• Title/Summary/Keyword: Stoichiometric number

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Determination of Non-stoichiometry of Tubular Titanium Carbide Formed by Self-Propagating High Temperature Synthesis

  • Choi, Y.;Cho, N.I.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.782-783
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    • 2006
  • Titinium carbide $(TiC_x)$ was produced by self-propagating high temperature synthesis (SHS) method. The morphology and non-stoichiometric number of the SHS product were observed by scanning electron microscopy and neutron diffractometry, respectively. Tubular titanium carbide with hole inside was formed with different non-stoichiometric number (x), which value increased with combustion temperature.

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A Study on the Possibility of Pancreas Detection through Extraction of Effective Atomic Number using a Simulation such as Dual-energy CT (이중에너지 CT와 같은 시뮬레이션을 이용한 유효원자번호 추출을 통한 췌장 검출 가능성 연구)

  • Son, Ki-Hong;Lee, Soo-Yeul;Chung, Myung-Ae;Kim, Dae-Hong
    • Journal of the Korean Society of Radiology
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    • v.16 no.5
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    • pp.537-543
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    • 2022
  • The purpose of this simulation study was to evaluate the possibility of pancreas detection through effective atomic number information using dual-energy computed tomography(CT). The effective atomic number of 10 tissue-equivalent materials were estimated through stoichiometric calibration. For stoichiometric calibration, HU values at low-energy (80 kV) and high-energy (140 kV) for 10 tissue-equivalent materials were used. Based on this method, the effective atomic number image of the tissue-equivalent material was extracted through an iterative algorithm. According to the results, the attenuation ratio in accordance with the effective atomic number was estimated to have an R2 value of 0.9999, and the effective atomic number of Pancreas, Water, Liver, Blood, Spongiosa, and Cortical bone was overall within 1% accuracy compared to the theoretical value. Conventional pancreatic cancer examination uses a contrast medium, so there is a possibility of potential side effects of the contrast medium. In order to solve this problem, it is thought that it will be possible to contribute to an accurate and safe examination by extracting the effective atomic number using dual-energy CT without contrast enhancement. Based on this study, future research will be conducted on the detection of pancreatic cancer using the HU value of pancreatic cancer based on clinical images.

Diffusion-flame instability in the premixed-flame regime (예혼합화염 영역에서 확산화염의 불안정성에 관한 연구)

  • Lee, Su-Ryong;Kim, Jong-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.9
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    • pp.1218-1229
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    • 1997
  • The diffusional-thermal instability of diffusion flames in the premixed-flame regime is studied in a constant-density two-dimensional counterflow diffusion-flame configuration, to investigate the instability mechanism by which periodic wrinkling, travelling or pulsating of the reaction sheet can occur. Attention is focused on flames with small departures of the Lewis number from unity and with small values of the stoichiometric mixture fraction, so that the premixed-flame regime can be employed for activation-energy asymptotics. Cellular patterns will occur near quasisteady extinction when the Lewis number of the more completely consumed reactant is less than a critical value( ~ =0.7). Parametric studies for the instability onset conditions show that flames with smaller values of the Lewis number and stoichiometric mixture fraction and with larger values of the Zel'dovich number tend to be more unstable. For Lewis number greater than unity, near-extinction flame are found to exhibit either travelling instability or pulsating instability.

Neutron Diffraction Study of Powders Prepared by Self-propagating High Temperature Synthesis

  • Park, Yong;Kim, Y S.;Y. D. Hahn;S. H. Shim;Lee, J. S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2000.11a
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    • pp.11-12
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    • 2000
  • Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.

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Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Channel Patterns (유로형상 변화에 따른 고분자 전해질 연료전지의 성능 및 전달특성에 대한 3차원 수치해석적 연구)

  • Lee, Pil-Hyong;Cho, Son-Ah;Choi, Seong-Hun;Hwang, Sang-Soon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.407-410
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    • 2006
  • Selection of flow channel in the separation plate of PEMFC is very important parameter to improve its performance and reduce parasite loss. Flow patterns in the channel have great influence on the transport of hydrogen and all and water generated from electrochemical reaction in diffusion layer In this study, fluid flow in flow channel with parallel and interdigitated patterns are simulated three dimensionally on full flow domain including anode and cathode electrode together. The numerical results show that the fuel cell with interdigitated flow channel represents better performance than that with parallel flow channel due to its strong convective transport across the gas diffusion layer. But the pressure drop in parallel flow channel is much more than that in nterdigitated flow channel. The effect of temperature and stoichiometric number on performance can be calculated and analyzed as well.

