• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.1-7
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• 2013

In this study, simulation work of HCNG refueling system was performed. The hydrogen was produced from steam reforming process by natural gas. The conversion of natural gas is increased as SCR is increased. but it was no significant difference more than 3 of SCR and fuel throughput is increased as GHSV is increased. Both conversion and fuel throughput levels was optimized when the $1700h^{-1}$ of GHSV. CNG was compressed from low pressure natural gas. For the mixing of $H_2$ and CNG is mixed with the high pressure conditions such as 400bar of $H_2$ and 250bar of natural gas. Single-stage compression was required more power than multi stage. So, multi stage compression was suggested for high pressure compression. We calculated the intermediate pressure to minimize total required power of compressors. The intermediate pressure for $H_2$ and natural gas were derived at 61 and 65 bar, respectively.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.4
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• pp.286-294
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• 2010

According to the propagation of fuel cell system, the importance of that system efficiency is being magnified. Thus, the efficiency improvement of reformer which is the important part of fuel cell system will be required. In structural aspect, the reformer is classified into cylindrical and plate type. Plate type reformer features better maintenance and space efficiency compared with cylindrical type. In this study, we changed the shape of combustion chamber to improve the reforming efficiency. And then we performed the CFD simulation to predict the spacial distribution of temperature. Analysis cased contains with baffles, fins, baffles and fins, and without those. In case of only with-baffle, temperature distributions were uneven because the high temperature stream was concentrated near the baffle end. In case of with-fin, the temperature distributions were relatively even than other cases.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.2
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• pp.244-249
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• 2012

Recently energy crisis and environmental pollution using fossil fuel became social issue. The Fuel Cell, one of the new and renewable energy has great advantage for the former mentioned problems. The PEM Fuel Cell needs highly purified hydrogen for fuel, in many cases CH4 was reformed to H2 basically using steam reforming. The purpose of this paper is to understand the probability of ceramic honeycomb to apply the combustor of STR. We tested the heat accumulation performance of ceramic honeycomb by change of excess air ratio. The results were suitable for our purpose and also these results can be used to make high temperature air at mild combustion field.

• Journal of Advanced Marine Engineering and Technology
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• v.35 no.4
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• pp.397-405
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• 2011

Hydrogen energy, as part of eco-friendly alternative energy, is made mostly through reforming of fossil fuels. The turbulent premixed combustion type of metal-fiber flat burner which is recently used in industry was tested in this paper. We measured the mean temperature distributions, CO, HC, $CO_2$ and $O_2$ concentrations to observe the flame structure and flame stability in some kind of experimental conditions. And also PIV and several flow analysis methods were compared to establish the numerical analysis model. The results of this paper will be the basis of the burner design of steam reformer.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.11
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• pp.849-855
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• 2008

The paper addresses modeling and analysis of the part load performance of a hybrid fuel cell system integrating a polymer electrolyte membrane fuel cell(PEMFC) and a gas turbine(GT). The system is a pressurized one where the working pressure of the PEMFC is higher than the ambient pressure. In addition to the two major components, the system also includes auxiliary parts such as a steam reformer, a humidifier, and afterburner and so on. Based on design analysis, component off-design models are incorporated in the analysis program and part load operation is simulated. The mode for the part load operation of the PEMFC/GT hybrid system is a variable rotational speed operation. The operating characteristics and variations in the system efficiency and component performance parameters at part load are analyzed.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.6
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• pp.618-626
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• 2017

Conventional high temperature reformers are not suitable for hybrid fuel cell systems that use waste heat as a heat source. So, development of a low temperature type reformer is needed. However, the analysis was conducted in two ways to increase the thermal efficiency, because of low reforming rate due to the low heat source. First, it is a way to ger thermal gain from the outside through partial insulation. In the case of one heat source tube and several heat source tubes, we analyzed the effect of partial heat insulation in some cases. Second, we found the most efficient arrangement of the heat source tubes by changing the location of the heat source tubes. The interpretation was carred out using the COMSOL Mutiphysics program.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.5
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• pp.494-502
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• 2016

