• Title/Summary/Keyword: Stearic acid

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A Study on Chemical Washing Mechanism by Flowing Film of Detergent/Water Solution (흐르는 세제혼합액막에 의한 화학적 세척 메커니즘에 대한 연구)

  • Jang, Choong-Hyo;Park, Chan-Youl;Song, Tae-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.6 s.261
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    • pp.499-506
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    • 2007
  • This study aims to propose evaluation methods of chemical washing performance and estimate the washing capability by flowing detergent/water solution for application to home appliances such as dishwashers. Standard pollutant is stearic acid. A numerical study is also tried using a SIMPLER code. Preliminary experiments are performed by varying the concentration and temperature of the solution. From the pre-experiments, 10 minute pre-curing time is found to be necessary to remove the stearic acid. Stoichiometric ratio and detergent consumption coefficient of reaction between the detergent and stearic are estimated following a proposed method. Washing experiments of pollutant to compare with the numerical results are performed. The relative errors between the experimental and the numerical results with pre-curing time included are less than 7%. In conclusion, important mechanisms of chemical washing are revealed and methods of predicting washing performance are well established.

Varietal Differences of Major Chemical Components and Fatty Acid Composition in Mungbean (녹두의 주요 성분함량과 지방산 조성의 품종간 차이)

  • 이성춘;임태곤;김동철;송동석;김영국
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.1
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    • pp.1-6
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    • 1997
  • These experiments were conducted to obtain basic information for breeding material on the utility characteristics in mungbean, The crude protein, fat and ash content were 24.3, 0.67, 3.6%, repectively, and the fat content showed varietal differences, whereas the protein and ash content was not significantly differences among the varieties. The negative correlation existed between protein and carbohydrate content, seed moisture and fat content, seed weight and fat content. The unsaturated fatty acid contain 60∼67% and there were oleic, linoleic, linolenic and archidonic acid, and the saturated fatty acid contain 33∼40% and there were stearic, palmitic, behenic and lignoceric acid. The major fatty acids in mungbean were linoleic, linolenic and palmitic acid, and have contained 33.46, 21.87, 21.72, respectively, and oleic, stearic and arachidonic acid contained 5.98, 5.88, 4.87, respectively, and the behenic and lignoceric acid left traces. Highly positive correlation existed between palmitic and linoleic acid, oleic and lignoceric, behenic. However; palmitic and arachidonic, lignoceric acid, oleic and linolenic acid, arachidonic and liniceric acid showed negative correlations with each other. Seed weight of tested varieties showed highly positive correlation with oleic, arachidonic and behenic acid.

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Increase in Moisture Barrier Properties of Alginate-based Films by Composting with Fatty Acids and $CaCl_{2}$ Treatment (지방산과 $CaCl_{2}$ 처리에 의한 알긴산 필름의 수분저항성 증진)

  • Rhim, Jong-Whan;Kim, Ji-Hye
    • Korean Journal of Food Science and Technology
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    • v.36 no.3
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    • pp.432-439
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    • 2004
  • Increase in water vapor barrier properties of sodium alginate films was studied by preparing composite films with fatty acids, i.e., lauric, palmitic, stearic, and oleic acids, and by treatment with 3% $CaCl_{2}$ solution for 3 min. Film thickness, surface color, microstructure, tensile strength (TS), elongation at break (E), water vapor permeability (WVP), water solubility (WS), and sorption isotherm of films were investigated. Microstructure of films observed with SEM was changed by fatty acid and $CaCl_{2}$ treatments. TS decreased 25-70% depending on fatty acid used, and increased 1.5- to 2-fold by $CaCl_{2}$ treatment. E decreased by both fatty acid and $CaCl_{2}$ treatments. Except oleic acid, WVP decreased significantly (p<0.05) by forming composite films with fatty acids, particularly with stearic acid, WVP decreased more than two-fold. WS also decreased by fatty acid and $CaCl_{2}$ treatments. In stearic acid, WS decreased about 30-fold by combined treatment of fatty acid and $CaCl_{2}$. Sorption isotherm showed typical biphasic pattern with deliquescent point of 0.75. Results of isotherms and BET monolayer moisture content indicated hydrophilicity of film decreased by $CaCl_{2}$ treatment.

Changes in lipid and Fatty Acid Composition in Korean Native Meju during Fermentation (한국 재래식 메주 발효과정에 있어서 지질 및 지방산 조성의 변화)

