• Title/Summary/Keyword: Strength decrease

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Effects of Molecular Weight of PC on Mechanical Properties of PC/ABS Blends using High-Shear Rate Processing

  • Lee, Eun Ju;Park, Hee Jung;Kim, Se Mi;Lee, Seung Goo;Lee, Kee Yoon
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.343-348
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    • 2018
  • Each of the two polycarbonates (PC) of different molecular weights was blended with acrylonitrile-butadiene-styrene (ABS) under high-shear rate processing to afford PC/ABS. Sizes of ABS dispersed phases and mechanical properties of PC/ABS blends were investigated and high-shear rate processing of PC/ABS was carried out by changing screw speed and processing time. Prepared specimens were examined by scanning electron microscope (SEM) to observe morphology changes. Sizes of ABS dispersed phases in PC/ABS blends were observed to decrease gradually as screw speeds increased. Tensile strengths and elongations of specimens were investigated by universal testing method (UTM) to study the influence of molecular weight of PC exerting on PC/ABS blends. As a result, PC1/ABS blends (PC1: higher molecular weight PC) exhibited more strengthened properties than PC2/ABS (PC2: lower molecular weight PC). The tensile strength of PC1/ABS showed an increasing tendency when the screw speed increased, and the elongation did not show a significant decrease, but increased slightly with increasing shear time at a constant screw speed of 1000 rpm.

Physical and Mechanical Properties of Cementitious Specimens Exposed to an Electrochemically Derived Accelerated Leaching of Calcium

  • Babaahmadi, Arezou;Tang, Luping;Abbas, Zareen;Martensson, Per
    • International Journal of Concrete Structures and Materials
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    • v.9 no.3
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    • pp.295-306
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    • 2015
  • Simulating natural leaching process for cementitious materials is essential to perform long-term safety assessments of repositories for nuclear waste. However, the current test methods in literature are time consuming, limited to crushed material and often produce small size samples which are not suitable for further testing. This paper presents the results from the study of the physical (gas permeability as well as chloride diffusion coefficient) and mechanical properties (tensile and compressive strength and elastic modulus) of solid cementitious specimens which have been depleted in calcium by the use of a newly developed method for accelerated calcium leaching of solid specimens of flexible size. The results show that up to 4 times increase in capillary water absorption, 10 times higher gas permeability and at least 3 times higher chloride diffusion rate, is expected due to complete leaching of the Portlandite. This coincides with a 70 % decrease in mechanical strength and more than 40 % decrease in elastic modulus.

Rubber gaskets for fuel cells-Life time prediction through acid ageing

  • Kim, Mi-Suk;Kim, Jin-Kuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.47-51
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    • 2007
  • The present paper reports the life time prediction of Acrylonitrile-Butadiene rubber (NBR) fuel cell gasket materials as a function of operational variables like acid concentration, ageing time and temperature. Both material and accelerated acid-heat aging tests were carried out to predict the useful life of the NBR rubber gasket for use as a fuel cell stack. The acid ageing of the gasket compounds has been investigated at 120, 140 and $160^{\circ}C$, with aging times from 3 to 600 h and increasing acid ($H_2SO_4$) concentrations of 5, 6, 7 and 10 vol%. Material characteristics the gas compound such as cross-link density, tensile strength and elongation at break were studied. The hardness of the NBR rubber was found to decrease with decreasing acid concentration at both 120 and $140^{\circ}C$, but at $160^{\circ}C$ interestingly the hardness of the NBR rubber increased abruptly in a very short time at different acid concentrations. The tensile strength and elongation at break were found to decrease with increase in both the acid concentrate ion & temperature. The life time of the compounds were evaluated using the Arrhenius equation.

