• Title/Summary/Keyword: Stripping

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Modeling of Ammonia Mass Transfer Using a Hollow Fiber Membrane Contactor (중공사막 접촉기를 이용한 암모니아 물질전달 모델링)

  • Oh, Dae-Yang;Jeong, Joo-Young;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.503-510
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    • 2011
  • Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

Solvent Extraction of Sn(IV) from Hydrochloric Acid Solution by Alamine 336 (염산용액에서 Alamine 336에 의한 주석(IV)의 용매추출)

  • Ahn, Jae-Woo;Seo, Jae-Seong;Lee, Man-Seung
    • Korean Journal of Metals and Materials
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    • v.48 no.10
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    • pp.929-935
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    • 2010
  • The solvent extraction behavior of Sn(IV) from hydrochloric acid was investigated using Alamine336 (Tri-n-cotylamine) as an extractant. The experimental parameters of the concentration of the HCl solution, chloride ions, extractant, and Sn(IV) were assessed. The results showed that the extraction percentage of Sn(IV) was more than 95% in our experimental range and was only slightly affected by the HCl concentration. The extraction reaction of Sn(IV) by Alamine 336 from the chloride solution was identified as follows: $SnCl_6{^{2-}}+2R_3NHCl_{(org)}=(R_3NH)_2SnCl_{6(org)}+2Cl^-$ and $K=6.3{\times}10^4$. Stripping experiments of Sn(IV) from the loaded organic phase were done by using several stripping agents. A stripping percentage of 90% was obtained with a 2.0 M NaOH solution.

Determination of Heavy Metals in Sea Salt Using Anodic Stripping Voltammetry

  • Kim, Yong Hoon;Kim, Giyoung
    • Food Engineering Progress
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    • v.21 no.2
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    • pp.180-186
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    • 2017
  • Salt, as food, is the most essential element for human survival due to its significant physiological functions. Here, we report the simultaneous detection of Pb and Cd in sea salt by square wave anodic stripping voltammetry (SWASV). Stripping voltammetric measurements were conducted using a manufactured rotating disk electrode system (MRDES). The detection limit was $3.6{\pm}0.18{\mu}gL^{-1}$ for Pb and $3.9{\pm}0.37{\mu}gL^{-1}$ Cd in NaCl solution. When the pH increased from 5.5 to 8.5, the peak currents of Pb and Cd decreased. At a pH of 8.3, the ratio of the current drop compared with that at a pH of 5.5 was 0.6 for Pb and 0.73 for Cd. The concentrations corrected by the current drop are in agreement with the concentrations obtained with ICP (inductively coupled plasma). This system demonstrates the reliable detection of heavy metals in aqueous media and, at a high $Na^+$ concentration, the successful application for the determination of Pb and Cd in sea salts.

Solvent Extraction of Hydrochloric Acid Using Commercial Extractants and Synthesized Ionic Liquids (상용화 추출제 및 이온성액체에 의한 염산의 용매추출)

  • Nguyen, Viet Nhan Hoa;Lee, Man Seung
    • Resources Recycling
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    • v.29 no.6
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    • pp.79-87
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    • 2020
  • The extraction and stripping of HCl from aqueous solutions by commercial extractants like LIX 63 and its mixture with TEHA/ Cyanex 923/ Aliquat 336 and ionic liquids like ALi-SCN, ALi-PC in kerosene was investigated. Among these extractants, ALi-PC showed the best extraction effectivity (above 80%), but it was difficult to strip HCl from the loaded phase. Although the extraction percentage of HCl by LIX 63 was not high, the stripping performance was above 81%. The addition of octanol to the organic phase led to negative effect on the extraction performance of HCl. The addition of C2H5OH into aqueous solutions significantly increased the extraction and stripping percentage of HCl by LIX 63, ALi-PC and ALi-SCN.

A GMOS/IFU Spectroscopic Mapping of Jellyfish Galaxies in Extremely Massive Galaxy Clusters

  • Lee, Jeong Hwan;Lee, Myung Gyoon;Kang, Jisu;Cho, Brian S.;Mun, Jae Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.32.3-33
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    • 2020
  • Jellyfish galaxies show spectacular features such as star-forming knots and tails due to strong ram-pressure stripping in galaxy clusters. Thus, jellyfish galaxies are very useful targets to investigate the effects of ram-pressure stripping on the star formation activity in galaxies. Integral field spectroscopy (IFS) studies are the best way to study star formation in jellyfish galaxies, but they have been limited to those in low-mass galaxy clusters until now. In this study, we present a Gemini GMOS/IFU study of three jellyfish galaxies in very massive clusters (M_200 > 10^15 Mo). The host clusters (Abell 2744, MACSJ0916.1-0023, and MACSJ1752.0+4440) are X-ray luminous and dynamically unstable, suggesting that ram-pressure stripping in these clusters is much stronger than in low-mass clusters. We present preliminary results of star formation rates, kinematics, dynamical states, and ionization mechanisms of our sample galaxies and discuss how ram-pressure stripping relates with the star formation activity of jellyfish galaxies in massive clusters.

