• 제목/요약/키워드: Stoichiometric number

검색결과 41건 처리시간 0.029초

주기적 불안정성을 가지는 충격파 유도 연소의 무차원 해석 (Nondimensional Analysis of Periodically Unstable Shock-Induced Combustion)

  • 최정열;정인석;윤영빈
    • 한국연소학회지
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    • 제1권2호
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    • pp.41-49
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    • 1996
  • A numerical study is conducted to investigate the periodically unstable shock induced combustion around blunt bodies in stoichiometric hydrogen-air mixtures. Euler equations are spatially discretized by upwind-biased third order scheme and temporally integrated by Runge-Kutta method. Chemistry model used in this study involves 8 elementary kinetics steps and 7 species. At a constant Mach number, the effects of projectile size, inflow pressure and inflow temperature are examined with Lehr#s experimental condition as a reference. In addition to oscillation frequency, characteristic distances and time averaged values are found from the result to find an relation with dimensionless parameters. As a result, it is found that the effects of inflow pressure and body size are very similar and $Damk{\ddot{o}}hler$ number plays an important role in determining the instability characteristics.

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탄화수소계 연료의 축소반응모델과 가솔린연료의 옥탄가 변화에 따른 자발화 지연시간 (Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of Gasoline with Different Octane Numbers)

  • 여진구
    • 한국자동차공학회논문집
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    • 제11권3호
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    • pp.13-19
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    • 2003
  • Mathematically simplified reaction scheme that simulates autoignitions of the end gases in spark ignition engines has been studied computationally. The five equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius preexponential constants, A, and heats of reaction for stoichiometric n-heptane/air, iso-octane/air, and their mixtures have all been optimised. The optimisation has been guided by Morley's correlation of the ratio of chain branching to linear termination rates with octane number. Comparisons between computed and experimental autoignition delay times have validated the Present simplified reaction scheme and the influences of octane number upon autoignition delay times have been computationally investigated. It has been found that both cool flame and high temperature direct reactions can have an effect on autoignition delay times.

A Study on Laminar Lifted Jet Flames for Diluted Methane in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Kwon, Oh Boong
    • 한국연소학회지
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    • 제20권3호
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    • pp.1-7
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    • 2015
  • The laminar lifted jet flames for methane diluted with helium and nitrogen in co-flow air have been investigated experimentally. Such jet flames could be lifted in both buoyancy-dominated and jet momentum dominated regimes (even at nozzle exit velocities much higher than stoichiometric laminar flame speed) despite the Schmidt number less than unity. Chemiluminescence intensities of $OH^*$ radical (good indicators of heat release rate) and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera and digital video camera at various conditions. It was shown that, an increase in $OH^*$ concentration causes increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime, an increase in radius of curvature in addition to the increased $OH^*$ concentration stabilizes such lifted flames. Stabilization of such lifted flames is discussed based on the stabilization mechanism.

Laminar Lifted Methane Jet Flames in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Lee, Byeong Jun;Kwon, Oh Boong
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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    • pp.83-86
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    • 2015
  • The Laminar lifted methane jet flames diluted with helium and nitrogen in co-flow air have been investigated experimentally. The chemiluminescence intensities of $OH^{\ast}$ and $CH_2O^{\ast}$ radicals and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera, monochromator and digital video camera. The product of $OH^{\ast}$ and $CH_2O^{\ast}$ is used as a excellent proxy of heat release rate. These methane jet flames could be lifted in buoyancy and jet dominated regimes despite the Schmidt number less than unity. Lifted flames were stabilized due to buoyancy induced convection in buoyancy-dominated regime. It was confirmed that increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration caused an increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime lifted flames were observed even for nozzle exit velocities much higher than stoichiometric laminar flame speed. An increase in radius of curvature in addition to the increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration stabilizes such lifted flames.

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Effect of Improving Accuracy for Effective Atomic number (EAN) and Relative Electron Density (RED) extracted with Polynomial-based Calibration in Dual-energy CT

  • Daehong Kim;Il-Hoon Cho;Mi-jo Lee
    • 한국방사선학회논문지
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    • 제17권7호
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    • pp.1017-1023
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    • 2023
  • The purpose of this study was to improve the accuracy of effective atomic number (EAN) and relative electron density (RED) using a polynomial-based calibration method using dual-energy CT images. A phantom composed of 11 tissue-equivalent materials was acquired with dual-energy CT to obtain low- and high-energy images. Using the acquired dual-energy images, the ratio of attenuation of low- and high-energy images for EAN was calibrated based on Stoichiometric, Quadratic, Cubic, Quartic polynomials. EAN and RED were extracted using each calibration method. As a result of the experiment, the average error of EAN using Cubic polynomial-based calibration was minimum. Even in the RED image extracted using EAN, the error of the Cubic polynomial-based RED was minimum. Cubic polynomial-based calibration contributes to improving the accuracy of EAN and RED, and would like to contribute to accurate diagnosis of lesions in CT examinations or quantification of various materials in the human body.

