• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.113.1-113.1
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• 2010

IGCC(Integrated Coal Gasification and Combined Cycle) plants can be among the most advanced and environmental systems for electric energy generation from various feed stocks and is becoming more and more popular in new power generation fields. In this work, the performance of IGCC plants employing Shell gasification technology and a GE 7FB gas turbine engine was simulated using IPSEpro open-equation modeling environment for different operating conditions. Performance analyses and comparisons of all operating cases were performed based on the design cases. Discussions were focused on gas composition, syngas production rate and overall performance. The validation of key steady-state performance values calculated from the process models were compared with values from the provided heat and material balances for Shell coal gasification technology. The key values included in the validation included the inlet coal flow rate; the mass flow rate, heating value, and composition of major gas species (CO, H2, CH4, H2O, CO2, H2S, N2, Ar) for the syngas exiting the gasifier island; and the HP and MP steam flows exiting the gasifier island.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.506-512
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• 2013

Biomass and low-grade coals are known to be better potential sources of energy compared to crude oil and natural gas since these materials are readily available and found to have large reserves, respectively. Gasification of these carbonaceous materials produced syngas for chemical synthesis and power generation. Woodchip, sawdust and lignite were gasified with steam in a thermobalance reactor under atmospheric pressure in order to evaluate their kinetic rate information. The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (20~90 kPa) on the gasification rate were investigated. The three different types of gas-solid reaction models were applied to the experimental data to predict the behavior of the gasification reactions. The modified volumetric model predicted the conversion data well, thus the model was used to evaluate kinetic parameters in this study. The observed activation energy of biomass, sawdust and lignite gasification reactions were found to be in reasonable range and their rank was found to be sawdust > woodchip > lignite. The expression of apparent reaction rates for steam gasification of the three solids was proposed to provide basic information on the design of coal gasification processes.

• Nuclear Engineering and Technology
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• v.33 no.2
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• pp.241-253
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• 2001

Under severe accidents, the pressure and temperature response has an important role for the integrity of a nuclear power plant containment. The history of the pressure and temperature is characterized by the amount and state of steam/air mixture in a containment. Recently, the heat transfer rate to the structure surface is supposed to be increased by the wavy interface formed on condensate film. However, in the calculation by using CONTAIN code, the condensation heat transfer on a containment wall is calculated by assuming the smooth interface and has a tendency to be underestimated for safety. In order to obtain the best- estimate heat transfer calculation, we investigated the condensation heat transfer model in CONTAIN 1.2 code and adopted the new forced convection correlation which is considering wavy interface. By using the film tracking model in CONTAIN 1.2 code, the condensate film is treated to consider the effect of wavy interface. And also, it was carried out to investigate the effect of the different cell modelings - 5-cell and 10-cell modeling - for KNGR(Korean Next Generation Reactor) containment phenomena during a severe accident. The effect of wavy interface on condensate film appears to cause the decrease of peak temperature and pressure response . In order to obtain more adequate results, the proper cell modeling was required to consider the proper flow of steam/air mixture.

• Nuclear Engineering and Technology
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• v.45 no.5
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• pp.589-596
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• 2013

In a pressurized heavy water reactor, following loss of the primary coolant, severe core damage would begin with the depletion of the liquid moderator, exposing the top row of internally-voided fuel channels to steam cooling conditions on the inside and outside. The uncovered fuel channels would heat up, deform and disassemble into core debris. Large inventories of water passively reduce the rate of progression of the accident, prolonging the time for complete loss of engineered heat sinks. The efficacy of available backup and ultimate heat sinks, available in a CANDU 6 reactor, in mitigating the consequences of a prolonged station blackout scenario was analysed using the MAAP4-CANDU code. The analysis indicated that the steam generator secondary side water inventory is the most effective heat sink during the accident. Additional heat sinks such as the primary coolant, moderator, calandria vault water and end shield water are also able to remove decay heat; however, a gradually increasing mismatch between heat generation and heat removal occurs over the course of the postulated event. This mismatch is equivalent to an additional water inventory estimated to be 350,000 kg at the time of calandria vessel failure. In the Enhanced CANDU 6 reactor ~2,040,000 kg of water in the reserve water tank is available for prolonged emergencies requiring heat sinks.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1505-1515
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• 2009

A new method to semicontinuously determine $PM_{2.5}$ ionic species with a short time resolution is described in detail. In this system, a particle collection section (mixing part, particle collection chamber, and air/liquid separator) was developed. A Y-type connector was used to mix steam and an air sample. The particle collection chamber was constructed in the form of a helix coil and was cooled by a water circulation system. Particle size growth occurred due to the high relative humidity and water absorbed particles were efficiently collected in it. Liquid samples were drained out with a short residence time (0.08-0.1 s). The air/liquid separator was also newly designed to operate efficiently when the flow rate of the air sample was 16.7 L $min^{-1}$. For better performance, the system was optimized for particle collection efficiency with various types of test aerosols such as ($NH_4)_2SO_4,\;NaCl,\;NH_4HSO_4,\;and\;NH_4NO_3$. The particle collection efficiencies were almost 100% at different concentration levels in the range over 500 nm in diameter but 50-90% in the range of 50-500 nm under the following experimental conditions: 15 coil turns, a water flow rate for steam generation of 0.65 mL $min^{-1}$, and an air sample flow rate of 16.7 L $min^{-1}$. Finally, for atmospheric applications, chemical compositions of $PM_{2.5}$ were determined with a time resolution of 20 min on January 11-24, 2006 in Seoul, Korea, and the chemical characteristics of $PM_{2.5}$ ions were investigated.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.1
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• pp.21-28
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• 2019

