• Macromolecular Research
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• 제16권5호
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• pp.434-440
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• 2008

Three-armed, star-shaped molecules containing 4-(N,N-diphenyl)amino-4'-nitroazobenzene chromophores were synthesized to study the diffraction behavior after inscribing surface relief gratings. The two molecules differed in terms of their mode of chromophore attachment to the core. In compound 5, they were bound to the core laterally through alkylene spacers, whereas the chromophores were tethered perpendicularly to the core in compound 4. Although 60 wt% of the polar azobenzene chromophores was comprised of large molecules, no aggregation behavior was observed in the absorption spectra of the thin films. The surface relief gratings were elaborated on the surface of the molecular films by the two-beam interference method. The dynamics of grating formation were studied in terms of the diffraction efficiency using two different film samples made up of two star-shaped molecules. The maximum diffraction efficiency of D-$(ENAZ)_3$, compound 4, was measured to be about 30%, which was significantly high. The mode of chromophore attachment affected the dynamic properties of the diffraction gratings.

• 천문학회보
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• 제41권2호
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• pp.39.2-40
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• 2016

The molecular gas surrounding an H II region is thought to be a place where star formation can be induced. Such triggered star formation can arise form the overpressurization of existing density enhancements or thought the collapse of a swept up layers of material. In this talk, We will discuss the results of a study of star-formation activity associated with the outer Galaxy ring-shaped H II regions KR 7, KR 81, KR 120 and KR 140 using archival Spitzer and WISE data along with the JHK observations. We used CO data cubes from the FCRAO and TRAO in order to define extent of the molecular cloud associated each HII region. Using the infrared data sets, We identified and classified YSO populations within each molecular cloud using measures such as the class I/II ratio and YSO spatial density. Along with this, one of the main question in the study of star formation is how protostar accrete material from their parent molecular clouds and observations of infall motions are needed to provide direct evidence for accretion. Combining our observation of the YSO population distribution with time scales associated with YSO evolution and HII expansion, we investigated the possible significance of triggered star formation in the molecular cloud surrounding each region.

• Rapid Communication in Photoscience
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• 제1권1호
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• pp.19-20
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• 2012

Novel star-shaped imide compounds containing electron-donating triphenylamine and/or electron-withdrawing bis(trifluoromethyl)phenyl side groups were synthesized via a two-step process. First, 3,6-dibromo-benzene-1,2,4,5-tetracarboxylic acid (2B4BA) was reacted with 4-aminophenyl (diphenylamine) (ATPA) or 3,5-bis(trifluoromethyl)aniline (6FA) by imide reaction. Then, Suzuki coupling reaction was carried out on these compounds with 4-(N,N-diphenylamino)-1-phenyl boronic acid (BTPA) or 3,5-bis(trifluoromethyl)phenyl boronic acid (6FBB), resulting in 3,6-bis[4-(diphenylamino)phenyl]-N,N'-bis[4-(diphenylamino) phenyl]-pyromellitimide (TPTPPI), 3,6-bis[3,5-bis(trifluoro methyl) phenyl]-N,N'-bis[3,5-bis(trifluoromethyl) phenyl]-pyro mellitimide (6F6FPI) or 3,6-bis[4-(diphenylamino)phenyl]-N,N'-bis[3,5-bistrifluoromethyl)phenyl]-pyromellitimide (6FTPPI). The imide compounds obtained were characterized by NMR, FT-IR, DSC, TGA, melting point analyzer, EA, and solubility measurements. In addition, their optical and electrical properties were evaluated by fluorescence spectroscopy, UV-vis spectroscopy, and cyclic voltammetry (CV). 6F6FPI exhibited deep blue emission (443 nm), along with high $T_m$ ($382^{\circ}C$) and relatively high $T_g$ ($148^{\circ}C$).

• 경영과정보연구
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• 제34권3호
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• pp.101-123
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• 2015

외부 환경의 불확실성이 점점 더 높아지는 가운데 조직의 경쟁우위를 달성하기 위한 방안으로 우수한 인적자원의 확보 및 보유가 점차 중요시되고 있다. 특히, 동료 직원들에 비해 몇 배나 높은 탁월한 성과를 창출할 수 있는 '스타 인재'는 지식과 정보가 중시되는 지식기반산업에서 점차 그 중요성이 강조되고 있어 이에 관련된 학계와 산업계의 관심이 증대되고 있다. 하지만 이처럼 스타 인재에 대한 관심이 증가하고 있음에도 불구하고 스타 인재의 보유가 조직성과에 미치는 영향을 실증적으로 분석한 선행연구는 부족한 편이다. 특히 스타 인재의 보유가 조직 내외부에 미치는 긍정적 부정적 영향력을 고려할 때, 조직 내 스타 인재의 비율(ratio of star employee)과 조직성과의 관계는 단순 선형 관계(simple linear relationship)의 가능성 뿐 아니라 비선형의 곡선형 관계(curvilinear relationship)가 존재할 가능성도 가지고 있다. 이에 본 연구에서는 스타 인재에 관한 선행 연구를 토대로, 스타 인재의 비율이 증가함에 따라 한계효과가 증가하는 체증관계(U자형 곡선)와 한계효과가 감소하는 체감관계(역U자형 곡선)의 두 가지 대립가설을 설정한 후 국내 34개 상장증권사의 2008~2013년 134개 관측수를 대상으로 실증분석을 진행하였다. 국내 경제전문지가 선정한 '베스트 애널리스트'(스타 인재)의 비율이 증권사의 재무성과에 미치는 영향을 불균형 패널모형으로 검증한 결과, 스타 인재의 비율이 증가할수록 조직성과는 증가하지만, 그 한계효과는 점차 감소하는 체감형 비선형 관계가 검증되었다. 이러한 연구결과는 지식기반 산업에서도 스타 인재를 활용하는 것이 중요함을 시사함과 동시에, 스타 인재에 대한 과도한 의존은 경계할 필요성이 있음을 시사한다.