전단동축형인젝터를 통해 분사된 메탄-산소 이원추진제의 연소특성 (Combustion Characteristics of the Methane-Oxygen Bipropellant Injected by a Shear-coaxial Injector)

  • 홍준열;배성훈;배대석;김정수
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.787-790
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    • 2017
  • 본 연구는 이원추진제 추력기(thruster)에 사용되는 메탄-산소 연소특성규명의 선행연구로서 모델연소실 내 전단동축형인젝터를 통해 분사된 기체메탄-기체산소 비예혼합화염의 연소안정한계 및 화염형상을 도출하기 위한 실험적 연구가 수행되었다. DSLR 카메라를 이용하여 화염 직접이미지(direct image)를 촬영하였고, 이미지 후처리(post-processing)를 통해 연소특성파악 및 화염길이 정량화를 수행하였다. 그 결과, 산화제 레이놀즈 수($Re_o$)가 증가함에 따라 이론반응비(stoichiometric ratio)에서 안정된 화염이 발생하였고, 동일 인젝터직경 조건에서 난류화염의 길이가 늘어남을 확인하였다.

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LPG 엔진 모델링 및 ECM 설계에 관한 연구 (Development of An Engine Modeling and an Engine Control Module for an LPG Engine)

  • 심한섭;선우명호
    • 한국자동차공학회논문집
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    • 제7권9호
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    • pp.1-9
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    • 1999
  • Liquid Petroleum Gas (LPG) has been widely used for commercial light-duty vehicles worldwide. Since LPG has a higher octane number and a lower maximum combustion temperature than gasoline , it becomes more popular fuel for reducing exhaust emissions. In tihs study, mathematical models of air intake and fuel delivery system are presented, and a PI-controller is designed for air-fuel ratio control. Hardware and software of an engine control module (ECM) are designed for an LPG engine. The ECM is built using a Motorola MC68HC05. In order to control the air-fuel ratio at stoichiometry, the PI-control algorithm is implemented in the ECM. The experiment results show the proto LPG ECM and its control scheme perform well to meet the stoichiometric air-duel ratio requirement.

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$a-In_{2}Se_{3}$ 단결정의 전기전도도 특성 연구 (Electrical Conductivity Properties of the $a-In_{2}Se_{3}$ Single Crystal)

  • 김형곤;김남오;이우선
    • 한국전기전자재료학회논문지
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    • 제14권8호
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    • pp.629-633
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    • 2001
  • Electrical properties of the $\alpha$-In$_2$Se$_3$ single crystals grown by use of the Bridgman technique were examined in the transition temperature range between $\alpha$-phase and $\beta$-phase. $\alpha$-In$_2$Se$_3$ single crystal has ' the rhombohedral structure and lattice constants are a=4.025 $\AA$, c=28.771 $\AA$ in c-axis. The transition temperatures of the stoichiometric $\alpha$-In$_2$Se$_3$ single crystal is 198.8$^{\circ}C$ according to the specimens. The temperature of $\alpha$longrightarrow$\beta$ phase transition decreased but the temperature of $\beta$longrightarrow$\alpha$ phase transition increased as the number of heating-cooling cycle increased.

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A New Topology of Solutions of Chemical Equations

  • Risteski, Ice B.
    • 대한화학회지
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    • 제57권2호
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    • pp.176-203
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    • 2013
  • In this work is induced a new topology of solutions of chemical equations by virtue of point-set topology in an abstract stoichiometrical space. Subgenerators of this topology are the coefficients of chemical reaction. Complex chemical reactions, as those of direct reduction of hematite with a carbon, often exhibit distinct properties which can be interpreted as higher level mathematical structures. Here we used a mathematical model that exploits the stoichiometric structure, which can be seen as a topology too, to derive an algebraic picture of chemical equations. This abstract expression suggests exploring the chemical meaning of topological concept. Topological models at different levels of realism can be used to generate a large number of reaction modifications, with a particular aim to determine their general properties. The more abstract the theory is, the stronger the cognitive power is.

좌약제조를 위해 사용되는 자기물질 충전재에 대한 연구 (A Study of the Magnetic Filler for Suppositories by Mossbauer Spectroscopy)

  • Do, Tae-Sung;Nam, Hyo-Duk;Park, Se-Gon;Kim, Eng-Chan
    • 한국의학물리학회지:의학물리
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    • 제9권2호
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    • pp.73-75
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    • 1998
  • Mossbauer spectroscopy methods are discussed when applied to test the properties of magnetic suppositories used in medicine. The experiments were carried out on magnetic rectal suppositories containing parmadine and fine-dispersed ferrite powder (BaOㆍnFe$_2$O$_3$) as a magnetic filler. According to the data on the value of effective magnetic field on $^{57}$ Fe nuclei in ferrite magnetic sublattices, the stoichiometric n-number equals approximately 5.5; this value corresponds to the composition range of optimal magnetic properties.

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