A 1-dimensional heterogeneous reactor model with the gas-solid interfacial phase gradients was developed for the simulation of the packed bed reactor where the exothermic reversible water gas shift reaction for the natural gas steam reformed gas was proceeding in adiabatic mode. Experimental results obtained over the WGS catalyst, C18-HA, were best simulated when the frequency factor of the reaction rate constant was adjusted to a half the value reported over another WGS catalyst, EX-2248, having the same kinds of active components as the C18-HA. For the reactor of the inside diameter 158.4 mm and the bed length 650 mm, the optimum feeding temperature of the reformed gas was simulated to be $194^{\circ}C$, giving the lowest CO content in the product gas by 1.68 mol% on the basis of dried gas. For reactors more extended in the bed length, the possible lowest CO content in the product gas with the optimum feeding temperature of the reformed gas were suggested.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.470-476
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• 2021

In the near future, with the urgent requirement of environmental protection, hydrogen based energy system is essential. However, at the present time, most of the hydrogen is produced by reforming, which still produces carbon dioxide. This study proposes a high-power electrolytic hydrogen production system based on solid oxide electrolysis cell with no harmful emissions to the environment. Besides that, the parametric study and optimization are also carried to examine the effect of individual parameter and their combination on system efficiency. The result shows that the increase in steam conversion rate and hydrogen molar fraction in incoming stream reduces system efficiency because of the fuel heater power increase. Besides, the higher Faraday efficiency does not always result a higher system efficiency.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2010.04a
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• pp.192-192
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• 2010

현재 산업과 과학의 발달로 인한 무분별한 화석연료의 사용은 에너지자원의 고갈과 환경오염의 문제를 야기시켜, 이의 해결을 위한 청정 신에너지에 대한 연구가 전 세계적으로 집중되고 있다. 이 중 바이오매스는 화석연료보다 비교적 높은 H/C 비를 갖기 때문에 신에너지인 수소 또는 Syngas를 생산하기 위한 가스화 특성이 우수한 특징을 가지고 있으며, 구성성분 내 중금속, 황, 질소를 거의 함유하지 않는 점에서 환경오염 저감과 동시에 대체 신에너지로써 각광을 받고 있다. 이에 본 연구에서는 목질계 바이오매스인 Wood pellet (미송)에 대하여 고정층 반응기를 이용하여 질소분위기하에서 온도 및 Steam/Biomass Ratio(이하 SBR) 조건에 따른 가스화 특성으로 고찰하는데 그 목적을 둔다. 온도의 영향에 대하여, 높은 온도 범위에서 수소 수율이 증가함을 알 수 있었다. SBR에 대한 영향으로서, 저온 (700, $800^{\circ}C$)에서는 SBR=1에서는 수소의 수율이 증가하였으나 SBR=2, 3에서 감소하는 것을 보였다. 하지만 $900^{\circ}C$에서는 SBR이 증가 할수록 수소의 수율이 증가하는 것으로 나타났다. 또한 볼륨비로 나타내었을 경우 $H_2/CO(vol/vol)$의 경우 $900^{\circ}C$, SBR=3에서 0.73%로 water gas shift reaction이 가장 잘 일어난 것을 확인했고, $H_2/CH_4(vol/vol)$의 경우 마찬가지로 위의 조건과 동일조건에서 2.59%로 steam reforming이 가장 잘 일어난 것을 확인할 수 있었다. 최종적으로 본 실험에서는 $900^{\circ}C$, SBR=3인 경우에 가장 높은 수소수율을 얻을 수 있으며, 이때 수소의 수율은 32.7 Vol%였다.

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.468-473
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• 2018

In this study, the reforming reaction of vacuum residues (VR), high viscosity oil residues produced from vacuum distillation process of petroleum oil, was carried out using catalytic aquathermolysis reaction. VR showed a prone to decrease the amount of resins and asphaltenes in the constituents, and to increase saturates and aromatics when reacting with steam at 30 bar and above $300^{\circ}C$ for 24 h. When the amount of steam is not enough at this reaction, the asphaltene content in the products was rather increased after the reaction. As a result of the catalytic aquathermolysis using the metal oxide-zeolite catalyst with the decaline as a hydrogen donor, a 10% decrease in resin and asphaltene as well as a 10% increase in the aromatic hydrocarbon were observed. Consequently, the viscosity of VR decreased by 70% after the reaction. GC-Mass spectroscopy showed that the aquathermolysis of VR resulted in the decomposition of the resins and asphaltens into a low molecular weight material.