of osmotic solution concentration on the obtained permeate flux is presented. The experimental set-up was equipped with a system for the regeneration of dilute brine. The regeneration was carried out using a method of natural evaporation to the air surrounding the installation. The evaporation area was created by the Białecki rings, assembled in the form of tower. The obtained evaporation rate was sufficient to maintain a constant NaCl concentration (over 300 g/L), for air with the relative humidity in the range of 30-80%. Accurel PP S6/2 hydrophobic polypropylene membranes were used in the study. The membranes exhibited 100% rejection for 600 h of the process duration.

• Journal of the Korean Applied Science and Technology
• /
• v.29 no.4
• /
• pp.626-630
• /
• 2012

Diagnosis with an ex-vivo gold sensor was done using a modified fluorine-doping sensor, and cyclic voltammetry (CV) redox potentials of 0.4 V anodic and -0.2 V cathodic were obtained. Both peak currents were optimized using square-wave (SW) stripping voltammetry, and an analytical working range of 10-80 ug/L SW was attained. The precision of the 10-mg/L Au was 0.765 (n=8) RSD under the optimum conditions, and the analytical detection limit approached 0.006 ug/L (S/N=3) with only a 60 sec accumulation time. The developed method was used to examine the mouse droppings for medicinal diagnosis.

• Journal of the Korean Applied Science and Technology
• /
• v.31 no.4
• /
• pp.663-668
• /
• 2014

An in-vivo diagnosis of trace Mg(II) ion was performed using a low-cost and environment-friendly voltammetric method, using a graphite counter and reference electrodes and a fluorine-immobilized graphite working electrode, and clean deep seawater was used as an electrolyte solution. Under optimum conditions, the analytical working ranges attained microgram ranges, and a detection limit of $80.6ugL^{-1}$ was obtained using stripping voltammety with 60 sec accumulation time. Ex-vivo application was performed on fish liver and mice droppings. The developed techniques can be applicable to tumor cell analysis.

• The Korean Journal of Nuclear Medicine
• /
• v.34 no.4
• /
• pp.336-343
• /
• 2000

Purpose: Thallous-201 chloride produced at Korea Cancer Center Hospital(KCCH) is used in detecting cardiovascular disease and cancer. Thallium impurity can cause emesis, catharsis and nausea, so the presence of thallium and other metal impurities should be determined. According to USP and KP, their amounts must be less than 2 ppm in thallium and 5 ppm in total. In this study, the detection method of trace amounts of metal impurities in $[^{201}Tl]$TICI injection with polarography was optimized without environmental contamination. Materials and Methods: For the detection of metal impurities, Osteryoung Square Wave Stripping Voltammetry method was used in Bio-Analytical System (BAS) 50W polarograph. The voltammetry was composed of Dropping Mercury Electrode (DME) as a working electrode, Ag/AgCl as a reference electrode and Pt wire as a counter electrode. Square wave stripping method, which makes use of formation and deformation of amalgam, was adopted to determine the metal impurities, and pH 7 phosphate buffer was used as supporting electrolyte. Results: Tl, Cu and Pb in thallous-201 chloride solution were detected by scanning from 300 mV to -800 mV Calibration curves were made by using $TINO_3,\;CuSO_4\;and\;Pb(NO_3){_2}$ as standard solutions. Tl was confirmed at -450 mV peak potential and Cu at -50 mV Less than 2 ppm of Tl and Cu was detected and Pb was not detected in KCCH-produced thallous-201 chloride injection. Conclusion: Detection limit of thallium and copper is approximately 50 ppb with this method. As a result of this experiment, thallium and other metal impurities in thallous-201 chloride injection, produced at Korea Cancer Center Hospital, are in the regulation of USP and KP Polarograph could be applied for the determination of metal impurities in the quality control of radiopharmaceuticals conveniently without environmental contamination.

• International Journal of Highway Engineering
• /
• v.17 no.1
• /
• pp.17-24
• /
• 2015

PURPOSES : Recently, crack, rutting, and stripping problems from the surface of asphalt pavements in National highway are observed and they affect the drivers to feel uncomfortable on the road. Surface treatments are recommended to use in distressed pavements due to cost-effective, and improvement of surface performance. The purpose of this study is to evaluate the performance of micro-surfacing and polymer slurry seal treatments for distressed asphalt pavements. METHODS : Surface conditions and friction resistance are evaluated for asphalt pavements treated with micro-surfacing and polymer slurry seal mixes in National highway 30 line and 34 line. Visual observation is conducted and surface performance is measured by PES (Performance Evaluation Surveyor) in terms of crack ratio, rutting and IRI(International Roughness Index). BPN(British Pendulum Number) is measured by BPT(British Pendulum Tester) to evaluate the friction resistance in the field. RESULTS : The surface evaluation results are presented for asphalt pavement treated with micro-surfacing and polymer slurry seal treatments in National highway 30 line and 34 line. Based on the visual observation, micro-surfacing and polymer slurry seal treatments show better improvements in terms of cracks and stripping. Based on the surface conditions measured by PES vehicle, the surface performance of micro-surfacing treatments improves from 53.3% to 54.2% and the surface performance of polymer slurry seal treatments improves from 21.6% to 59.7%. However, the friction resistance of both micro-surfacing and polymer slurry seal treatments decreases from 2.5% to 6.7%. Further, it should be verified to produce the surface exposed with aggregates during the construction process of both treatment methods in the field. CONCLUSIONS : Based on the performance evaluation results in the filed, the surface performance of asphalt pavement treated with micro-surfacing and polymer slurry seal treatments improves from 21.6% to 59.7%. While, the friction resistance of asphalt pavement treated with micro-surfacing and polymer slurry seal treatments does not improve. It can be concluded that current micro-surfacing and polymer slurry seal treatments would improve surface performance but would not improve the friction resistance.

• Clean Technology
• /
• v.18 no.4
• /
• pp.432-439
• /
• 2012

The electrocatalytic oxidation of CO was studied using carbon-supported 20 wt% PtRu (PtRu/C) catalysts, which were prepared with different Pt : Ru atomic ratios from 7 : 3 to 3 : 7 using a colloidal method combined with a freeze-drying procedure. The bimetallic PtRu/C catalysts were characterized by various physicochemical analyses, including X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). CO stripping voltammetry measurements indicated that the addition of Ru with a Pt catalyst significantly improved the electrocatalytic activity for CO electrooxidation. Among the tested catalysts, the $Pt_5Ru_5/C$ catalyst had the lowest onset potential (vs.Ag/AgCl) and the largest CO EAS. Structural modification via lattice parameter change and electronic modification in the unfilled d band states for Pt atoms may facilitate the electrooxidation of CO.