• Title/Summary/Keyword: State

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CONCENTRATION DEPENDENCES OF GROUND-STATE AND EXCITED-STATE INTRAMOLECULAR PROTON TRANSFER OF PIROXICAM IN METHANOL

  • Cho, Dae-Won;Kang, Seong-Gwan;Kim, Yong-Hee;Yoon, Min-Joong;Kim, Dong-Ho
    • Journal of Photoscience
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    • v.1 no.1
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    • pp.15-23
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    • 1994
  • The absorption and fluorescence spectral properties of piroxicam (PRX) in the hydrogenbonding solvents show the most sensitive dependence on the concentration ranging from 8 x 10$^{_5}$ to 2 x10$^{_5}$ M. These are attributed to both the solvent-mediated ground-state intermolecular proton transfer (GSIerPT) leading to formation of the ground state anion and the excited-state intmmolecular proton transfer (ESIraPT). The concentration dependences of the time-resolved emission kinetics at both room temperature and 77 K have also been investigated. It is shown that in the excited state, the ESIraPT of PRX is the dominant process to form a keto tautomer at the high concentration, whereas at the low concentration the excited-state conformational change of the anion is an additional process leading to formation of a zwitterion. The ESI~PT of PRX in the hydrogenbonding solvent is coupled with the ultrafast excited-state solvent reorganization.

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The Effect of Economic State, Health State, and Sex-Role Identity on Self-Esteem of the Elderly Men and Women (남녀 노인의 경제상태, 건강상태, 성역할 정체감에 따른 자아존중감)

  • 이신숙;이경주
    • Korean Journal of Human Ecology
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    • v.4 no.1
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    • pp.1-10
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    • 2001
  • The purpose of the study was to investigate relationships among self-esteem of the elderly men and women in the economic state, health state, and degree of sex role identity. The subjects were 246 elderly men and women living in Chonnam. Statistics were Frequency, Percentage. Mean, Standard Deviation, Cronbach's ${\alpha}$, ANOVA and Regression analysis. Major results obtained were as follows ; 1) The mean scores of self-esteem in the elderly men and women were 19.26 and 18.84 respectively 2) There were meaningful differences in self-esteem according to health state. economic state. sex role identity in both elderly men and women. And. in the elderly men and Women. the highest influencing variables on their self-esteem were the economic state and health state, and the sex role identity respectively.

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Threshold Voltage Instability in a-Si:H TFTs and the Implications for Flexible Displays and Circuits

  • Allee, D.R.;Venugopal, S.M.;Shringarpure, R.;Kaftanoglu, K.;Uppili, S.G.;Clark, L.T.;Vogt, B.;Bawolek, E.J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1297-1300
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    • 2008
  • Electrical stress degradation of low temperature, amorphous silicon thin film transistors is reviewed, and the implications for various types of flexible circuitry including active matrix backplanes, integrated drivers and general purpose digital circuitry are examined. A circuit modeling tool that enables the prediction of complex circuit degradation is presented.

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Behavioral Characteristics of Local Korean Neonates by Brazelton′s NBAS (브레즐튼 신생아 행동평가법을 이용한 일지역 신생아들의 행동 특성에 관한 연구)

  • Shin Yeong-Hee
    • Child Health Nursing Research
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    • v.7 no.3
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    • pp.298-307
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    • 2001
  • This study assessed behavioral characteristics of 73 normal neonates in Daegu area using the NBAS. Being one of few studies on this topic, the study is to document and to accumulate data on the neonatal behaviors of Korean babies. Overall scores were at moderate levels in 6 behavioral clusters including Habituation, Social Interactive, Motor System, State Organization, and State Regulation. Autonomic Stability showed relative stableness. Scores of Orientation were higher in neonates of working mothers and rural mothers. Neonates of mothers with no abortion history have higher scores in Motor System and State Organization. Score of State Organization was higher in neonates of mothers with no habitual use of amenity during their pregnancy. Scores of Habituation and State Organization, as well as scores of Motor System with State Organization, State Regulation and Autonomic Stability were positively correlated. Scores of Habituation and State Organization indicate that babies are agreeable and even tameable that is advantageous for attachment to caregiver.

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A State Estimator for servo system using discrete Kalman Filter (이산형 칼만 필터를 이용한 서보 시스템의 상태 추정자 설계)

  • Shin, Doo-Jin;Yum, Hyung-Sun;Huh, Uk-Youl;Lee, Je-Hie
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.420-422
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    • 1998
  • In this paper, we propose a position-speed control of servo system with a state estimator. And also we utilized two mass modelling in order to deals with real system accurately. The overall control system consists of two parts: the position-speed controller and state estimator. The Kalman filter applied as state - feedback controller is an optimal state estimator applied to a dynamic system that involves random perturbations and gives a linear,unbiased and minimun error variance recursive algorithm to estimate the unknown state optimally. Therefore we consider the error problem about the servo system modelling, the measurement noise at low-speed ranges a stochastic system, and implement a optimal state observer. Performance of the proposed state estimator are demonstrated by computer simulations.