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Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Channel Patterns (유로형상 변화에 따른 고분자 전해질 연료전지(PEMFC)의 성능 및 전달특성에 대한 3차원 수치 해석적 연구)

  • Lee, Pil-Hyong;Cho, Son-An;Choi, Seong-Hun;Hwang, Sang-Soon
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.78-85
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    • 2006
  • Selection of flow channel in the separation plate of PEMFC is very important parameter to improve its performance and reduce parasite loss. Flow patterns in the channel have great influence on the transport of hydrogen and air and removal of water generated from electrochemical reaction in diffusion layer. In this study. fluid flow in flow channel with parallel and interdigitated patterns are simulated three dimensionally on full flow domain including anode and cathode channel together. The numerical results show that the fuel cell with interdigitated flow channel represents better performance than that with parallel flow channel due to its strong convective transport across the gas diffusion layer. But the pressure drop in parallel flow channel is much more than that in interdigitated flow channel. And effects of temperature and stoichiometric number on performance can be calculated and analyzed as well. Nomenclature.

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Edge Flame : Why Is It So Hot in Combustion?

  • Kim, Jong-Soo
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.19-27
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    • 2000
  • A turbulent combustion model, based on edge flame dynamics, is discussed in order to predict global extinction of turbulent flames. The model is applicable to the broken flamelet regime of turbulent combustion, in which global extinction of turbulent flame is achieved by gradual expansion of flame holes. The edge flame dynamics is the key mechanism to describe the flame hole expansion or contraction. For flames with Lewis numbers near unity, there is a $Damk{\ddot{o}}hler$ number, namely the crossover $Damk{\ddot{o}}hler$ number, at which edge flame changes its direction of propagation. The parametric region between the quasi-steady extinction condition and the edge-flame crossover condition is a metastable region, in that flames without edge can stay in their burning states while flames with edge have to retract to expand quenching holes. Using the above properties of edge flame, Hartley and Dold proposed a Lagrangian hole dynamics, which allows us to simulate transient variation of quenching holes. In their model, each stoichiometric surface is subjected to a random sequence of scalar dissipation rate compatible to the equilibrium turbulence. Then, each stoichiometric surface will evolve, according to the combustion map, dependent on the scalar dissipation rate and existence of flame edge, If all the burning surfaces are annihilated, the event can be declared as a global extinction. The consequence obtained from the above model also can be used as a subgrid model to determine local extinction occurring in a calculation grid.

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Laminar Burning Velocities and Flame Stability Analysis of Hydrocarbon/Hydrogen/Carbon Monoxide-air Premixed Flames (탄화수소/수소/일산화탄소-공기의 예혼합화염에서 층류화염전파속도와 화염안정성)

  • Vu, Tran Manh;Song, Won-Sik;Park, Jeong;Lee, Kee-Man
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.23-32
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    • 2011
  • To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

Mossbauer Research of the Magnetic Filler for Suppositories (좌약제조를 위해 사용되는 자기물질 충전재에 대한 연구)

  • 도태성;김응찬;남효덕;최세곤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.440-442
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    • 1997
  • The properties of magnetic suppositories used in medicine has been tested with M ssbauer spectroscopy methods. The experiments were carried out on magnetic rectal suppositories containing parmadine and fine-dispersed ferrite powder BaO.nFe$_2$O$_3$as a magnetic filler. According to the data on the value of effective magnetic field on $^{57}$ Fe nuclei in ferrite magnetic sublattices, the stoichiometric n-number equals approximately 5.5; this vague corresponds to the composition range of optimal magnetic properties.

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Feasibility of a methane reduced chemical kinetics mechanism in laminar flame velocity of hydrogen enriched methane flames simulations

  • Ennetta, Ridha;Yahya, Ali;Said, Rachid
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.213-221
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    • 2016
  • The main purpose of this work is to test the validation of use of a four step reaction mechanism to simulate the laminar speed of hydrogen enriched methane flame. The laminar velocities of hydrogen-methane-air mixtures are very important in designing and predicting the progress of combustion and performance of combustion systems where hydrogen is used as fuel. In this work, laminar flame velocities of different composition of hydrogen-methane-air mixtures (from 0% to 40% hydrogen) have been calculated for variable equivalence ratios (from 0.5 to 1.5) using the flame propagation module (FSC) of the chemical kinetics software Chemkin 4.02. Our results were tested against an extended database of laminar flame speed measurements from the literature and good agreements were obtained especially for fuel lean and stoichiometric mixtures for the whole range of hydrogen blends. However, in the case of fuel rich mixtures, a slight overprediction (about 10%) is observed. Note that this overprediction decreases significantly with increasing hydrogen content. This research demonstrates that reduced chemical kinetics mechanisms can well reproduce the laminar burning velocity of methane-hydrogen-air mixtures at lean and stoichiometric mixture flame for hydrogen content in the fuel up to 40%. The use of such reduced mechanisms in complex combustion device can reduce the available computational resources and cost because the number of species is reduced.