• 제목/요약/키워드: Storage modulus

검색결과 335건 처리시간 0.03초

유럽산 바이올린 용재의 비중과 년륜폭이 소재의 음향적 성질에 미치는 영향 (Effect of specific gravity and annual ring width on the acoustical properties of European lumber used in violin making)

  • 정우양;홍병화
    • 한국가구학회지
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    • 제10권1호
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    • pp.57-63
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    • 1999
  • This study was carried out to analyze the relationship between basic physical properties and acoustical characteristics of imported violin wood and to offer the information on raw material procurement and incoming-material quality control to domestic violin makers which have purchased most raw materials from European exporting countries at high expense. Equilibrium moisture content of European spruce with lower specific gravity after the prolonged storage was rather higher than that of European maple with higher specific gravity. The specific gravity of spruce increased with decreasing annual ring width, however, that of narrower annual ring. Increasement in specific gravity enhanced the dynamic Young's modulus of both wood species, but influenced the vibration energy loss by internal friction differently between two species. For dynamic MOE, qurater-sawn spruce was higher than the flat-sawn, but maple showed the reverse directional characteristics. Consequently, it would be well for violin makers to establish the standard for materials and quality control system to assure the quality of their violin products.

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지하 대공동의 3차원 굴착거동에 관한 연구 (Three Dimensional Behaviour of the Rock Mass around a Large Rock Cavern during Excavation)

  • 이영남;서영호;주광수
    • 터널과지하공간
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    • 제8권1호
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    • pp.67-73
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    • 1998
  • This paper presents the results of deformation measurement and numerical analysis carried out to study the behaviour of the rock mass around large underground oil storage caverns. Displacements during excavation have been monitored using borehole extensometers which had been installed before the excavation of caverns proceeded. Numerical analysis has been carried out to examine the three-dimensional behaviour of rock and the face advance effect. The input parameters for this analysis were determined from the results of laboratory and field tests. The deformation modulus of the rock mass was determined from plate loading test at the site and in-situ stresses were measured from the overcoring method with USBM deformation gauge. The results from this study gave a clear picture for three-dimensional behaviour of the rock mass, hence would be used for the optimum design.

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아크릴 중합체 및 아크릴-이타코닉산 공중합체/ 디메틸술폭시드 용액의 유변학적 특성의 시간의존성 (Time Dependence of the Rheological Properties of the Solutions of Polyacrylontrile and Acrylonitrile-Itaconic Acid Copolymer in Dimethyl sulfoxide)

  • 이남순
    • 한국염색가공학회지
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    • 제13권6호
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    • pp.435-440
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    • 2001
  • This study investigates the rheological properties of in-situ polymerized solutions of polyacrylonitrile(PAN) and acrylonitrile(AN) -itaconic acid(IA) in dimethyl sulfoxide(DMSO) in terms of temperature, concentration, and time. The complex viscosity and storage modulus of the solutions were generally increased with elapsing time, which is ascribable to the three-dimensional pseudostructures formed by strong inter- or Intra-molecular attractions through Polar -CN and -COOH groups. The three-dimensional pseudonetworks would lead to relation of the acrylic solutions in long term. This was more noticeable at higher temperature within the temperature range examined. In the case of 20% solutions one can not observe lower Newtonian flow region in the viscosity curve. Disappearance of lower Newtonian flow region is indicative of heterogeneity of the solution system. Casson Plot of the viscosity data revealed that 20% solutions of PAN and AN-IA copolymer in DMSO clearly demonstrated positive yield stress, ascertaining formation of pseudostructures in the solution systems.

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아크릴 중합체 및 아크릴-이타코닉산 공중합체/디메틸술폭시드 용액의 유변학적 특성의 시간의존성 (Time Dependence of the Rheological Properties of the Solutions of Polyacrylontrile and Acrylonitrile-Itaconic Acid Copolymer in Dimethyl sulfoxide)

  • 이남순
    • 한국염색가공학회지
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    • 제13권6호
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    • pp.77-77
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    • 2001
  • This study investigates the rheological properties of in-situ polymerized solutions of polyacrylonitrile(PAN) and acrylonitrile(AN)-itaconic acid(IA) in dimethyl sulfoxide(DMSO) in terms of temperature, concentration, and time. The complex viscosity and storage modulus of the solutions were generally increased with elapsing time, which is ascribable to the three-dimensional pseudostructures formed by strong inter- or intra-molecular attractions through Polar -CN and -COOH groups. The three-dimensional pseudonetworks would lead to gelation of the acrylic solutions in long term. This was more noticeable at higher temperature within the temperature range examined. In the case of 20% solutions one can not observe lower Newtonian flow region in the viscosity curve. Disappearance of lower Newtonian flow region is indicative of heterogeneity of the solution system. Casson Plot of the viscosity data revealed that 20% solutions of PAN and AN-IA copolymer in DMSO clearly demonstrated positive yield stress, ascertaining formation of pseudostructures in the solution systems.

