• 제목/요약/키워드: Stripping

검색결과 645건 처리시간 0.025초

벗김 전압전류법에 의한 오스뮴 정량 (Stripping Voltammetric Determination of Osmium)

  • 권영순;김소진;채명준
    • 분석과학
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    • 제10권2호
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    • pp.114-118
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    • 1997
  • 히드록실아민 존재하에서 오스뮴(IV)의 벗김 전압전류법적 정량법을 연구하였다. 가장 좋은 조건은 다음과 같다: 히드록실아민 0.05M, pH 1.8, 누적전위 -0.65V, 누적시간 60초, 주사속도 10mV/s. 이 조건에서 검출한계는 $6.3{\times}10^{-8}M$이었으며, 검량선의 직선성이 성립하는 오스뮴의 농도 범위는 $10^{-4}{\sim}10^{-7}M$이었다. 유사한 매질에서 같은 족인 루테늄이 촉매 수소파를 주는데 비해 오스뮴은 촉매성이 전혀 없는 확산 지배성 전류를 주었다.

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RLG Trapping 신호처리 기법의 성능개선에 관한 연구 (A study on the Performance Improvement in Trapping Signal Processing Method of RLG)

  • 유기정;김천중;심규민
    • 한국항공우주학회지
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    • 제36권10호
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    • pp.1003-1010
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    • 2008
  • 본 논문은 RLG의 신호처리 기법인 Trapping 기법 적용시 각속도와 가속도의 측정시점 불일치에 의해 발생되는 오차를 보상하는 기법에 관한 연구이다. RLG의 대표적인 신호처리 기법인 Stripping 신호처리 기법과 Trapping 신호처리 기법에 대하여 각 기법의 오차요인을 분석하고 이에 대한 모델링을 수행하였다. 그리고 Trapping 기법 적용시 각속도와 가속도 측정시점 불일치에 의해 발생되는 오차에 대한 모델링을 통하여 항법오차에 미치는 영향을 분석하였으며 이를 감소시키기 위한 새로운 신호처리 기법을 제안하고 시뮬레이션 및 시험을 통하여 이에 대한 성능분석 결과를 제시하였다. 성능 분석결과 본 논문에서 제시한 신호처리 기법이 기존의 방법에 비하여 항법오차를 크게 감소시키는 것을 확인할 수 있었다.

흡착벗김 전압전류법적 지르코늄의 정량 (Adsorptive Stripping Voltammetrical Determination of Zirconium)

  • 최원형;이진식;김도훈;김종철
    • 분석과학
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    • 제6권5호
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    • pp.425-433
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    • 1993
  • oxine을 리간드로 이용하여 흡착벗김 전압전류법으로 극미량의 지르코늄을 정량하는 방법을 연구하였다. 이때 지지전해질은 $2.5{\times}10^{-3}M$ borax 완충용액을 사용하였고, oxine의 농도가 $4{\times}10^{-8}M$로 되도록 하여 실험하였다. accumulation potential을 -0.2V, accumulation time을 400sec로 하고 scan rate를 4mV/sec로 하여 실험한 결과 지르코늄의 농도가 $1{\sim}100{\mu}g/L$ 범위에서 얻은 검정곡선은 직선성을 나타내었다.

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18-crown-6을 포함하는 poly(3-methylthiophene) 전도성 고분자 막전극에 의한 Ag(I)의 벗김 전압-전류법적 정량에 관한 연구 (A study on Stripping Voltammetric Determination of Ag(I) by Poly(3-methylthiophene) Conducting Polymer Film Electrode Containing 18-crown-6)

  • 이인종;손정인;김국진
    • 분석과학
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    • 제7권2호
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    • pp.181-186
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    • 1994
  • Poly(3-methylthiophene) 전도성 막전극을 이용해서 벗김 전압-전류법으로 Ag의 분석 가능성을 연구하였다. 막전극 표면에 존재하는 18-crown-6은 수용액에서 Ag(I)을 착화에 의해서 흡수하고 이 Ag(I)은 제한된 전위 범위의 순환 전압-전류법에 의해서 막전극 속으로 이동하여 유리질 탄소전극에서 산화-환원된다. 따라서 막전극은 Ag(I)의 침투를 용이하게 하기 위해서 적당한 두께의 다공성으로 제조되어야 한다. 이러한 실험 결과를 바탕으로 수용액에서 $5.0{\times}10^{-6}M$의 Ag(I)을 검출할 수 있었다.