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Ram pressure stripping conditions : Theory vs. Observation

  • Lee, Seona;Sheen, Yun-Kyeong;Yoon, Hyein;Jaffe, Yara;Chung, Aeree
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.33.1-33.1
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    • 2020
  • Ram pressure stripping (RPS) which is known to be one of the key effects that can remove the interstellar gas in the dense environment, can be described as a simple momentum transfer relation (Gunn & Gott 1972). However, it has been suggested that the actual gas stripping process is likely more complicated than Gunn & Gott's prescription due to the complexity of gas physics such as compression, cooling and heating. By comparing the gas truncation radius predicted by theory with the stripping radius measured from the HI observation of Virgo cluster galaxies, we attempt to verify how well the RPS process can be understood by momentum transfer alone. Among the sample of galaxies undergoing active RPS, we generally find a good agreement between what is predicted and what is observed within the measurement uncertainties. However, those galaxies with the signs of other environmental effects than RPS such as tidal interaction, and/or the ones likely at relatively early or later stages of RPS show some offsets between the theory and the observation. These results imply that Gunn & Gott's formula works reasonably well in a broad sense when the RPS is a dominant process and the surrounding environment at the current location of the sample can be well defined. Otherwise, the impact of the second mechanism, as well as the (current and past) environment of the sample, should be more carefully reviewed to assess the impact of RPS on galaxy evolution.

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Determination of Fluoroquinolone Antibacterial Agents by Square Wave Adsorptive Stripping Voltammetry (네모파 흡착 벗김 전압전류법에 의한 플루오로퀴놀론 계 항생제의 검출)

  • Boo, Han-Kil;Song, Youn-Joo;Park, Se-Jin;Chung, Taek-Dong
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.63-69
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    • 2010
  • Electrochemical behavior of fluoroquinolone antibacterial agents on carbon paste electrode (CPE) were investigated by cyclic voltammetry and square wave adsorptive stripping voltammetry. The fluoroquinolone antibacterial agents tested in this study were Enrofloxacin (ENR), Norfloxacin (NOR), Ciprofloxacin (CIP), Ofloxacin (OFL) and Levofloxacin (LEV). In acetate buffer at pH 4.5, the oxidation peak potentials of the fluoroquinolone antibacterial agents of ENR, NOR, CIP, OFL, and LEV were 0.952 V, 1.052 V, 1.055 V, 0.983 V, and 0.990 V (vs. Ag/AgCl), respectively. And their oxidation peak currents from square wave adsorptive stripping voltammograms are proportional to the concentration of each antibacterial agent over the range from $0.2\;{\mu}M$ to $1\;{\mu}M$.

A Study on the Mass Transfer and Metal Extraction by use of Hydrophobic Membrane (소수성막을 이용한 금속추출 및 물질전달에 관한 연구)

  • Lee, Ryong-Jin;Kim, Young-Il;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1036-1042
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    • 1998
  • It was investigated that the extraction of Cr(VI) from aqueous solution into the organic TDA and the stripping(back extraction) of Cr(VI) from the Cr(VI)-TDA complex into NaOH aqueous solution by hydrophobic hollow fiber membrane. It was found that the mass transfer rates of stripping process were smaller than those of the extraction process. This result was expected that membrane resistance, neglected in the extraction process, acts on the stripping process when organic phase flow in the tube side of the hydrophobic membrane. Hollow fiber modules were made by potting the desired number(60, 100, 150, 300fibers). We also examined the effect of flow rates of aqueous and organic phase on the mass transfer rate in the membrane modules. From these experiments, we identified for the extraction process by using hydrophobic membrane, the effect of flow rate of aqueous phase on the mass transfer rate was significant, but that of organic phase was negligible one. In the stripping process, however, mass transfer rate depend neither flow rate of aqueous(stripping solution) phase nor that of organic(Cr-TDA complex) phase.

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Growth and nutrient removal of Chlorella vulgaris in ammonia-reduced raw and anaerobically-digested piggery wastewaters

  • Kwon, Gyutae;Nam, Ji-Hyun;Kim, Dong-Min;Song, Chulwoo;Jahng, Deokjin
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.135-146
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    • 2020
  • This study was aimed to investigate the possibility of using raw and anaerobically-digested piggery wastewater as culture media for a green microalga Chlorella vulgaris (C. vulgaris). Due to high concentration of ammonia and dark color, the microalga did not grow well in this wastewater. In order to solve this problem, air stripping and NaOCl-treatment were applied to reduce the concentration of NH3-N and the color intensity from the wastewater. Algal growth was monitored in terms of specific growth rate, biomass productivity, and nutrient removal efficiency. As a result, C. vulgaris grew without any sign of inhibition in air-stripped and 10-folds diluted anaerobically-digested piggery wastewater with enhanced biomass productivity of 0.57 g/L·d and nutrient removal of 98.7-99.8% for NH3-N and 41.0-62.5% for total phosphorus. However, NaOCl-treatment showed no significant effect on growth of C. vulgaris, although dark color was removed greatly. Interestingly, despite that the soluble organic concentration after air stripping was still high, the biomass productivity was 4.4 times higher than BG-11. Moreover, air stripping was identically effective for raw piggery wastewater as for anaerobic digestate. Therefore, it was concluded that air stripping was a very effective method for culturing microalgae and removing nutrients from raw and anaerobically-digested piggery wastewaters.

Dither-stripping with the differential of dither rate signal for a ring laser gyroscope (링레이저 자이로의 각진동 센서신호 미분에 의한 dither-stripping)

  • Shim, Kyu-Min;Chung, Tae-Ho;Lim, Hoo-Jang
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.8
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    • pp.65-74
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    • 2005
  • It is required for getting the ring laser gyro output purely related to the input rotation to eliminate the output of the modulated angular vibration from the ring laser signal. In this paper we discuss the dither stripping methods of compensating the ring laser signal by converting the rate signal of dither detector from voltage to frequency for a dither type ring laser gyro. We discuss the differential methods for getting rid of the offset of the V-F signal. And we develope the methods of compensating the phase differences between the ring laser signals and the V-F differential signals by using analog integrator and digital time delays. And also, we develope the gain calculation method by comparing the standard deviations of the ring laser signals with V-F differential signals. We implemented these methods and analyzed the effectiveness of these methods by comparing the dither trapping methods.