Reversible solid oxide fuel cell (ReSOC) system was integrated with waste steam for electrical energy storage in distributed energy storage application. Waste steam was utilized as external heat in SOEC mode for higher hydrogen production efficiency. Three system configurations were analyzed to evaluate techno-economic performance. The first system is a simple configuration to minimize the cost of balance of plant. The second system is the more complicated configuration with heat recovery steam generator (HRSG). The third system is featured with HRSG and fuel recirculation by blower. Lumped models were used for system performance analyses. The ReSOC stack was characterized by applying area specific resistance value at fixed operating pressure and temperature. In economical assessment, the levelized costs of energy storage (LCOS) were calculated for three system configurations based on capital investment. The system lifetime was assumed 20 years with ReSOC stack replaced every 5 years, inflation rate of 2%, and capacity factor of 80%. The results showed that the exergy round-trip efficiency of system 1, 2, 3 were 47.9%, 48.8%, and 52.8% respectively. The high round-trip efficiency of third system compared to others is attributed to the remarkable reduction in steam requirement and hydrogen compression power owning to fuel recirculation. The result from economic calculation showed that the LCOS values of system 1, 2, 3 were 3.46 ¢/kWh, 3.43 ¢/kWh, and 3.14 ¢/kWh, respectively. Even though the systems 2 and 3 have expensive HRSG, they showed higher round-trip efficiencies and significant reduction in boiler and hydrogen compressor cost.

• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.190-195
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• 1999

The thermal pyrolysis of chlorodifluoromethane (R22) for producting tetrafluoroethylene (TFE) has been studied using the tubular reactor designed by the authors. The reaction temperature over $600{\sim}850^{\circ}C$, residence time over 0.005~0.6 sec, and steam/R22 ratio 3 to 30 were varied through experiments to analyze the effect of these variables on the conversion of R22 and selectivity for TFE. We have provided the guidelines for the optimal operation and design for the pyrolysis reactor. With increasing the dilution ratio, not only the conversion of R22 but also the selectivity for TFE increase. The optimum range of reaction temperature was $700{\sim}750^{\circ}C$ and the residence time 0.07~0.1 sec. In the kinetic study, first order rate equation was fitted well with the experimental data. This indicates that the main reaction step is a $CF_2$ generation from R22 pyrolysis. The range of activation energy for the rate constant was obtained 44.7~48 kcal/mol.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.157-160
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• 2008

The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. In general, most feasible strategies to generate hydrogen from hydrocarbon fuels consist of a reforming step to generate a mixture of $H_2$, CO, $CO_2$ and $H_2O$ (steam) followed by water gas shift (WGS) and CO clean-up steps. The WGS reaction that shifts CO to $CO_2$ and simultaneously produces another mole of $H_2$ was carried out in a two-stage catalytic conversion process involving a high temperature shift (HTS) and a low temperature shift (LTS). In a typical operation, gas emerges from the reformer is taken through a high temperature shift catalyst to reduce the CO concentration to about 3~5%. The HTS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to a range of 2~4%. The iron based catalysts (G-3C) was used for the HTS to convert the most of CO in the effluent from the partial oxidation (POX) to $H_2$ and $CO_2$ at a relatively high rate. Parametric screening studies were carried out for variations of the following variables: reaction temperature, steam flow rate, components ratio ($H_2/CO$), and reforming gas flow rate.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.4
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• pp.325-332
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• 2005

This paper addresses the development of a scroll expander for power generation from relatively low temperature steam source. It has a double-sided orbiting scroll member so that no thrust bearing is needed to support the base plate of the orbiting scroll. Three power transmission shafts are placed at the periphery of the orbiting scroll base plate, and these shafts can also function as anti-rotation devices. Final output is obtained from the main central shaft engaged with the three power transmission shafts through gear assembly. The clearance between the fixed and orbiting scroll elements was estimated by comparing measurement of the mass flow rate with calculation results of a computer simulation. Due to large clearance, the expander total and volumetric efficiencies were measured to be $34\%\;and\;43\%$, respectively. It has been shown through the computer simulation that the total and volumetric efficiencies could be improved to $65\%\;and\;83\%$, respectively, if the current clearance is reduced by half.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.329-330
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• 2009

Food waste contains almost no heavy metals and high fuel ratio 0.14-0.17 that makes it a good candidate for solid fuel. Thermogravimetric analysis showed that volatile matter volatilizes at $200-400^{\circ}C$, and ignition temperature is $460^{\circ}C$. Combustion efficiency measured from energy balance before and after combustion was over 99%. Pulverized fuel made from food waste is a new and renewable energy which contribute to low carbon green economic growth.