• Bulletin of the Korean Chemical Society
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• v.30 no.3
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• pp.722-725
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• 2009

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.1070-1072
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• 2007

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.12
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• pp.2370-2378
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• 2009

The enhanced phase angle estimation algorithm is essential to supply the power stably under synchronizing with grid source. In this paper, we are proposed the novel phase angle estimation algorithm and verified the validity of proposed method as simulation with PSIM and experiments. We sort the harmonics element using high-pass filter(HPF) that have the cut-off frequency below basic element and make reverse d-q transformation. So, it can be restored the harmonics element at stationary axis, and we can get the fundamental voltage element of AC grid. Proposed PLL method have a rapid responsibility and a large margin at controller design than conventional method because it have a small phase delay and a sufficient controller gain margin. And, it can reduce the error of voltage rms value and axis transformation according to robust PLL algorithm against the harmonic and phase unbalance.

• Journal of Power Electronics
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• v.14 no.6
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• pp.1334-1344
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• 2014

A novel single phase Phase-Locked Loop (PLL) is proposed in this paper to accurately and rapidly estimate the instantaneous phase angle of a grid. A conjugate rotating vector pair is proposed and defined to synthesize the single phase signal in the stationary reference frame. With this concept, the proposed PLL innovatively sets one phase input of the PARK transformation to a constant zero. By means of a proper cancellation, a zero steady state phase angle estimation error can be achieved, even under magnitude and frequency variations. The proposed PLL structure is presented together with guidelines for parameters adjustment. The performance of the proposed PLL is verified by comprehensive experiments. Satisfactory phase angle estimation can be achieved within one input signal cycle, and the estimation error can be totally eliminated in four input cycles for the most severe conditions.

• Bulletin of the Korean Chemical Society
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• v.32 no.spc8
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• pp.3017-3021
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• 2011

Two chiral stationary phases (CSPs) based on (3,3'-diphenyl-1,1'-binaphthyl)-20-crown-6 bonded covalently to silica gel were applied for the first time to the resolution of racemic vigabatrin and its analogue ${\gamma}$-amino acids and the resolution results were compared to those on the commercially available Crownpak CR(+) based on (3,3'-diphenyl-1,1'-binaphthyl)-20-crown-6 coated dynamically onto octadecylsilica gel. While vigabatrin was not resolved at all on Crownpak CR(+), it was resolved quite well on the two CSPs. Among four vigabatrin analogue ${\gamma}$-amino acids, only two were resolved on Crownpak CR(+), but three were resolved on the CSP (CSP 1) containing residual silanol groups and all of four were resolved on the CSP (CSP 2) containing residual silanol group-protecting n-octyl groups. The improved lipophilicity in CSP 2 was proposed to be responsible for its superiority to CSP 1 for the resolution of vigabatrin and analogue ${\gamma}$-amino acids. In addition, the composition of aqueous mobile phase was found to affect the chiral recognition behaviors for the resolution of vigabatrin and analogue ${\gamma}$-amino acids on CSP 2.

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.605-607
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• 2015

The development of time-frequency analysis techniques allow astronomers to successfully deal with the non-stationary time series that originate from unstable physical mechanisms. We applied a recently developed time-frequency analysis method, the Hilbert-Huang transform (HHT), to two non-stationary phenomena: the superorbital modulation in the high-mass X-ray binary SMC X-1 and the quasi-periodic oscillation (QPO) of the AGN RE J1034+396. From the analysis of SMC X-1, we obtained a Hilbert spectrum that shows more detailed information in both the time and frequency domains. Then, a phase-resolved analysis of both the spectra and the orbital profiles was presented. From the spectral analysis, we noticed that the iron line production is dominated by different regions of this binary system in different superorbital phases. Furthermore, a pre-eclipse dip lying at orbital phase ~0:6-0:85 was discovered during the superorbital transition state. We further applied the HHT to analyze the QPO of RE J1034+396. From the Hilbert spectrum and the O-C analysis results, we suggest that it is better to divide the evolution of the QPO into three epochs according to their different periodicities. The correlations between the QPO periods and corresponding fluxes were also different in these three epochs. The change in periodicity and the relationships could be interpreted as the change in oscillation mode based on the diskoseismology model.