  • Son, Yang-Don;Choi, Chun-Un;An, Bong-Jeun;Son, Gu-Mok;Choi, Cheong
    • Applied Biological Chemistry
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    • v.28 no.4
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    • pp.226-232
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    • 1985
  • Changes in lipid and fatty acid composition in Korean native Meju were investigated at one week interval over 6 weeks of fermentation. For the systematically, salicic acid column chromatography and gas liquid chromatography were used. Following results were obtained. 1. The lipid fraction obtained from the soared soybean and the cooked soybean were mainly composed of $72.47%{\sim}92.35%$ of neutral lipid, phospholipid and glycolipid were 4.64% and 4.88%, respectively. During fermentation period, lipid content decreased to 80.59%, but glycolipid and phospholipid contents increased. 2. The triglyceride contents of nonpolar lipids prepared from the cooked soybean and the soaked sobean was 89.66% and 87.83% respectively. Free fatty acid, diglyceride and sterol contents increased during fermentation, whereas triglyceride content decreased. 3. Lipids extracted from the soaked soybean and the cooked soybean were composed of 54.58% linoleic acid, $22{\sim}20%$ oleic acid, $10{\sim}12%$ palmitic acid and $3{\sim}5%$ stearic acid. 4. During the Korean native Meju fermentation in palmitic acid decreased from the second week and stearic acid through $3rd{\sim}4th$ week. Oleic acid and linoleic acid content decreased gradually, but linolenic acid content increased. 5. During the fermentation, myristic acid content of glycolipid fraction increased. Lipase activity reached to the maximum at the 3rd week.

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Studies on the Fatty Acid Composition of Duck Meat (오리고기의 지방산조성(脂肪酸組成)에 관(關)한 연구(硏究))

  • Nam, Hyun-Keun
    • Journal of Nutrition and Health
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    • v.10 no.1
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    • pp.34-37
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    • 1977
  • Quantitative analysis of the fatty acids contained in Duck meat was carried out by the Gas Chromatography with Flame ionization Detector, The general components and chemical constants have been performed with A.O.A.C. methods. The results art summarized as follows : 1. General composition of Duck meat come out to be 64.87% moisture, 19.06% protein, 17.05% fat, and 1.02% ash. 2. It was investigated that extraction of lipids were performed by Soxhlet extractor for 12 hours. Amounts of lipids were extracted 79.57% in ethylether, 70.15% in chloroform, and 72.35% in n-hexane. 3. Chemical constants of lipids in Duck meat were obtained as follows : Saponification number 201.5, Acid number 5.01, Iodine number 50.1 and Carbonyl number 4.5 4. It was investigated that the fatty acid component were quantitatively determined by the gas chromatography : Linolenic acid 1.6%, Linoleic acid 19.9%, Oleic acid 45.9%, Stearic acid 3.1% Palmitic acid 17.2% and Myristic acid 0.12% in leg portion. Linolenic acid 1.7% Linoleic acid 17.2%, Oleic acid 51.2%, Stearic acid 3.3%, Palmitic acid 17.1% and Myristic acid 0.17% in breast portion. 5. Cholesterol of blood, breast and leg portion fat in Duck were obtained as follows : Total cholesterol 200 mg%, 260 mg% , and 400 mg% respectively; cholesterol ester 120mg%, 151 mg%, and 240mg% respectively.

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Comparative Studies on the Fatty Acid Composition of Korean and Chinese Sesame Oils and Adulterated Sesame Oils with Commercial Edible Oils (국내산 및 중국산 참기름과 변조 참기름의 지방산 조성에 관한 연구)

  • 강치희;박재갑;박정웅;전상수;이승철;하정욱;황용일
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.1
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    • pp.17-20
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    • 2002
  • This study was carried out to determine the composition of fatty acids from the samples such as Korean and Chinese sesame oils and adulterated sesame oils with commercial edible oils including soybean and corn oils collected in Gyeongnam area. The fatty acid composition of sesame oils extracted from commercial Korean and Chinese sesame showed similar pattern except the result that Korean sesame oils contained lower levels of palmitic acid, stearic acid and higher level of linolenic acid than Chinese sesame oils. In adulterated sesame oils with commercial soybean oil, the composition of linolenic acid was increased 0.73$\pm$0.05%, 1.25$\pm$0.04% by adding of commercial soybean oil, 3%, 9%, respectively. And that of the linoleic acid was 50.22$\pm$0.06%, 51.14$\pm$0.05% by 5%, 9% addition of commercial corn oil, respectively. From these results, sesame oils and adulterated sesame oils with commercial edible oils will be verified by the composition analysis of fatty acids.

Effect of Oil Extraction Methods on Fractionation Pattern and Fatty Acid Composition of the Each Fraction of Sesame Oil (채유방법(採油方法)이 참기름의 분획별지질(分劃別脂質) 및 지방산(脂肪酸) 조성(組成)에 미치는 영향(影響))

  • Choi, Sang-Do;Yang, Min-Suk;Cho, Moo-Je
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.13 no.3
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    • pp.259-262
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    • 1984
  • In order to examine the effect of oil extraction methods on the charateristics of sesame oil, the fractionation pattern and fatty acid compositions of the each fraction of the oil were compared in the oil extracted by the three different extraction methods, that is, pressure extraction of roasted seed (RTP), acetone extraction of roasted seed (RTE) and acetone extraction of raw seed (RWE). The amount of triglyceride in RWE oil was slightly higher as 77.2% of the total lipid than that in RTP and RTE oil of 73.4%. The content of oleic and linoleic acid in glycolipld and fatty acid fractions, linoleic acid in triglyceride, and palmitic and stearic acid in phospholipid fractions from RTP and RTE oil were higher than those from RWE oil, but the oleic acid in triglyceride. Palmitic and stearic acid in free fatty acid, and oleic and linoleic acid in phospholipid from RTP and RTE oil were lower than those from RWE oil. The ratio of $C_{18}$ to $C_{16}$ fatty acids and unsaturated to saturated fatty acids in glycolipid and phospholipid fractions from RTP and RTE oil were higher than those from RWE oil, but the ratios in triglyceride and free fatty acid fractions from RTP and RTE oil were lower than those from RWE oil.

