• 제목/요약/키워드: State of energy

검색결과 4,971건 처리시간 0.032초

TiO2 전극 표면의 전자상태 계산 (Calculation on Surface Electronic State of $TiO_2$ Electrode)

  • 이동윤;이원재;송재성
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
    • /
    • pp.259-262
    • /
    • 2003
  • The surface electronic state of rutile $TiO_2$, which is an oxide semiconductor and has a wide band gap of 3.1 $\sim$ 3.5 eV, was calculated by DV-$X_{\alpha}$ method, which is a sort of the first principle molecular orbital method and uses Hartre-Fock-Slater approximation. The $[Ti_{15}O_{56}]^{-52}$ cluster model was used for the calculation of bulk state and the $[OTi_{11}O_{34}]^{-24}$ model for the surface state calculation. After calculations, the energy level diagrams and the deformation electron density distribution map were compared in both models. As results, it was identified that the surface energy levels are found between the valence and conduction band of bulk $TiO_2$ on the surface area. The energy values of these surface-induced levels are lower than conduction band of bulk $TiO_2$ by 0.1 $\sim$ 1 eV. From this fact, it is expected that the surface energy levels act as donar levels in n-type semiconductor.

  • PDF

Solid-State Laser Mode-Locking Near 1.25 μm Employing a Carbon Nanotube Saturable Absorber Mirror

  • Cho, Won-Bae;Choi, Sun-Young;Kim, Jun-Wan;Yeom, Dong-Il;Kim, Ki-Hong;Rotermund, Fabian;Lim, Han-Jo
    • Journal of the Optical Society of Korea
    • /
    • 제15권1호
    • /
    • pp.56-60
    • /
    • 2011
  • We demonstrate passive mode-locking of a Cr:forsterite laser with a single-walled carbon nanotube saturable absorber mirror (SWCNT-SAM). Without compensation of intra-cavity dispersion, the self-mode-locked laser generates 11.7 ps pulses at a repetition rate of 86 MHz. The dispersion-compensated laser yields ultrashort pulses as short as 80 fs near $1.25\;{\mu}m$ at 78 MHz with average output powers up to 295 mW, representing the highest power ever reported for mode-locked solid-state lasers based on saturable absorption of SWCNTs in this spectral region.

Hybrid Double Direction Blocking Sub-Module for MMC-HVDC Design and Control

  • Zhang, Jianpo;Cui, Diqiong;Tian, Xincheng;Zhao, Chengyong
    • Journal of Power Electronics
    • /
    • 제19권6호
    • /
    • pp.1486-1495
    • /
    • 2019
  • Dealing with the DC link fault poses a technical problem for an HVDC based on a modular multilevel converter. The fault suppressing mechanisms of several sub-module topologies with DC fault current blocking capacity are examined in this paper. An improved half-bridge sub-module topology with double direction control switch is also designed to address the additional power consumption problem, and a sub-module topology called hybrid double direction blocking sub module (HDDBSM) is proposed. The DC fault suppression characteristics and sub-module capacitor voltage balance problem is also analyzed, and a self-startup method is designed according to the number of capacitors. The simulation model in PSCAD/EMTDC is built to verify the self-startup process and the DC link fault suppression features.

3차원 전고체 전극 구조체 형성, 분석 및 성능 예측 기술 동향 (A Review on 3D Structure Formation, Analysis and Performance Prediction Technique for All-solid-state Electrode and Battery)

  • 박주남;진다희;김도환;배경택;이강택;이용민
    • 전기화학회지
    • /
    • 제22권4호
    • /
    • pp.139-147
    • /
    • 2019
  • 고에너지밀도 대용량 리튬이온전지를 채용한 전기자동차 및 에너지저장시스템에서 발생하고 있는 발화사고로 인해, 고안전성 전고체 리튬이차전지(All-solid-state Lithium Secondary Battery, ALSB)에 대한 연구가 국내외에서 활발히 진행되고 있다. 하지만, 단순히 액체전해질을 고체전해질로만 바꾸는 것이 아니라, 이로 인해 수반되는 전극 및 전지 설계와 해석이 크게 달라진다는 점에서 해결해야 될 이슈들이 산재해 있다. 특히, 전지는 전극 설계에 따라 그 성능이 굉장히 상이함에도 불구하고, 실질적인 전고체 전지 실험 구현의 어려움으로 전고체 전극(All-solid-state Electrode, ASSE) 설계에 따른 성능 차이를 체계적으로 비교 분석하여 최적화하는 연구는 매우 제한적이다. 이를 극복하기 위한 방안으로, 가상의 3차원 전고체 전극 구조체를 형성하고, 형성된 구조체를 바탕으로 다양한 성능 결정 파라미터를 도출하며, 더불어 분석 전극을 포함한 전지의 성능까지 예측할 수 있는 기술을 개발하는 연구가 주목을 받기 시작했다. 본 총설에서는 3차원 전고체 전극 구조체 형성부터 전고체 리튬이차전지의 성능을 예측하는 기술까지 각각의 기술들이 갖고 있는 장단점을 폭넓게 다룰 것이며, 나아가 본 기술이 나아갈 최종적인 목표까지 간략히 기술하고자 한다.