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Large Scale Applications of Nanocellulosic Materials - A Comprehensive Review -

  • Lindstrom, Tom;Naderi, Ali;Wiberg, Anna
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.5-21
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    • 2015
  • The common production methods of nanocellulosic (cellulosic nanofibrils, CNF) materials from wood are being reviewed, together with large scale applications and particularly papermaking applications. The high energy demand for producing CNF has been one particular problem, which has been addressed over the years and can now be considered solved. Another problem was the clogging of homogenizers/microfluidizers, and the different routes to decrease the energy demand. The clogging tendency, related to the flocculation tendency of fibres is discussed in some detail. The most common methods to decrease the energy demand are TEMPO-oxidation, carboxymethylation and mechanical/enzymatic pre-treatments in the order of increased energy demand for delamination. The rheology characteristics of CNF materials, i.e. the high shear viscosity, shear thinning and the thixotropic properties are being illuminated. CNF materials are strength adjuvants that enhance the relative bonded area in paper sheets and, hence increase the sheet density and give an increased strength of the paper, particularly for chemical pulps. At the same time papers obtain a lower light scattering, higher hygroexpansion and decreased air permeability, similar to the effects of beating pulps. The negative effects on drainage by CNF materials must be alleviated through the appropriate use of microparticulate drainage aids. The use of CNF in films and coatings is interesting because CNF films and coatings can provide paper/board with good oxygen barrier properties, particularly at low relative humidities. Some other high volume applications such as concrete, oil recovery applications, automotive body applications and plastic packaging are also briefly discussed.

The Effects of Tai Chi Exercise on Physical Function, Stress and Depression in Middle Aged Women with Osteoarthritis (태극권 운동이 골관절염 중년여성의 신체기능, 스트레스 및 우울에 미치는 효과)

  • Lee, Sook-Ryon;Park, Hyoung-Sook;Cho, Gyoo-Yeong
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.17 no.2
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    • pp.159-168
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    • 2010
  • Purpose: The purpose of this study was to identify the effects of 12 weeks of Tai Chi exercise on physical function, stress and depression in middle aged women with osteoarthritis. Method: The research design was a nonequivalent control group pretest-posttest design. Forty two participants were assigned to either the experimental group (21) or control group (21). Frequency, percentages, mean, standard deviations, $X^2$-test, Wilcoxon rank sum test and repeated measured ANOVA with SPSS 12.0/PC program were used to analyzed the collected data. Results: For physical function the physical fitness of the experimental group improved significantly more than the control group: Leg strength, balance, flexibility and grip strength. Difficulty of performing activity had a tendency of decrease. Stress showed a tendency of as time passed but the decrease was not significant. Depression decreased and the change was significant. Conclusion: The Tai Chi exercise was effective in improving physical function and reducing the stress and depression of middle aged women with osteoarthritis. Therefore the Tai Chi exercise could be used as a nursing intervention for osteoarthritis in middle aged women.

Comparison of the Effects of an Exercise Program in Non-obese and Obese Women (정상체중여성과 비만여성에게 시행한 운동 프로그램의 효과 비교)

  • Lee, Kun-Ja;Yi, Yeo-Jin;Kim, Cha-Nam
    • Journal of Korean Academy of Nursing
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    • v.37 no.5
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    • pp.684-692
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    • 2007
  • Purpose: The purpose of this study was to compare the effects of an exercise program on physical fitness, obesity indices, and blood lipids in cases of non-obese and obese women. Method: Data was collected from May, 2006 to November, 2006 in a public health center. All Subjects(37 women) participated in an exercise program that consisted of Latin dance, muscular strength training, and dumbbell exercises. Thirty-seven women were divided into two groups(16 non-obese women and 21 obese women) by %body fat. After 8 weeks, the effects of treatment were compared between pre-test and post-test in each group. Results: Physical fitness(abdominal muscle strength, muscle endurance, flexibility, agility, balance) was significantly different between the pre-test and post-test in the non-obese and obese group. Obesity indices(body weight, BMI) was significantly different in obese women after the 8-week exercise program. There was no decrease of blood lipids in either group. Conclusion: These findings indicate that an exercise program could be an effective nursing intervention to increase physical fitness in non-obese and obese women and to decrease obesity indices(body weight, BMI) in obese women.

