• 제목/요약/키워드: Stoichiometry

검색결과 437건 처리시간 0.021초

The Study on Material Properties of Boron Phosphide

  • Hong, Kuen-Kee;Kim, Chui-Ju
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.243-246
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    • 2004
  • Boron Phosphide films were deposited on (111) Si substrate at $650^{\circ}C$, by the reaction of $B_2H_6$ with PH, using APCVD. $N_2$ was carried out as carrier gas. The optimal gas rates were 20 ml/min for B2H6, 60 ml/min for PH3 and 1 l/min for N2. After as grown the films were insitu annealed fur 1hour in $N_2$ ambient at $550^{\circ}C$ and measured. The measurement of AFM shows that the average surface roughness is $10.108{\AA}$ for the reaction temperature at $450^{\circ}C$ and $29.626{\AA}$ fur the reaction temperature at $650^{\circ}C$. The measurement of XRD shows that the films have the orientation of(1 0 1). Also, the measurement of AES is shown that the films have $B_{13}P_2$ stoichiometry. For the Result of microwaves absorbtion properties using VNA, it obtained the permittivity of BP about 8 between $1.5{\sim}2.5GHz$. In this study, it obtained the BP thin film by deposited in atmosphere pressure And BP thin film can be after to applicate as microwave absolution material is obtained.

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Formation of SiC layer on Single Crystal Si Using Hot-Filament Reactor

  • Kim, Hong-Suk;Park, In-Hoon;Eun, Kwang-Yong;Baik, Young-Joon
    • The Korean Journal of Ceramics
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    • 제4권1호
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    • pp.25-27
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    • 1998
  • The effect of gas activation on the formation of SiC layer on Si substrate using methane as a carbon source was investigated. Tungsten filaments, heated above 200$0^{\circ}C$, were used to activate the methane-hydrogen mixed gas. The dissociation of methane gas by the heated filament was enough to form a SiC layer successfully, which was very difficult without any activation. The SiC layer formed on the Si substrate was crystalline and nearly epitaxial as measured by X-ray diffraction. The SiC layer formed on the Si substrate was crystalline and nearly epitaxial as measured by X-ray diffraction. The stoichiometry was also close to 1:1. However, the characteristic of the SiC layer was dependent on the heat-treatment condition. The general behavior of the layer growth with the variables was discussed.

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ZnO 압전 박막을 이용한 고주파 SAW 필터 연구 (A Study on the ZnO Piezoelectric Thin Film SAW Filter for High Frequency)

  • 박용욱;신현용
    • 한국세라믹학회지
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    • 제40권6호
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    • pp.547-552
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    • 2003
  • RF 마그네트론 스퍼터링법을 이용하여 유리기판위에 인가전력 100 W, 1.33Pa, Ar/O2=50 : 50, 20$0^{\circ}C$ 그리고 타겟과 기판사이의 거리 4 cm의 조건으로 ZnO 압전 박막을 성장시켰다. 증착된 박막의 결정성, 표면형상, 화학적 결합비와 전기적 특성을 XRD, SEM, AFM, RBS와 electrometer를 이용하여 측정 분석하였다 제조된 박막은 우수한 c축 우선 배향성을 보였고 또한 화학 양론적인 결합비를 나타내었다. 전극 구조가 single 및 double IDT를 갖는 ZnO/1DT/glass SAW 필터를 제작하여 특성을 분석한 결과, 전파속도는 각각 2,589 m/sec, 2,533 m/sec이었고, 삽입손실은 -11 dB과 -21 dB 값을 나타내어 박막형 SAW 필터로 응용이 기대된다.