SWR as Tool for Determination of the Surface Magnetic Anisotropy Energy Constant

  • Maksymowicz, L.J.;Lubecka, M.;Jablonski, R.
    • Journal of Magnetics
    • /
    • 제3권4호
    • /
    • pp.105-111
    • /
    • 1998
  • The low energy excitations of spin waves (SWR) in thin films can be used for determination of the surface anisotropy constant and the nonhomogeneities of magnetization in the close-to-surface layer. The dispersion relation in SWR is sensitive on the geometry of experiment. We report on temperature dependence of surface magnetic anisotropy energy constant in magnetic semiconductor thin films of$ CdCr_{2-2x}In_{2x}Se_4$ at spin glass state. Samples were deposited by rf sputtering technique on Corning glass substrate in controlled temperature conditions. Coexistence of the infinite ferromagnetic network (IFN) and finite spin slusters (FSC) in spin glass state (SG) is know phenomena. Some behavior typical for long range magnetic ordering is expected in samples at SG state. The spin wave resonance experiment (microwave spectrometer at X-band) with excited surface modes was applied to describe the energy state of surface spins. We determined the surface magnetic anisotropy energy constant versus temperature using the surface inhomogeneities model of magnetic thin films. It was found that two components contribute to the surface magnetic anisotropy energy. One originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the stray field of the surface roughness. The second one comes from the demagnetizing field of close-to surface layer with grad M. Both term linearly decrease when temperature is increased from 5 to 123 K, but dominant contribution is from the first component.

  • PDF

Transient Characteristics and Physical Constraints of Grid-Tied Virtual Synchronous Machines

  • Yuan, Chang;Liu, Chang;Yang, Dan;Zhou, Ruibing;Tang, Niang
    • Journal of Power Electronics
    • /
    • 제18권4호
    • /
    • pp.1111-1126
    • /
    • 2018
  • In modern power systems, distributed generators (DGs) result in high stress on system frequency stability. Apart from the intermittent nature of DGs, most DGs do not contribute inertia or damping to systems. As a result, a new control method referred to as a virtual synchronous machine (VSM) has been proposed, which brought new characteristics to inverters such as synchronous machines (SM). DGs employing an energy storage system (ESS) provide inertia and damping through VSM control. Meanwhile, energy storage presents some physical constraints in the VSM implementation level. In this paper, a VSM mathematical model is built and analyzed. The dynamic responses of the output active power are presented when a step change in the frequency occurs. The influences of the inertia constant, damping factor and operating point on the ESS volume margins are investigated. In addition, physical constraints are proposed based on these analyses. The proposed physical constraints are simulated using PSCAD/EMTDC software and tested through RTDS experiment. Both simulation and RTDS test results verify the analysis.

회전하는 타이어의 동특성을 고려한 진동에너지 하베스터 성능 예측 (Performance Prediction of Vibration Energy Harvester considering the Dynamic Characteristics of Rotating Tires)

  • 나혜중
    • 한국기계가공학회지
    • /
    • 제19권10호
    • /
    • pp.87-97
    • /
    • 2020
  • In general, tires require various sensors and power supply devices, such as batteries, to obtain information such as pressure, temperature, acceleration, and the friction coefficient between the tire and the road in real time. However, these sensors have a size limitation because they are mounted on a tire, and their batteries have limited usability due to short replacement cycles, leading to additional replacement costs. Therefore, vibration energy harvesting technology, which converts the dynamic strain energy generated from the tire into electrical energy and then stores the energy in a power supply, is advantageous. In this study, the output voltage and power generated from piezoelectric elements are predicted through finite element analysis under static state and transient state conditions, taking into account the dynamic characteristics of tires. First, the tire and piezoelectric elements are created as a finite element model and then the natural frequency and mode shapes are identified through modal analysis. Next, in the static state, with the piezoelectric element attached to the inside of the tire, the voltage distribution at the contact surface between the tire and the road is examined. Lastly, in the transient state, with the tire rotating at the speeds of 30 km/h and 50 km/h, the output voltage and power characteristics of the piezoelectric elements attached to four locations inside the tire are evaluated.

The Construction of Semi-diabatic Potential Energy Surfaces of Excited States for Use in Excited State AIMD Studies by the Equation-of-Motion Coupled-Cluster Method

  • Baeck, Kyoung-Koo;Martinez, Todd J.
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권6호
    • /
    • pp.712-716
    • /
    • 2003
  • The semi-diabatic potential energy surfaces (PESs) of the excited states of polyatomic molecules can be constructed for use in ab initio molecular dynamics (AIMD) studies by relying on the continuity of the electronic energy, oscillator strength, and spherical extent of an excited state along with first derivatives of these quantities as computed by using the equation-of-motion coupled-cluster (EOM-CC) method. The semidiabatic PESs of both the π → $π^*$ valence excited state and the 3s-type Rydberg state of ethylene are presented and discussed in this paper, in conjunction with some of the AIMD results we obtained for these states.

Nuclear Structure Studies with Low Temperature Technique (I)

  • Young Koh;Park, Won-Seok;Park, Chang-Kyu;Shin, Hee-Sung;Song, Tae-Yung
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1996년도 추계학술발표회논문집(2)
    • /
    • pp.669-674
    • /
    • 1996
  • The theory of quantum mechanics states that for any system there are a set of discrete physical states, quantum states, which corresponds a particular energy level of the system. The lowest energy the system can have, corresponding to its ground state, is not necessarily zero, but depends only on the precise microscopic nature of the system under consideration. At the absolute zero of temperature all systems will be in their lowest energy state (zero point energy) and as the system is warmed from OK, the higher energy states become occupied. The probability of occupancy of the excited states relative to that of the ground state is proportional to the absolute temperature. Therefore we can obtain nuclear dipole and quadrupole moment very accurately at ultra low temperature (<15mk) by NMR and from the destruction of anisotropy. The former is called LTNO/NMR and the latter is called LTNO (Low Temperature Nuclear Orientation). In this paper we discuss and introduce only an experimental apparatus with results of cooling power test, a helium dilution refrigerator, which can reache 8mK, and an actual technique for the experiment, a theory and results will be presented in another papers.

  • PDF