Effect of firing temperatures on alkali activated Geopolymer mortar doped with MWCNT

  • Khater, H.M.;Gawwad, H.A. Abd El
    • Advances in nano research
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    • v.3 no.4
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    • pp.225-242
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    • 2015
  • The current investigation aims to study performance of geopolymer mortar reinforced with Multiwalled carbon nanotubes upon exposure to $200^{\circ}C$ to $1000^{\circ}C$ for 2 hrs. MWCNTs are doped into slag Geopolymer mortar matrices in the ratio of 0.0 to 0.4, % by weight of binder. Mortar composed of calcium aluminosilicate to sand (1:2), however, binder composed of 50% air cooled slag and 50% water cooled slag. Various water / binder ratios in the range of 0.114-0.129 used depending on the added MWCNT, while 6 wt., % sodium hydroxide used as an alkali activator. Results illustrate reduction in mechanical strength with temperature except specimens containing 0.1 and 0.2% MWCNT at $200^{\circ}C$, while further increase in temperature leads to decrease in strength values of the resulting geopolymer mortar. Also, decrease in firing shrinkage with MWCNT up to 0.1% at all firing temperatures up to $500^{\circ}C$ is observed, however the shrinkage values increase with temperature up to $500^{\circ}C$. Further increase on the firing temperature up to $1000^{\circ}C$ results in an increase in the volume due to expansion.

Removal of Pb(II) and Cd(II) From Aqueous solution Using Oxidized Activated Carbons Developed From Pecan Shells.

  • Youssef, A.M.;EL-Khouly, Sahar M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.9 no.1
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    • pp.8-16
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    • 2008
  • Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.

Dielectric Recovery Characteristics between Poles of 800kV Model Interrupter -I. Effects or separation between Moving Main Contact and Moving Arcing Contact- (800kV 모델차단부의 극간 절연회복특성 -I. 가동주접점과 가동아크접점간 이격거리의 변화에 대한 영향분석-)

  • Shin, Y.J.;Park, K.Y.;Chang, K.C.;Song, K.D.;Jeong, J.K.;Song, W.P.;Kang, J.H.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.270-273
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    • 1994
  • The capacitive current breaking capability as well as the short circuit current breaking capability is a very important factor in the performance of a circuit breaker. The dielectric recovery capability between poles should be considered in the desist of a circuit breaker because approximately two times of the maximum power system voltage might be applied between poles after the capacitive current be interrupted. The electric field and flow field analyses were utilized in the calculation of dielectric recovery characteristics between poles of 800kV model interrupter. The results show that the separation between moving main contact and moving arcing contact will affect to decrease significantly the electric field strength of a moving arcing contact and an insulation cover, to increase slightly the electric field strength of a fixed arcing contact and to decrease consequently the dielectric recovery capability between poles of the interrupter.

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Demand response modification factor for the investigation of inelastic response of base isolated structures

  • Cheraghi, Rashid Eddin;Izadifarda, Ramezan Ali
    • Earthquakes and Structures
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    • v.5 no.1
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    • pp.23-48
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    • 2013
  • In this study, the effect of flexibility of superstructures and nonlinear characteristics of LRB (Lead Rubber Bearing) isolator on inelastic response of base isolated structures is investigated. To demonstrate the intensity of damage in superstructures, demand response modification factor without the consideration of damping reduction factor, demand RI, is used and the N2 method is applied to compute this factor. To evaluate the influence of superstructure flexibility on inelastic response of base isolated structures, different steel intermediate moment resisting frames with different heights have been investigated. In lead rubber bearing, the rubber provides flexibility and the lead is the source of damping; variations of aforementioned characteristics are also investigated on inelastic response of superstructures. It is observed that an increase in height of superstructure leads to higher value of demand RI till 4-story frame but afterward this factor remains constant; in other words, an increase in height until 4-story frame causes more damage in the superstructure but after that superstructure's damage is equal to the 4-story frame's. The results demonstrate that the low value of second stiffness (rubber stiffness in LRBs) tends to show a significant decrease in demand RI. Increase in value of characteristic strength (yield strength of the lead in LRBs) leads to decrease in the demand RI.