학습자의 인지 및 동기 변인들과 비유를 통한 개념 이해도의 관계 (The Relationships among Learners' Cognitive Variables, Motivational Variables, and Conceptual Understandings in Learning with Analogy)

  • 노태희;임희연;김창민;강석진
    • 한국과학교육학회지
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    • 제19권3호
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    • pp.471-478
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    • 1999
  • In this study, the relationships among learners' cognitive variables, motivational variables, and conceptual understandings in learning with analogy were investigated. The instruments regarding analogical reasoning ability, field dependence-independence, mental capacity, and logical thinking ability were administered. Some subtests (self-efficacy, expectancy, self-concept of ability, and value) of the Patterns of Adaptive Learning Survey were administered. After students learned with a worksheet that included analogy, a conception test regarding 'stoichiometry that included limiting reagent' was also administered. It was found that learners' conceptual understandings were significantly correlated with the logical thinking ability and the field dependence-independence among the cognitive variables, and the self-efficacy and the self-concept of ability among the motivational variables. The multiple regression analysis of the cognitive variables on conceptual understandings revealed that the logical thinking ability was the most significant predictor. The field dependence-independence also had predictive power. In the analysis of the motivational variables, the self concept of ability was the only significant predictor.

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우르소데옥시콜린산 및 케노데옥시콜린산의 베타시클로덱스트린 포접복합체의 물리화학적 특성비교 (Comparison of Physicochemical Properties between Ursodeoxycholic Acid and Chenodeoxycholic Acid Inclusion Complexes with ${\beta}-Cyclodextrin$)

  • 이승룡;정연복;한건;신재영
    • 약학회지
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    • 제38권3호
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    • pp.300-310
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    • 1994
  • Physicochemical properties for the inclusion complex of chenodeoxycholic acid(CDCA) and it's $7{\beta}-hydroxy$ epimer ursodeoxycholic acid(UDCA) with ${\beta}-cyclodextrin({\beta}-CyD)$ were studied. The formation of the complex in the solid state were confimed by polarized microscopy and differential scanning calorimetry(DSC). Proton nuclear magnetic resonance$(^1H-NMR)$spectroscopy showed that CDCA and UDCA form an inclusion complex with ${\beta}-CyD$ in aqueous solution. The 1 : 1 stoichiometry of the complex was dextermined by the continuous variation method. From DSC and $^1H-NMR$ studies, there were not any differences between CDCA and UDCA. Complex of CDCA and UDCA showed increase in solubility and dissolution compared with CDCA and UDCA alone, respectively. Solubility pattern of UDCA complex was pH independent but, CDCA complex was like that of CDCA. Dissolution rate increased markedly in case of UDCA complex compared with CDCA complex, especially in acidic pH value.

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MULTI-SCALE MODELS AND SIMULATIONS OF NUCLEAR FUELS

  • Stan, Marius
    • Nuclear Engineering and Technology
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    • 제41권1호
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    • pp.39-52
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    • 2009
  • Theory-based models and high performance simulations are briefly reviewed starting with atomistic methods, such as Electronic Structure calculations, Molecular Dynamics, and Monte Carlo, continuing with meso-scale methods, such as Dislocation Dynamics and Phase Field, and ending with continuum methods that include Finite Element and Finite Volume. Special attention is paid to relating thermo-mechanical and chemical properties of the fuel to reactor parameters. By inserting atomistic models of point defects into continuum thermo-chemical calculations, a model of oxygen diffusivity in $UO_{2+x}$ is developed and used to predict point defect concentrations, oxygen diffusivity, and fuel stoichiometry at various temperatures and oxygen pressures. The simulations of coupled heat transfer and species diffusion demonstrate that including the dependence of thermal conductivity and density on composition can lead to changes in the calculated centerline temperature and thermal expansion displacements that exceed 5%. A review of advanced nuclear fuel performance codes reveals that the many codes are too dedicated to specific fuel forms and make excessive use of empirical correlations in describing properties of materials. The paper ends with a review of international collaborations and a list of lessons learned that includes the importance of education in creating a large pool of experts to cover all necessary theoretical, experimental, and computational tasks.