Flow behavior of high internal phase emulsions and preparation to microcellular foam

  • Lee, Seong Jae
    • Korea-Australia Rheology Journal
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    • 제16권3호
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    • pp.153-160
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    • 2004
  • Open microcellular foams having small-sized cell and good mechanical properties are desirable for many practical applications. As an effort to reduce the cell size, the microcellular foams combining viscosity improvers into the conventional formulation of styrene and water system were prepared via high internal phase emulsion polymerization. Since the material properties of foam are closely related to the solution properties of emulsion state before polymerization, the flow behavior of emulsions was investigated using a controlled stress rheometer. The yield stress and the storage modulus increased as viscosity improver concentration and agitation speed increased, due to the reduced cell size reflecting both a competition between the continuous phase viscosity and the viscosity ratio and an increase of shear force. Appreciable tendency was found between the rheological data of emulsions and the cell sizes of polymerized foams. Cell size reduction with the concentration of viscosity improver could be explained by the relation between capillary number and viscosity ratio. A correlative study for the cell size reduction with agitation speed was also attempted and the result was in a good accordance with the hydrodynamic theory.

Preparation of photo-crosslinkable silk sericin hydrogel

  • Kim, Jung Eun;Kim, Eui Hwa;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • 제36권1호
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    • pp.10-14
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    • 2018
  • A photo-crosslinkable sericin hydrogel has been prepared by introducing methacrylate groups on sericin. Lysine was the amino acid for methacrylation and the degree of methacrylation was increased with the amount of methacrylic anhydride added. When the concentration of methacrylic anhydride was 20% of sericin, 0.635 mmol/g of methacrylate group could be introduced. The storage modulus of sericin hydrogel was increased proportionally with the degree of methacrylation. However, the swelling ratio of sericin hydrogel decreased with the increase of methacrylation.

Effects of Moisture Content on Non-Fracture Dynamic Properties and Fracture Quality of Pacific Whiting Surimi

  • Esturk, Okan;Park, Jae-Won;Raik, Moo-Yeol;Kim, Byung-Yong
    • Food Science and Biotechnology
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    • 제15권6호
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    • pp.856-859
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    • 2006
  • The effects of moisture content on non-fracture dynamic properties and fracture gel quality of Pacific whiting surimi were investigated to determine their relationships. Surimi samples were tested at various moisture contents (75, 78, and 81 %). Torsion test showed that shear stress decreased rapidly and strain values decreased gradually as moisture concentration increased. Dynamic storage modulus (G') also decreased as moisture content increased. A strong positive correlation ($R^2=0.90$ to 0.99) was found between the G' measured at temperatures between 10 and $45^{\circ}C$ and fracture stress values. The results indicate that dynamic rheological measurements could be used as a tool for early gel quality assessment.

염수환경을 고려한 섬유강화 복합재의 내구성 평가 (Durability of Fiber Reinforced Composites under Salt Water Environments)

  • 윤성호;황영은
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2005년도 춘계학술대회 논문집
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    • pp.391-396
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    • 2005
  • Salt water spray test and salt water immersion test were experimentally conducted in order to investigate the durability of fiber reinforced composites under salt water environment. The specimens were made of glass fabric reinforcement and phenolic resin. Mechanical test was performed to obtain mechanical properties such as tensile properties, flexural properties, and shear properties by varying with exposure times. Also dynamic mechanical test and FTIR were conducted to investigate a change in chemical structure as well as thermal analysis properties such as storage shear modulus, loss shear moduls, and tan ${\delta}$. According to the results, salt water environment has effected on mechanical properties and thermal analysis properties and especially the durability of glass fabric/phenolic composites were severely affected on salt water immersion environment rather than salt water spray environment.

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Acrylic Polyol 함량을 달리한 폴리우레탄 제품의 형태학적 열적 및 동적·기계적 성질 (Morphological, Thermal and Dynamic Mechanical Properties of Polyurethane Product with Various Contents of Acrylic Polyol)

  • 김태성;박찬영
    • Elastomers and Composites
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    • 제48권4호
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    • pp.276-281
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    • 2013
  • acrylic polyol로 개질한 polyester형 polyurethane foam을 quasi prepolymer법으로 제조하였다. 열적 및 동적 기계적 성질은 thermal gravimetric analysis 및 dynamic mechanical analysis에 의하여 분석하였다. 또한 유리전이온도는 differential scanning calorimeter로 측정하였다. Acrylic polyol 함량이 증가함에 따라 TGA에 의해 측정한 열적 안정성은 약간 감소하였다. 그리고 acrylic polyol 함량이 증가함에 따라 저장 탄성률은 증가한 반면에 tan delta 값은 감소하였다.

Degradation and Rheological Properties of Biodegradable Nanocomposites Prepared by Melt Intercalation Method

  • Lee, Su-Kyong;Seong, Dong-Gi;Youn, Jae-Ryoun
    • Fibers and Polymers
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    • 제6권4호
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    • pp.289-296
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    • 2005
  • Biodegradable nanocomposites were prepared by mixing a polymer resin and layered silicates by the melt intercalation method. Internal structure of the nanocomposite was characterized by using the small angle X-ray scattering (SAXS) and transmission electron microscope (TEM). Nanocomposites having exfoliated and intercalated structures were obtained by employing two different organically modified nanoclays. Rheological properties in shear and extensional flows and biodegradability of nanocomposites were measured. In shear flow, shear thinning behavior and increased storage modulus were observed as the clay loading increased. In extensional flow, strain hardening behavior was observed in well dispersed system. Nanocomposites with the exfoliated structure had better biodegradability than nanocomposites with the intercalated structure or pure polymer.