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Biohydrogenation Pathways for Linoleic and Linolenic Acids by Orpinomyces Rumen Fungus

  • Nam, I.S.;Garnsworthy, P.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.11
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    • pp.1694-1698
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    • 2007
  • The objective of this study was to identify biohydrogenation pathways for linoleic, linolenic, oleic and stearic acids by Orpinomyces species of rumen fungus during in vitro culture. Biohydrogenation of linoleic acid produced conjugated linoleic acid (cis-9, trans-11 C18:2), which was then converted to vaccenic acid (trans-11 C18:1) as the end product of biohydrogenation. Biohydrogenation of linolenic acid produced cis-9, trans-11, cis-15 C18:3 and trans-11, cis-15 C18:2 as intermediates and vaccenic acid as the end product of biohydrogenation. Oleic acid and stearic acid were not converted to any other fatty acid. It is concluded that pathways for biohydrogenation of linoleic and linolenic acids by Orpinomyces are the same as those for group A rumen bacteria.

Studies on the Fatty Acid Composition of Amorpha-fruticosa Seeds (Amorpha-fruticosa종자(種子)의 지방산조성(脂肪酸組成)에 관한 연구(硏究))

  • Whang, Byung-Ho;Lee, Sang-Young
    • Korean Journal of Food Science and Technology
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    • v.6 no.2
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    • pp.86-90
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    • 1974
  • Quantitative analysis of the fatty acids contained in Amorpha-fruticosa seeds was carried out by means of gas chromatography with F.I.D. The general components and chemical constants have been performed with A.O.A.C methods. The results are summarized as follow: 1. General components of Amorpha-fruticosa seeds come out to be 17.65% moisture, 21.02% crude protein, 12.04% crude lipid and 5.37% ash. 2. Extraction of crude lipids were performed by soxhlet extractor for 14 hour. Amounts of the crude lipids were extracted 80.25% in ether, 80.00% in methanol, 77.34% in benzene and 69.96% in hexane. 3. Chemical constants of Amorpha-fruticosa seed oil were saponification number 178.67, acid number 3.11 and iodine number 54.27. 4. The fatty acid components of Amorpha-fruticosa seeds were quantitatively determined by gas chromatography to give 78.73wt% linoleic, 5.8wt% oleic, 5.68wt% palmitic, 4.8wt% stearic and 3.40wt% linolenic acid in ether solvent and to give 77.86wt% linoleic, 7.77wt% palmitic, 5.84wt oleic and 4.97wt% stearic acid in methanol solvent. The peak of capric acid was not found. Myristic, arachidic and lauric acids were very small.

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Distribution of Fatty Acids in Newly Developed Tissues of Soybean Seedlings

  • Dhakal, Krishna Hari;Jeong, Yeon-Shin;Ha, Tae-Joung;Baek, In-Youl;Yeo, Young-Keun;Hwang, Young-Hyun
    • Korean Journal of Breeding Science
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    • v.43 no.1
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    • pp.32-41
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    • 2011
  • The objective of this study was to determine the fatty acid composition of newly developed tissues of germinated soybean seeds. Five soybean accessions with varied fatty acid composition were allowed to germinate in sand under greenhouse conditions. Seedlings were picked up after 4, 6, 8, 10 and 12 days of germination and freeze dried. The fatty acid composition of the newly developed tissues was analyzed by gas chromatography. Significant variation in fatty acid composition was observed between accessions, days of germination, and variety ${\times}$ day of germination in whole and the cotyledons. In the case of newly developed five tissues, significant variation in fatty acid composition were observed between days of germination except oleic acid for root, hypocotyl and epicotyl stem and except stearic acid for hypocotyl and unifoliate leaves while all the parameters were significantly different for accession. Significant interactions of accession and days of germination were observed for palmitic, linoleic and linolenic acid in all tissues; only for oleic acid in hypocotyl, epicotyl and unifoliate leaves; and only for stearic acid in root, hypocotyl, epicotyl and unifoliate leaves. During germination, the fatty acid composition of newly developed tissues changed dramatically but whole seedlings and cotyledons changed slightly. These tissues contained five major fatty acids as found in original seeds, but compositions were totally different from that of the seed: higher in palmitic, stearic and linolenic acid and lower in oleic and linoleic acid. New tissues conserved their fatty acid compositions regardless of genotypic variation in the original seeds.