• Journal of the Korean Chemical Society
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• v.51 no.1
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• pp.21-30
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• 2007

A multiwavelength spectrophotometric titration method was applied to study protolytic constants of four water-soluble vitamins, folic acid(vitamin B9 or B0), thiamine(vitamin B1), riboflavin(vitamin B2) and pyridoxal (vitamin B6) in binary ethanol-water mixtures at 25oC and an ionic strength of 0.1M NaNO3. The protolytic equilibrium constants, spectral profiles, concentration diagrams and also the number of components has been calculated from the curve fitting of the pH-absorbance data with appropriate mass balance equations by an established factor analysis model. DATAN program was used for determination of acidity constant and SPECFIT program was used for calculation of standard deviations and partial correlation coefficients. A glass electrode calibration procedure based on the four parameter equation pH=α+SpcH+JH+[H+]+ JOH-Kw/[H+] based on the Gran,s plots was used to obtain pH-readings in the concentration scale (pcH). The effect of the solvent on the protolytic constants was discussed.

• Journal of the Earthquake Engineering Society of Korea
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• v.6 no.3
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• pp.11-21
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• 2002

The evaluation of displacement ductility is performed by direct method through tracking the inelastic hysteretic behavior of RC bridge columns subject to cyclic loading using a flexibility-based fiber element mode. To reasonably track the inelastic behavior until the RC bridge column reaches its ultimate state, the average stress-average strain relations and joint elements, which agree well with experiments, are modified and applied considering the tension stiffening behavior and discontinuous displacement between the column and its base. In addition the evaluation of displacement ductility is performed by a direct method easily applicable to numerical analysis. Locations for the integration points, values for the post-crushing concrete strength and low-cycle fatigue failure of longitudinal reinforcement that affect the calculation of yielding and ultimate displacements are proposed for the application to flexibility-based fiber element model. Since less than 10% of error occurs during the displacement ductility analysis, the yielding and ultimate displacements evaluated by the applied analysis method and model appear to be valid.

• Tunnel and Underground Space
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• v.23 no.4
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• pp.261-270
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• 2013

As part of the development of the 3-D geologic modeling software, this study addresses on new development of software modules that can perform the analysis and visualization of the fracture network system in 3-D. The developed software modules, such as BOUNDARY, DISK3D, FNTWK3D, CSECT and BDM, are coded on Microsoft Visual Studio platform using the MFC and OpenGL library supported by C++ program language. Each module plays a role in construction of analysis domain, visualization of fracture geometry in 3-D, calculation of equivalent pipes, production of cross-section map and management of borehole data, respectively. The developed software modules for analysis and visualization of the 3-D fracture network system can be used to tackle the geomechanical problems related to strength, deformability and hydraulic behaviors of the fractured rock masses. All these benefits will further enhance the economic competitiveness of the domestic software industry.

• Journal of The Korean Astronomical Society
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• v.36 no.2
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• pp.55-60
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• 2003

In Lee, Kang & Byun (2001) the discovery of Raman scattered 6545 A feature was reported in symbiotic stars and the planetary nebula M2-9. The broad emission feature around 6545 A is formed as a result of Raman scattering of He II n = 6 $\to$ n = 2 photons by atomic hydrogen. In this paper, we introduce a method to compute the equivalent width of He II $\lambda$ 1025 line and present an optical spectrum of the symbiotic star RR Telescopii as an example for a detailed illustration. In this spectrum, we pay attention to the broad H$\alpha$ wings and the Raman scattered He II 6545 feature. The broad Ha wings are also proposed to be formed through Raman scattering of continuum around Ly$\beta$ by Lee (2000), and therefore we propose that the equivalent width of the He II $\lambda$ 1025 emission line is obtained by a simple comparison of the strengths of the 6545 feature and the broad H$\alpha$ wings. We prepare a template H$\alpha$ wing profile from continuum radiation around Ly$\beta$ with the neutral scattering region that is supposed to be responsible for the formation of Raman scattered He II 6545 feature. Isolation of the 6545 feature that is blended with [N II] $\lambda$ 6548 is made by using the fact that [N II] $\lambda$ 6584 is always 3 times stronger than [N II] $\lambda$ 6548. We also fit the 6545 feature by a Gaussian which has a width 6.4 times that of the He II $\lambda$ 6527 line. A direct comparison of these two features for RR Tel yields the equivalent width $EW_{Hel025} = 2.3{\AA}$ of He II $\lambda$ 1025 line. Even though this far UV emission line is not directly observable due to heavy interstellar extinction, nearby He II lines such as He II $\lambda$ 1085 line may be observed using far UV space instruments, which will verify this calculation and hence the origins of various features occurring in spectra around H$\alpha$.

• Korean Journal of Materials Research
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• v.5 no.7
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• pp.869-879
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• 1995

TiAi intermetallic compound has been extensively studied for possible high temperature structural applications because of its high specific strength at high temperature, high creep resistance, and good oxidation resistance at elevated temperatures. In addition to its good properties, an economic manufacturing routes should be developed for this material to be used more extensively. One of the promising route in manufacturing TiAl intermetallics is the Self-propagating High-temperature Synthesis (SHS) method. Thus in this study, an attempt was made to study the mechanism of the SHS process in TiAl synthesis. The composition of the sample was Ti-(45, 50, 53)at% Al and the microstuctures of the products were analyzed using optical microscope and scanning electron microscope. When the phases formed at the main SHS reaction of whicyh combustion temperature is higher than the melting temperature of aluminum were identified as TiAl and Ti$_3$Al ; Ti$_3$Al cores surrounded by TiAl phase. In order to increase the combustion temperature, carbon was added 5 and 10at.%. When the carbon content was 10at.%, the heat of the reaction was large enough to melt the phase formed and that is consistent with the theoretical calculation results of the adiabatic temperature. The combution temperatue, which was measured by a computer data acquisition system, increased with the carbon content. The phases formed from the reaction involving the carbon added were indentified as TiAl and Ti$_2$AlC using XRD. The vickers hardness of the reaction product increased with the carbon content.

