• Korean Journal of Materials Research
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• v.33 no.4
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• pp.151-158
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• 2023

In this study, a new type of composite material combined with carbonyl iron, a relatively strong ferromagnetic material, was prepared to overcome the current application limitations of Prussian blue, which is effective in removing radioactive cesium. The surface of the prepared composite was analyzed using SEM and XRD, and it was confirmed that nano-sized Prussian Blue was synthesized on the particle surface. In order to evaluate the cesium removal ability, 0.2 g of the composite prepared for raw cesium aquatic solution at a concentration of 5 ㎍ was added and reacted, resulting in a cesium removal rate of 99.5 %. The complex follows Langmuir's adsorption model and has a maximum adsorption amount (q_e) of 79.3 mg/g. The Central Composite Design (CCD) of the Response Surface Method (RSM) was used to derive the optimal application conditions of the prepared composite. The optimal application conditions achieved using Response optimization appeared at a stirring speed of pH 7, 17.6 RPM. The composite manufactured through this research is a material that overcomes the Prussian Blue limit in powder form and is considered to be excellent economically and environmentally when applied to a cesium removal site.

• Applied Chemistry for Engineering
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• v.28 no.4
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• pp.437-441
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• 2017

This study was carried out to investigate the volumetric expansion ratio and hardness of expanded graphite after coating with various resins which were used as an additive of fireproof sealant. The coating thickness of the resin, which represents the coating rate, was dependent of the drying speed of the resin and the viscosity of the resin. Therefore the coating thickness was shown as follows: polyvinyl acetate > acrylic resin > urethane resin > water soluble latex. Furthermore, the volumetric expansion ratio was as follows: urethane resin > water soluble latex > acrylic resin > polyinyl acetate and the hardness was as follows: polyvinyl acetate resin > acrylic resin > water soluble latex > urethane resin. This showed that the volume of expansion was reduced by expansion, which was not covered by coating, but significantly increased by increasing hardness and allowed it to be used as a refractory addition. According to the response surface methodology, the optimized addition amount and stirring speed of acrylic resin were 37.6 wt% and 441.4 rpm, respectively.

• Polymer(Korea)
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• v.26 no.3
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• pp.400-409
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• 2002

Polyurethane microcapsules containing functional oil (citronella oil) were successfully prepared by conventional interfacial polymerization of tolulene 2,4-diisocyanate (TDI) and ethylene glycol (EG) and characterized by Fourier transform (FT-IR) spectroscopy, Ultraviolet spectroscopy, particle size analysis, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Tile effects of polymerization variables, such as surfactant concentration and agitation speed, on the particle size and particle size distribution were investigated. FT-IR spectroscopic data showed that citronella oil was successfully encapsulated in the microcapsule. Thermogravimetric analysis data showed that the microcapsule was thermally stable up to $220^{\circ}C$. The controlled release of the citronella oil present in the microcapsule core in a methanol medium was demonstrated by ultraviolet spectroscopy showing that the amount of released citronella oil was increased with increasing time. It was observed that the amount of released citronella oil was increased with increasing stirring speed and emulsifier concentration in the rnicrocapsule preparation step. Polyurethane microcapsules containing citronella oil showed excellent anti-moth property.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.51 no.2
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• pp.212-220
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• 2015

We examined the appearance of cold water in the southwest region of the East Sea, based on the sea surface temperature (SST) at the east coast of Korea and buoy data in Donghae ($37^{\circ}31$'N, $130^{\circ}00$'E, 80 km east away from Donghae port) and Pohang ($36^{\circ}21$'N, $129^{\circ}46$'E, 35 km east away from Ganggu port) from June to August in 2013. Also, the serial oceanographic data of National Fisheries Research and Development Institute (NFRDI) were used to see the oceanographic conditions for June and August in 2013. The SST anomaly at the east coast showed negative values in $3{\sim}6^{\circ}C$ from 2 July. At Janggigab, the SST anomaly showed negative value amount to $10^{\circ}C$ in 8 July. The negative values of SST anomaly continued to the middle of August at Janggigab. The wind speed was 6~11 m/s and the direction was south-southwestly in 1 July. The wind speed amounts to 6~16 m/s in 2 July. It means that the strong wind induced the upwelling effect by a day. The temperature was lower than normal at the depth in 20 m of the East Sea in June and August. The air pressure was 996~998 hPa in the beginning of July. It was the lowest air pressure during the studied period. The correlation was 0.3 between the SST anomaly and air pressure. It was suggested that the appearance of cold water in the East Sea was influenced by a stirring due to wind and low air pressure as well as coastal upwelling.

• Journal of Adhesion and Interface
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• v.13 no.1
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• pp.17-23
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• 2012

A fragrant microcapsule was prepared for use by students to reduce the stress of taking examinations. Rosmarinic acid was used as a fragrant oil which had the effect of relaxing stress, polycaprolactone (PCL) was used as a capsule wall material, and poly(vinyl alcohol) (PVA) as a stabilizer. The solvent evaporation method was used to form the microcapsule. The microcapsules were prepared by changing the stirring rate, the concentration of the stabilizer, and the molecular weight of PCL. The shape of the microcapsule was characterized by scanning electron microscopy (SEM). The size of the microcapsule was reduced by increasing the stirring speed. The release rate of rosmarinic acid was decreased when the higher molecular weight PCL was used. When the prepared microcapsule was tested in an aromatherapy class, the microencapsulated fragrant oil had a longer release time than the original fragrant oil. The study data showed that this fragrant oil was effective for increasing concentration ability, reducing stress, increasing digestive power, and increasing memory for the students.

