• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.95-100
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• 1993

A noise-induced transition is presented for a bistable system subjected to a multiplicative random force, which is singular at the unstable state. The stationary probability distribution is obtained from the Fokker-Planck equation and the effects of the singularity is analyzed. On the basis of noise-induced phase transition with Gaussian white noise, the relaxation time and the transition rate of the system are evaluated up to the first order correction of D. In the parameter region v < l, the transition rates decrease as the exponent v goes to 1 and as the coefficient of the linear term of the kinetic equation increases.

• ETRI Journal
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• 제38권4호
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• pp.714-723
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• 2016

Considerable attention has been given to processing graph data in recent years. An efficient method for computing the node proximity is one of the most challenging problems for many applications such as recommendation systems and social networks. Regarding large-scale, mutable datasets and user queries, top-k query processing has gained significant interest. This paper presents a novel method to find top-k answers in a node proximity search based on the well-known measure, Personalized PageRank (PPR). First, we introduce a distribution state transition graph (DSTG) to depict iterative steps for solving the PPR equation. Second, we propose a weight distribution model of a DSTG to capture the states of intermediate PPR scores and their distribution. Using a DSTG, we can selectively follow and compare multiple random paths with different lengths to find the most promising nodes. Moreover, we prove that the results of our method are equivalent to the PPR results. Comparative performance studies using two real datasets clearly show that our method is practical and accurate.

• Bulletin of the Korean Chemical Society
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• 제26권12호
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• pp.1953-1961
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• 2005

We have performed high-level quantum mechanical calculation for multiple proton transfer in HOCl + HCl and $H_2O$ + $ClONO_2$ on water clusters, which can be used as a model of the reactions on ice surface in stratospheric clouds. Multiple proton transfer on ice surface plays crucial role in these reactions. The structures of the clusters with 0-3 water molecules and the transition state structures for the multiple proton transfer have been calculated. The energies and barrier heights of the proton transfer were calculated at various levels of theory including multi-coefficient correlated quantum mechanical methods (MCCM) that have recently been developed. The transition state structures and the predicted reaction mechanism depend very much on the level of theory. In particular, the HF level can not correctly predict the TS structure and barrier heights, so the electron correlation should be considered appropriately.

• 대한기계학회논문집A
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• 제25권12호
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• pp.2040-2047
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• 2001

In this paper, a singularity problem of the state transition matrix is investigated in the spatial propagation when the spatial matrix differential equation is constructed via time finite element analysis. A parametric study shows that the degree of singularity of the state transition matrix depends on the degree of flexibility of the structures. As an alternative to avoid the numerical problems due to the singularity, an analytic solution fur spatial propagation of the flexible structures is proposed. In the proposed method, the spatial properties of the structure are analytically expressed by a combination of transcendental functions. The analytic solution serves fast and accurate results by eliminating the possibility of the error accumulation caused by the boundary condition. Several numerical examples are shown to validate the effectiveness of the proposed methods.

• 대한전자공학회논문지
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• 제11권2호
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• pp.22-26
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• 1974

변이응동 비동기순서회로를 합성하기 위하여 D-형 변이응동 flirt-flop을 사용하였다. 입력조의 상이라는 새로운 개념을 도입하여 내부상태를 감소할 수 있었다. 원시상태표로부터 직접 다입력변화 회로를 합성하는 등차를 마련하였고 실례를 들어 지금까지의 방법보다 더 나은 방법임을 실증하였다.

• Food Science and Biotechnology
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• 제14권2호
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• pp.301-303
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• 2005

State diagram of highly concentrated branched oligosaccharides (HBOS) was constructed to better understand phase behavior of mixtures with different size of oligosaccharides. It showed dramatic plasticizing effect on glass transition, which was successfully described based on Couchman-Karasz equation model. $T_g$' estimated from state diagram corresponded well with previous empirical data measured by maximum ice formation through isothermal holding (annealing) process. Estimated $T_g$' and $C_g$' values were $-36.3^{\circ}C$ and 79.99%, respectively. $T_g$' value of HBOS was approximately $10^{\circ}C$ higher than that of sucrose, while $C_g$' value was similar to those of general carbohydrate materials, which could be useful for applications in frozen system.

• 조명전기설비학회논문지
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• 제21권4호
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• pp.11-18
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• 2007

A moving object detection algorithm for surveillance video is here proposed which employs background initialization based on two-stage median filtering and a background updating method based on state transition diagram. In the background initialization, the spatiotemporal similarity is measured in the subinterval. From the accumulated difference between the base frame and the other frames in a subinterval, the regions affected by moving objects are located. The median is applied over the subsequence in the subinterval in which regions share similarity. The outputs from each subinterval are filtered by a two-stage median filter. The background of every frame is updated by the suggested state transition diagram The object is detected by the difference between the current frame and the updated background. The proposed method showed good results even for busy, crowded sequences which included moving objects from the first frame.

• 대한화학회지
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• 제57권6호
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• pp.697-702
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• 2013

The addition reaction of cyclopropane with $MgH_2$ has been investigated using the B3LYP density functional method employing several split-valence basis sets. Both along the and perpendicular to the cyclopropane ring approach has been reported. It is shown that the reaction proceeds via a four-centered transition state. Calculations at higher levels of theory were also performed at the geometries optimized at the B3LYP level, but only slight changes in the barriers were observed. Structural parameters for the transition state are also reported.

• Bulletin of the Korean Chemical Society
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• 제17권7호
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• pp.653-655
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• 1996

A comparative molecular field analysis (CoMFA) was carried out for the correlation of the transition state structures and the reaction rates for the SN2 reaction of 4-nitrophenyl benzoate and its sulfur analogs with anionic nucleophiles. The CoMFA analysis showed that both steric and electrostatic effects are important, and the steric contribution increased when nucleophiles are alkoxides or arylsulfides. In this study, we have demonstrated that the CoMFA analysis can be expanded beyond the scope of dealing with reactants and products. The reactant complex and transition state conformations generated along the reaction path can be more appropriately used for the correlation of structures and reaction rates.

• 한국게임학회 논문지
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• 제14권5호
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• pp.127-136
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• 2014

게임 NPC(Non Player Character)는 게임 플레이어와 대전 또는 협력함으로써 게임의 재미를 증가시키는 중요한 요소이다. 대부분 기존 게임에서 제공되는 NPC 인공지능은 FSM(Finite State Machine)으로 제작되어 행동 패턴이 정해져 있고 능력이 동일한 특징을 갖고 있다. 따라서 이러한 특징을 갖는 NPC들과 대전하는 플레이어는 창조적인 게임 플레이를 진행하는 것이 어려울 수 있다. 본 논문은 이 문제점을 개선하기 위하여 실제 생활에서 늑대들이 먹이를 사냥하는 행동 모델을 게임 NPC의 행동 모델로 제작하고 이를 평가하기 위한 것이다. 이를 위하여 첫째, 실세계에서 늑대들이 먹이를 포획하기 위한 행동 상태들을 조사 연구한다. 둘째, 이 행동 상태들을 Unity3D 엔진을 이용하여 구현한다. 셋째, 구현된 NPC들의 상태 전이 비율과 실세계의 NPC들의 상태 전이 비율, 일반적인 게임 NPC의 상태 전이 비율을 비교한다. 비교 결과, 구현된 NPC들의 상태 전이 비율은 실세계의 상태 전이 비율과 비슷함을 보인다. 이는 구현된 NPC들의 행동 패턴이 실세계의 늑대 사냥 행동 패턴과 유사함을 의미하는데, 이렇게 함으로써 플레이어에게 보다 증가된 사용자 경험을 제공할 수 있다.