• Journal of Microbiology
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• v.35 no.4
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• pp.277-283
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• 1997

Promoters inducible by paraquat, a superocide-generating agent, were isolated from Escherichia coli using a promoter-probing plasmid pRS415 with promoterless lacA gene. Twenty one promoters induced by paraquat were selected and further characterized. From sequence analysis, thirteen of the promoters were mapped to their specific loci on the Escherichia coli chromosome. Several promoters were mapped to the upstream of known genes such as usgl, katG, and mglB, whose relationships with superoxide response have not been previously reported. Other promoters were mapped to the upstream region of unknown open reading frames. Downstream of HC 96 promoter are uncharacterized ORFs whose sequences are homologous to ABC-transporter subunits. Downstream of HC84 promoter is an ORF encoding a transcriptional regulator-like protein, which contains a LysR family-specific HTH (helix-turn-helix) DNA bindign motif. We investigated whether these promoters belong to the soxRS regulon. All promoters except HC96 were found to belong to the soxRS regulon. The HC96 promoter was significantly induced by paraquat in the soxRS deletion mutant strain. The basal transcription level of three promoters (HE43, HC71, HD94) significantly increased at the stationary phase, implying that they are regulated by RpoS. However, paraquat inducibility of all promoters disappeared in the stationary phase, suggesting that SoxRS regulatory system is active only in rapidly growing cells.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.6 no.1
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• pp.12-22
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• 1994

Time evolution of linear water waves on a constant depth generated by a disturbance is analyzed by asymptotic methods; stationary phase, steepest descents and leading wave approximation. In order to verify the derived formulae of surface displacements for 1-D and 2-D waves. surface displacements are calculated and plotted from both the formulae and a numerical integration. The existing results for surface displacements are verified in which the leading amplitude of 1-D waves during the evolution decays as f- T/B, the rest of the wavetrain as t$^{-1}$ 2/ and the rest of the wavetrain of 2-D waves as t-1. But it is shown that the leading amplitude of 2-D waves decays as t 5/6 which is different from Kajiura's result t$^{-4}$ 3/.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2006.11a
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• pp.661-665
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• 2006

This study investigates objective and subjective evaluations of refrigerator noise. To describe the fluctuations like a click, a rapid increase of sound level, a change of pitch, a transition into the stationary and ending phase, the psychoacoustical and autocorrelation function(ACF) parameters have been employed. First, subjective evaluation of the noisiness of 24 kinds of refrigerators was conducted. Then, the relationship between objective measures of the refrigerator noise on perceived noisiness was examined with multiple regression analyses. Sound Quality Indices using the psychoacoustical and ACF parameters were also developed. The important psychoacoustical parameters for evaluating noisiness are loudness and roughness of stationary phase. The relationship between the noisiness and the ACF parameters shows that sound energy ${\Phi}(0)$ and its fluctuations are important. Also, refrigerator sounds that had a fluctuation of pitch were rated as more annoying. The fluctuation of pitch is expressed by ${\tau}_1\;and\;{\Phi}_1$ defined by the delay time and the amplitude of the first peak of the ACF.

• Bulletin of the Korean Chemical Society
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• v.23 no.9
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• pp.1291-1294
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• 2002

Various racemic N-protected ${\alpha}-amino$ acids such as N-t-BOC-(tert-butoxycarbonyl), N-CBZ-(benzyloxycarbonyl) and N-FMOC-(9-fluorenylmethyloxycarbonyl) ${\alpha}-amino$ acids were resolved as their anilide and 3,5-dimethylanilde derivatives on an HPLC chira l stationary phase (CSP) developed by modifying a commercial (S)-leucine CSP. The chromatographic resolution results were compared to those on the commercial (S)-leucine CSP. The resolutions were greater on the modified CSP than those on the commercial CSP with only one exception, the resolution of N-t-BOC-phenylglycine anilide. In addition, the chromatographic resolution behaviors were quite consistent except for the resolution of N-protected phenylglycine derivatives, the (S)-enantiomers being retained longer. Based on the chromatographic resolution behaviors and with the aid of CPK molecular model studies, we proposed a chiral recognition mechanism for the resolution of N-protected ${\alpha}-amino$ acid derivatives. However, for the resolution of N-protected phenylglycine derivatives, a second chiral recognition mechanism, which competes in the opposite sense with the first chiral recognition mechanism, was proposed. The two competing chiral recognition mechanisms were successfully used in the rationalization of the chromatographic behaviors for the resolution of N-protected phenylglycine derivatives.