• Clean Technology
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• v.29 no.2
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• pp.95-101
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• 2023

An experiment was conducted to produce vaterite-type precipitated calcium carbonate from waste oyster shells in order to use them as recyclable resources. Calcined oyster shells containing calcium oxide as their main component were prepared at a temperature of 800℃ for 24 h. The oyster shells were dissolved in nitric acid or hydrochloric acid solution to make 0.1 M calcium nitrate or calcium chloride aqueous solution, and a carbonation reaction was performed using a 0.1 M sodium carbonate aqueous solution under various experimental conditions, which included varying the amount of aspatic acid additive, the amount of NH₄OH added, the reaction time, the reaction temperature, the stirring speed, and the type of dissolved acid. The XRD, SEM, and size distributions were analyzed and the vaterite content was calculated. Spherical precipitated calcium carbonate with a vaterite content of 95.9% was synthesized by adding 0.1 mol aspatic acid/1 mol CaO and 2 cm³ of NH₄OH, and reacting for 1 h at 25℃ while stirring at 600 rpm. The average particle diameter was found to be 12.11 ㎛. Calcium carbonate contatining high vaterite is used as high value added calcium carbonate for medical, food, inke additiver, etc.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.8
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• pp.706-713
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• 2016

In this study, the welding characteristics of friction stir welding were investigated in accordance with the tool plunge position and cooling to the base materials for the joining of dissimilar materials (A6005-AZ61). Other different welding conditions, such as the tool rotation speed and welding speed, were fixed to 500rpm-30mm/min, respectively, and welding was then carried out by placing the Mg alloy (AZ61) on the advancing side and Al alloy(A6005) on the retreating side. Welding was conducted under six different conditions. To investigate the welding characteristic, tensile test and microstructure observations using an optical microscope were carried out. As the tensile test result, the maximum strength appeared under the condition in which the tool is moved 1 mm to the Mg alloy direction and cooling to the base materials. Under the same welding conditions, the strength with cooling was approximately two times higher than that without cooling. The tool was located in each direction of 1.7 mm from the weld line. Therefore, in the excessive off-set of tool position, the welding integrity was in an extremely poor condition due to the lack of stirring. This study was confirmed by the A6005-AZ61 dissimilar friction stir welding the welding speed and the tool rotation speed. In addition, the temperature control and tool plunge position are important welding parameters.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1143-1148
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• 2010

We investigated the separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction comprising four kinds of NHC [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compound (BAC) [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN) mixture with ten structural isomers (DMNs; regarded as one component)], biphenyl (Bp) and phenyl ether (Pe) by liquid membrane permeation (LMP). A batch-stirred tank was used as the permeation unit. An aqueous solution of saponin and n-hexane were used as the liquid membrane and the outer oil phase, respectively. Yield and selectivity of individual NHC was much larger than that of BAC, Bp and Pe. Increasing the initial mass fraction of the saponin to the membrane solution ($C_{sap,0}$) and the initial volume fraction of O/W emulsion to total liquid in a stirred tank (${\phi}_{OW,0}$) resulted in deteriorating the yield of individual NHC, but increasing the stirring speed (N) resulted in improving the yield of each NHC. With increasing $C_{sap,0}$, the selectivity of each NHC based on DMNs increased. Increasing ${\phi}_{OW,0}$ and N resulted in decreasing the selectivity of individual NHC based on DMNs. At an experimental condition fixed, the sequence of the yield and selectivity in reference to DMNs for each NHC was Q > Qu = iQ > In. Furthermore, we compared LPM method with methanol extraction method in view of the separation efficiency (yield, selectivity) of NHC.

• Journal of the Korean Institute of Rural Architecture
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• v.21 no.4
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• pp.45-52
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• 2019

Chemical grouting method is mainly used for construction of dams and reservoirs, stabilization and reinforcement of slopes, reinforcement of soft grounds such as embankments, dredging and landfills, the order of earthquake response method, and the reinforcement of structures. Recently, it is widely applied in construction sites such as highways, airfields, high-speed railways, subsea facilities, port construction works, tunnels, and subway works. As such, the demand for grouting continues to increase. The development of the grouting method was focused on increasing the strength of the ground, and the development of the chemical additives, the injection device, and the stirring device were mainly performed. But ordinary portland cement used for grouting is a product that consumes natural resources such as limestone, generates a large amount of greenhouse gases, consumes a large amount of energy sources, and it is time to develop products and new methods to replace them. In this study, Ordinary Portland Cement and New Grouting Binder (circulating fluidized bed boiler fly and blast furnace slag) were compared and analyzed by the following test. Homo-gel strength and homo-gel time, water quality analysis of the water used and soil contamination process tests of homo-gel samples were performed. In the case of NGB, when Using water is used as the reservoir water, the strength measured smaller than that of the other water. However, it shows about 2.5 times greater than the homo-gel compressive strength applied to OPC (7-day, reservoir water), so there is no problem with water quality when applied.

• Resources Recycling
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• v.28 no.6
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• pp.36-45
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• 2019

The spent petroleum catalysts contain rare metals such as vanadium, nickel, molybdenum, and cobalt. Therefore, the leaching of these rare metals from spent petroleum catalysts by organic acid was investigated in the present study. The leaching efficiency of metals by organic acid was in the following order: oxalic acid > tartaric acid > citric acid > maleic acid > ascorbic acid. Among the organic acids employed in this work, oxalic acid can be considered to be superior to the other acids in terms of metals leaching efficiency. The effect of several leaching conditions such as temperature, acid concentration, pulp density, stirring speed, and reaction time on the leaching of metals was investigated. Vanadium and molybdenum were selectively dissolved by oxalic acid from the spent catalysts. The leaching kinetics of vanadium by oxalic acid was also investigated. An activation energy of 8.76 kJ/mol indicated that the leaching kinetics of vanadium by oxalic acid solution was controlled by mass transfer.