• Journal of Environmental Science International
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• v.27 no.3
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• pp.203-217
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• 2018

For this study, WRF numerical modeling was performed, using RDAPS information for input data on typhoons affecting the Korean peninsula to produce wind data of 700hPa. RAM numerical modeling was also used to calculate 3-second gusts as the extreme wind speed. After comparing wind speeds at an altitude of 10 m to evaluate the feasibility of WRF numerical modeling, modeled values were found to be similar with measured ones, reflecting change tendencies well. Therefore, the WRF numerical modeling results were verified. As a result of comparing and analyzing these wind speeds, as calculated through RAM numerical modeling, to evaluate applicability for disaster preparedness, change tendencies were observed to be similar between modeled and measured values. In particular, modeled values were slightly higher than measured ones, indicating applicability for the prevention of possible damage due to gales. Our analysis of 3-second gusts during the study period showed a high distribution of 3-second gusts in the southeast region of the Korean peninsula from 2002-2006. The frequency of 3-second gusts increased in the central north region of Korea as time progressed. Our analysis on the characteristics of 3-second gusts during years characterized by El $Ni{\tilde{n}}o$ or La Nina showed greater strength during hurricanes that affected the Korean peninsula in El $Ni{\tilde{n}}o$ years.

• Tunnel and Underground Space
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• v.24 no.1
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• pp.81-88
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• 2014

In the course of performing the stability analysis of rock structures, there are times when the strength of the Hoek-Brown rock mass needs to be understood in terms of the internal friction angle and cohesion. In this case, the original Hoek-Brown criteion, giving the relationship between ${\sigma}_1$ and ${\sigma}_3$ at failure, have to be transformed to the corresponding Mohr envelope. A new approach to derive the Mohr envelope of the Hoek-Brown criterion is suggested in this study. The new method is based on the Londe's transformation making the stress components dimensionless. The correctness of the derivation leading to the new ${\tau}-{\sigma}$ relationship is confirmed by comparing the calculation results with the Bray's solution through a verification example.

• Applied Biological Chemistry
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• v.37 no.2
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• pp.124-129
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• 1994

The rate of hydrolysis of insecticidal $O,O-diethyl-{\alpha}-cyanobenzylideneamino-oxyphosphorothioate\;(Volaton^{\circledR})$ has been studied in 25% (v/v) aqueous dioxane. On the basis of solvent effect (pH 6.0; m=0.21, n=1.55, pH 12.0; m=0.42, n=3.14 & $|m|{\ll}|l|$), general base catalysis, hydrolysis product analysis, calculation of molecular orbital (MO) and rate equation, it may be concluded that the hydrolysis of Volaton proceeds through the $A_{AC}2$ mechanism via trigonal bipyramidal $(sp^3d^2)$ intermediate below pH 7.0, while above pH 9.0 the hydrolysis proceeds through the $B_{AC}2$ mechanism. Hydrolysis reactivity of Volaton depends on positive charge strength $(p{\gg}{\alpha}C_2)$ rather than steric hindrance. In the range between pH 7.0 and pH 9.0, these two reactions occur competitively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.3
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• pp.213-220
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• 2005

Recently, a concern to verify the displacement capacity of shear wall has been arised to produce suitable data for the performance based design. In this paper, a process is presented to evaluate the displacement capacity of shear wall. The displacement of shear wall is expressed as the superposition of shear and flexural deformation. Variable crack angle truss model with a modification and sectional analysis method are used in calculating shear and flexural displacement, respectively. In addition, the effect of axial force and the contribution of vertical and horizontal reinforcements in wall are considered in the analysis. The accuracy of proposed method is evaluated by the comparison calculation results with previous test results. From the comparison, it was shown that the hysteretic behavior of shear wall could be well predicted by using the process. In the case with flange wall, however, the method overestimates the contribution of flange wall for strength and stiffness and underestimates for displacement capacity.

• Journal of Adhesion and Interface
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• v.5 no.2
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• pp.14-26
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• 2004

For reliable determination of mechanical characteristics of adhesively bonded joints used e.g. as input data for computer-aided design of complex components, the thick-adherend tensile-shear test according to ISO 11003-2 is the most important material testing method. Although the total displacement of the joint is measured across the polymer layer directly in the overlap zone in order to minimize the influence of the stepped adherends, the substrate deformation must be taken into account within the framework of the evaluation of the shear modulus and the maximum shear strain, at least when high-strength adhesives are applied. In the standard ISO 11003-2 version of 1993, it was prescribed to perform the substrate deformation correction by means of testing a one-piece reference specimen. The authors, however, pointed to the excessive demands on the measuring accuracy of the extensometers connected with this technique in industrial practice and alternatively proposed a numerical deformation analysis of a dummy specimen. This idea of a mathematical correction was included in the revised ISO 11003-2 version of 2001 but in the simplified form of an analytical method based on Hooke's law of elasticity for small strains. In the present work, it is shown that both calculation techniques yield considerably discordant results. As experimental assessment would require high-precision distance determination (e.g. laser extensometer), finite element analyses of the deformation behavior of the bonded joint are performed in order to estimate the accuracy of the obtained substrate deformation corrections. These simulations reveal that the numerical correction technique based on the finite element deformation modeling of the reference specimen leads to considerably more realistic results.