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Partially Folded States of Mutant Ubiquitin in Mild Denaturing Conditions

  • Park, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1567-1572
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    • 2009
  • Conformational change of ubiquitin variant with valine to alanine mutation at sequence position 26 was studied by varying solvent pH. Fluorescence emission spectra indicated that this variant ubiquitin has some residual structures in acidic and basic solution as compared to denaturant-induced unfolded state. Far-UV circular dichroic spectra indicated that the base-denatured state had more secondary structure than the acid-denatured state. Near-UV circular dichroic spectra indicated that the aromatic side-chains were in the relatively more rigid environment in the base-denatured state than those in the acid-denatured state. Although it appears that the more tertiary structure present in the base-denatured state, refolding reactions measured by stopped-flow fluorescence device suggest that both the acid- and base-denatured states occur before the major folding transition state. The acid- and base-denatured states are considered to reflect the early event of protein folding process.

Rotational State Distributions of I2(B) from Vibrational Predissociation of I2(B)-Ne

  • Cho, Sung-Sil;Sun, Ho-Sung
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1397-1402
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    • 2004
  • The vibrational predissociation of triatomic, i.e., atom-diatom, van der Waals complexes in transient electronic excited state has been widely investigated. The predissociation rates or lifetimes are major concerns of the previous studies. Experimentally rotational state distributions of diatomic product are hardly investigated and few theoretical stuides on rotational state distributions have appeared in literature. In this work, choosing the frequently studied $I_2(B)-Ne$ complex as an example, we investigate the change of rotational state distributions of $I_2(B)-Ne$ produced from predissociation of the various initial states of $I_2(B)-Ne$. The present study on the rotational distributions indicates that rotational state distributions depend significantly on the predissociation energy and the van der Waals vibrational modes of $I_2(B)-Ne$. That is, the initial state dependency of rotational state distributions is extensively discussed.

On optimal state feedback scheme to a position control system by the state observer (상태관측기에 의한 위치제어계의 최적 설계에 관한 연구)

  • 장세훈;박순규
    • 전기의세계
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    • v.31 no.1
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    • pp.43-49
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    • 1982
  • This paper intends to compare and illustrate the feedback effects of the state feedback scheme to a positional control system by the use of the state observer. As a case study, the dynamic properties of a proposed positional control system lie derived, first, and the design of an optimal state feedback control system by the actual states is intended as a primary case study. For the illustration of the feedback effects with the asymptotic state observer, unobservability of some state variables are assumed and an optimal state feedback design is carried by using the estimated states which is reconstructed through the observer. That is, when some of the states of the system to be controlled are not avalable, an observer is constructed to estimate the unaccessable states. Adigital computer is used for the comparative study of the feedback effects in both cases. The resultant response of the proposed system have shown quite reasonable satisfaction oncontrol quality.

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Discrete-Time Output Feedback Algorithm for State Consensus of Multi-Agent Systems (다 개체 시스템의 상태 일치를 위한 이산 시간 출력 궤환 협조 제어 알고리즘)

  • Kim, Jae-Yong;Lee, Jin-Young;Kim, Jung-Su
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.3
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    • pp.625-631
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    • 2011
  • This paper presents a discrete-time output feedback consensus algorithm for Multi-Agent Systems (MAS). Under the assumption that an agent is aware of the relative state information about its neighbors, a state feedback consensus algorithm is designed based on Linear Matrix Inequality (LMI) method. In general, however, it is possible to obtain its relative output information rather than the relative state information. To reconcile this problem, an Unknown Input Observer (UIO) is employed in this paper. To this end, first it is shown that the relative state information can be estimated using the UIO and the measured relative output information. Then a certainty-equivalence type output feedback consensus algorithm is proposed by combining the LMI-based state feedback consensus algorithm with the UIO. Finally, simulation results are given to illustrate that the proposed method successfully achieves the state consensus.

A Quantitative Performance Index for an Input Observer (II) - Analysis in Steady-State - (입력관측기의 정량적 성능지표 (II) -정상상태 해석-)

  • Jung, Jong-Chul;Lee, Boem-Suk;Huh, Kun-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.10
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    • pp.2067-2072
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    • 2002
  • The closed-loop state and input observer is a pole-placement type observer and estimates unknown state and input variables simultaneously. Pole-placement type observers may have poor performances with respect to modeling error and sensing bias error. The effects of these ill-conditioning factors must be minimized for the robust performance in designing observers. In this paper, the steady-state performance of the closed-loop state and input observer is investigated quantitatively and is represented as the estimation error bounds. The performance indices are selected from these error bounds and are related to the robustness with respect to modeling errors and sensing bias. By considering both transient and steady-state performance, the main performance index is determined as the condition number of the eigenvector matrix based on $L_2$-norm.