• Title/Summary/Keyword: Stereoselective synthesis

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Regio- ＆ Stereoselective Synthetic Method for Polyhydroxyamines using Chlorosulfonyl lsocyanate

  • Kim, In-Su;Lim, Seung-Yong;Kim, Ji-Duck;Jung, Young-Hoon
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.341.3-342
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    • 2002

  • The interest in polyhydroxyamines is based in their biological activity as enzyme inhibitors. and as starting materials in the synthesis of more complex compounds. Polyhydroxyamines is that amine group is continuing structurally with hydroxy groups and has become important target of the synthesis strategy because of the chirality control of amine group and each hydroxy groups. (omitted)

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The First Synthesis of Dually Modified Southern-Mimicking Nucleoside: 4'-Methyl Branched and Bicyclo [3.1.0] Hexane Locked Nucleoside

  • Kim, Kwan-Woo;Hong, Joon-Hee
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.668-672
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    • 2004

  • This paper reports the stereoselective synthesis of a novel nucleoside, 4'-methyl branched and bicyclo [3.1.0] hexane locked-nucleoside 12, using a sequential [3,3]-sigmatropic rearrangement/carbene cycloaddition reaction/Curtius reaction strategy with a high stereoselectivity.

  • https://doi.org/10.5012/bkcs.2004.25.5.668 인용 PDF KSCI