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The Correlation between Mixture Distress and Strength of Bituminous Concretes

  • 김광우
    • 한국농공학회지
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    • 제32권E호
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    • pp.67-73
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    • 1990
  • Many distress mechanisms in pavement are known to be caused by the poor mechanical properties of bituminous concretes. Among many mechanical properties, tensile strength is one of the more important indicates that represent the resistance of pavement to traffic loading. However, there has been no relationship established between the strength and distress mechanisms. Therefore, this study was conducted to evaluate a correlation between the tensile strength value and the intensity of distress in bituminous concrete. Distress data were collected from an extensive field investigation over 77km of a four-lane highway in South Carolina, USA, and from laboratory prepared specimens in two phases of study. Strength data were obtained from a total of more than 400 field cores taken from the same highway and from 640marshall specimens of surface course mixture prepared in the laboratory. These data were analyzed using statistical test techniques. It was found from statistical analyses that the tensile strength of bituminous concrete had a strong relation with the pavement condition in the field. In the analysis of rutting and stripping, low strength concrete showed a higher distress rate in the mixture, and mixtures under distress in the field showed obviously reduced strength values. Stripping was found to be the most significant distress mechanism that was correlated with low strength bituminous concrete. Rutting appeared more frequently in a low strength pavement section of the highway as a sign of failure due to traffic loading.

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흡착벗김 전압전류법에 의한 국내산 약용식물에 함유된 게르마늄의 분석 (Determination of Germanium (IV) Content in the Korean Medicinal Herbs by Adsorption Stripping Voltammetry)

  • 정승일;천현자;김일광
    • 분석과학
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    • 제11권5호
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    • pp.400-403
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    • 1998
  • The germanium content of the cultivated Korean medicinal herbs in several growing district was determined by adsorption stripping voltammetry. The optimum conditions in germanium determination were as following: deposition time; 120 sec, deposition potential; -0.9 volts vs. Ag/AgCl, and frequency; 100 Hz in $5.0{\times}10^{-2}M$ perchloric acid supporting electrolyte solution containing $8.0{\times}10^{-2}M$ catechol. Calibration curve was shown a good lineality in the range of 0.4 ppb to 2.0 ppm and the detection limit was 0.08 ppb. There was a large difference in content of the cultivated hermit leaf according to growing district such as 29.7~385.7 ppm and the content of nontreated hermit leaf was higher than the processed health foodstuffs. The content of the Korean ginseng (5 years) was 83 ppm while the Korean herb of life was 214 ppm.

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Combination of air stripping and biological processes for landfill leachate treatment

  • Smaoui, Yosr;Bouzid, Jalel;Sayadi, Sami
    • Environmental Engineering Research
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    • 제25권1호
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    • pp.80-87
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    • 2020
  • Landfill waste decomposition generates a dark effluent named, leachate which is characterized by high organic matter content. To minimize these polluting effects, it becomes necessary to develop an effective landfill leachate treatment process. The objective of this study was to evaluate the performance of an innovative approach based on air stripping, anaerobic digestion (AD) and aerobic activated sludge treatment. A reduction of 80% of ammonia and an increase of carbon to nitrogen ratio to 25 were obtained, which is a suitable ratio for AD. This latter AD was performed in fixed bed reactor with progressive loading rate that reached 2 and 3.2 g COD/L/d for the raw and diluted leachate (1:2), respectively. The anaerobic treatment led to significant removal of chemical oxygen demand (COD) and biogas production, especially for the diluted leachate. The COD removal was of 78% for the raw leachate and a biogas production of 4 L/d with 70% methane content. The use of the diluted leachate led to 81% of COD removal and 7 L/d biogas with 75% methane content. It allowed a removal of 77% COD and more than 97% of the organic compounds present in the initial leachate sample.