Evaluation of geochemical processes affecting groundwater chemistry in Namwon, Korea

  • Kim, Kang-Joo;Natarajan Rajmohan;Kim, Hyung-Jung;Kim, Suk-Hwi;Hwang, Gab-Soo;Cho, Min-Joe;Lee, Sang-Ho
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.334-337
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    • 2004
  • Groundwater chemistry in Namwon area, Korea, was investigated to understand the contribution of geochemical processes on groundwater chemistry. For this study, a total of 279 groundwater samples were collected from 93 wells distributed over the study area. Higher concentrations of major ions are generally encountered in the shallow alluvial wells, suggesting that these chemicals are originated from the surface contamination sources. Mass balance analysis based on reaction stoichiometry reveals that the water chemistry is regulated by three major chemical processes: weathering of silicate/ carbonate minerals, input of C1/SO$_4$ salts, and nitrate generating processes. The results show that mineral weathering is the most dominating factor regulating the groundwater chemistry. However, the groundwaters with the higher salt concentration indicate the larger mineral weathering effect, suggesting that some part of the mineral weathering effect is also associated with the anthropogenic activities such as limes applied to the cultivated lands, carbonates (CaCO$_3$) in the cement materials.

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Si-N 코팅막의 기계적 물성 및 구조 분석 (Characterization of Silicon Nitride Coating Films)

  • 고철호;김봉섭;윤존도;김광호
    • 한국세라믹학회지
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    • 제42권5호
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    • pp.359-365
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    • 2005
  • Silicon nitride coating films with various ratios of nitrogen to silicon contents were prepared and characterized. The film was coated on silicon substrate by sputtering method with changing nitrogen gas flow rate in a chamber. The nitrogen to silicon ratio was found to have values in a range from 0 to 1.4. Coated film was characterized with scanning electron microscopy, transmission electron microscopy, electron probe microanalysis, nanoindentation scanning probe microscopy, x-ray photon spectrometry, and Raman spectrometry. Silicon nitride phase in all samples showed amorphous nature regardless of N/Si ratio. When N/Si ratio was 1.25, hardness and elastic modulus of silicon nitride film showed maximum with 22 GPa and 210 GPa, respectively. Those values decreased, when N/Si ratio was higher than 1.25. Raman spectrum showed that no silicon phase exist in the film. XPS result showed that the silicon-nitrogen bond was dominant way for atomic bonding in the film. The structure and property was explained with Random Bonding Model(RBM) which was consistent with the microstructure and chemistry analysis for the coating films.

Flexural wave를 이용한 고분자 전해질 연료전지 공기극 내에서의 플러딩 제거 (Removal of Flooding in a PEM Fuel Cell at Cathode by Flexural Wave)

  • 김경록;한성호;안득균;최영돈
    • 한국수소및신에너지학회논문집
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    • 제21권1호
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    • pp.35-41
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    • 2010
  • Water management is an important issue of PEM fuel cell operation. Water is the product of the electrochemical reactions inside fuel cell. If liquid water accumulation becomes excessive in a fuel cell, water columns will clog the gas flow channel. This condition is referred to as flooding. A number of researchers have examined the water removal methods in order to improve the performance. In this paper, a new water removal method that investigates the use of vibro-acoutic methods is presented. Piezo-actuators which are devices to generate the flexural wave are attached at the end of a cathode bipolar plate. Flexural wave is used to impart energy to resting droplets and thus cause movement of the droplets in the direction of the traveling wave.

MATLAB/Simulink를 이용한 자동차용 상압형 PEM 연료전지 시스템의 성능 및 효율 분석 연구 (A Study on the Analysis of the Performance and Efficiency of a Low-pressure Operating PEMFC System for Vehicle Applications Using MATLAB/Simulink)

  • 박래혁;김한상
    • 한국수소및신에너지학회논문집
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    • 제24권5호
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    • pp.393-400
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    • 2013
  • The air supply system has a significant effect on the efficiency of polymer electrolyte membrane fuel cell (PEMFC) systems. The performance and efficiency of automotive PEMFC systems are greatly influenced by their air supply system configurations. This study deals with the system simulation of automotive PEMFC systems using MATLAB/Simulink framework. In this study, a low-pressure operating PEMFC system adopting blower sub-module (turbo-blower) is modeled to investigate the effects of stack operating temperature and air stoichiometry on the parasitic power and efficiency of automotive PEMFC systems. In addition, the PEMFC net system efficiency and parasitic power of air supply system are mainly compared for the two types (low-pressure operating and high-pressure operating) of automotive PEMFC systems under the same net power conditions. It is suggested that the obtained results from this system approach can be applied for establishing the novel operating strategies for FC vehicles.