A case study of extraplanar molecular gas in a Virgo spiral using the ALMA

  • Lee, Bumhyun;Chung, Aeree
    • 천문학회보
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    • 제41권2호
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    • pp.61.3-62
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    • 2016
  • NGC 4522 is a spiral galaxy located in the Virgo cluster which appears to be undergoing active ram pressure stripping due to the intracluster medium (ICM). What makes this galaxy special is the extraplanar CO gas, some of which coincides with the extraplanar $H{\alpha}$ patches. As one of the few cases where the interstellar molecular gas is thought to have been pushed out from the stellar disk by the ICM, this galaxy provides an opportunity to study the impact of ICM pressure on the dense/star forming gas and its fate in the extraplanar space after stripping. In order to probe detailed molecular gas properties inside and outside the stellar disk and the associated star formation activities, we have observed NGC 4522 in 12CO (1-0) and 13CO (1-0) using the ALMA. We have targeted two regions, one around the center of the galaxy and one centered on the peak of the extraplanar CO, detecting both lines in both regions. Particularly, this is the first case where 13CO gas has been detected outside the stellar disk in a galaxy undergoing ram pressure stripping. In this work, we present preliminary results from the ALMA observations and discuss the evolution of molecular gas properties and star formation activities inside and outside the stellar disk.

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Ram Pressure Stripping of an elliptical galaxy in Abell 2670

  • Sheen, Yun-Kyeong;Smith, Rory;Jaffe, Yara;Kim, Minjin;Yi, Sukyoung
    • 천문학회보
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    • 제41권2호
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    • pp.34.3-35
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    • 2016
  • Ram pressure stripping of early-type galaxies has been largely neglected until now because of their gas poor nature. MUSE IFU observation vividly reveal the presence of star-forming blobs and ionised gas tails, around an early-type galaxy in Abell 2670. The galaxy was identified as a post-merger galaxy with disturbed faint features, in MOSAIC 2 deep optical images. The imaging also revealed a series of star-forming blobs, situated in the direction facing away from the cluster centre. Thanks to the revolutionary wide field-of-view of the MUSE, combined with 8.2-m VLT (UT-4) at Cerro Paranal, we could simultaneously obtain IFU spectra of the blobs, as well as the galaxy. The MUSE spectra clearly confirms that the star-forming blobs are associated with the early-type galaxy. Moreover, MUSE reveals long ionised-gas tails, emanating from the galaxy. The quantity of gas indicates a gas rich progenitor has merged with the early-type galaxy. However the direction of the tails and blobs, and the blob morphology, appears to indicate that strong ram-pressure stripping may have stripped out gas brought in by the merger. We will present kinematic structure of the whole system (the galaxy, star-forming blobs, and gas tails), as well as the star formation history of the system, supporting a scenario where a recent galaxy merger is subjected to cluster environmental mechanisms.

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유각 와편모조류 Pfiesteria piscicida (Dinophyceae)의 형태분석 (Visualization of Thecal Plates of Lightly Armored Dinoflagellates Cryptoperidiniopsis brodyi and Pfiesteria piscicida (Dinophyceae))

  • 박태규;배헌민;강양순
    • 한국환경과학회지
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    • 제18권1호
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    • pp.15-19
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    • 2009
  • Early studies claimed that heterotrophic dinoflagellates Pfiesteria piscicida and related genera may produce a putative water-soluble toxin that causes death of fish and other marine animals. Several methods were tested to visualize plate morphology of Cryptoperidiniopsis brodyi and Pfiesteria piscicida. Cellulose plates of cells were exposed and visualized- by a membrane stripping method using Triton X-100. While calcofluor M2R white stain could readily bind to the thecal plates, details of the plate tabulation were difficult to observe. Fixation with osmium tetroxide $(OsO_4)$ produced well preserved cells with little morphological distortion, but thecal plates could not be visualized. Scanning electron microscopy (SEM) observation using the membrane stripping method showed distinctive plate tabulations between C. brodyi and P. piscicida suggesting that this method is a useful tool for morphological identification of lightly armored dinoflagellates.