• 폴리머
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• 제38권5호
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• pp.671-675
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• 2014

본 연구에서는 잘 규정된 4-arm 스타형 및 선형 고분자를 합성하여 구조에 따른 구리 프탈로시아닌(CuPc)의 분산 안정성을 비교하였다. 분산제는 (2-dimethylamino)ethyl methacrylate(DMAEMA)와 poly(ethylene glycol) methyl ether methacrylate(PEGMA)를 사용하여 activators generated by electron transfer(AGET) 원자이동라디칼중합법(ATRP)으로 합성하였다. 합성된 고분자는 젤투과 크로마토그래피(GPC)와 핵자기 공명 분광법(NMR)을 사용하여 합성한 고분자들의 분자량 및 단량체의 조성을 결정하였다. 4-Arm 스타형 고분자 및 선형 고분자 분산제에서 stabilizing group인 PEGMA의 중합도를 조절하여 copper phthalocyanine(CuPc)의 분산 안정성에 미치는 영향을 연구하였다. PEGMA의 DP가 130인 4-arm 스타형 고분자를 사용한 경우 $25^{\circ}C$에서 7일 동안 CuPc의 분산상이 안정적으로 유지되었다.

• 대한수학회지
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• 제18권2호
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• pp.135-140
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• 1982

• Macromolecular Research
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• 제9권2호
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• pp.100-106
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• 2001

Several star-polymers with aliphatic cores were synthesized by ring opening polymerization (ROP) of $\xi$-caprolactone using stannous 2-ethyl-hexanoate as a catalyst. The star-polymers were thoroughly analyzed by MALDI-TOF mass spectrometry, temperature gradient interaction chromatography and $\^$13/C-NMR to obtain detailed information of the molecular structure. The imperfection of the star-polymers seemed to be originated from restricted participation of sterically hindered hydroxyl groups of initiator. The synthesized star-polymers had narrow molecular weight distributions. Various reaction conditions to control the imperfection were studied.

• 한국추진공학회지
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• 제27권1호
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• pp.17-26
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• 2023

Star 형상을 갖는 추진제 그레인은 다양한 면적 선도가 가능하고, 제작이 용이하여 실제 고체 추진제 로켓에 유용하게 적용될 수 있다. 그러나, 설계와 관련한 형상 변수가 많고 연소 말기 슬리버가 존재하므로, 해석 비용이 저렴한 일반적인 단일 최적화 기법으로는 최적 설계가 성공하기 어렵다. 본 연구에서는 활용성과 설계 성공률을 높이기 위해 데이터베이스를 사용하여 star 그레인을 설계하는 기법을 제안하였다. 제안된 방법에서는 성능 변수를 정의하고, 데이터베이스를 구축한 후 요구조건을 만족하는 해를 탐색한다. 제안된 방법을 적용하여 다양한 종류의 연소 면적 선도를 갖는 star 그레인의 설계를 수행하고, 설계 방법의 타당성을 검증하였다.

• 천문학회보
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• 제40권1호
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• pp.47.2-47.2
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• 2015

At local, galaxy properties are well known to be clearly different in different environments. However, it is still an open question how this environment-dependent trend has been shaped. In this presentation, we will show the results of our investigation about the evolution of star-formation properties of galaxies over a wide redshift range, from z~2 to z~0.5, focusing its dependence on their stellar mass and environment. In the UKIDSS/UDS region, we estimated photometric redshifts and stellar population properties, such as stellar masses and star-formation rates, using the deep optical and near-infrared data available in this field. Then, we identified galaxy cluster candidates at z~0.5-2. Through the analysis and comparison of star-formation (SF) properties of galaxies in clusters and in field, we found interesting results regarding the evolution of SF properties of galaxies: (1) regardless of redshifts, stellar mass is a key parameter controlling quenching of star formation in galaxies; (2) At z<1, environmental effects become important at quenching star formation regardless of stellar mass of galaxies; and (3) However, the result of the environmental quenching is prominent only for low mass galaxies (M* < $10^{10}M_{\odot}$) since the star formation in most of high mass galaxies are already quenched at z > 1.

• 복식
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• 제5권
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• pp.141-152
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• 1981

Various ceremonial flags were of great importance to the rulers who wished to have the absolute authorities for governing the people. Perhaps nothing indicated the ideas, thoughts and symbols of a certain period and people than the ceremonial flags. The ceremonial flags used in the old China and Korea took the shapes of the heaven and the earth, representing the social backgrounds and thoughts. This study was limited only to the discussion of the heaven-shaped patterns of the ceremonial flags. The 28 constellations of the heaven, in the Oriental way of thinking, were considered to express the immortal powers of Providence and the political domination of the earth. Hence the Polaris, the center of the heaven, symbolized the whole family of king, prince, child born of a concubine and royal harem. Among the constellation pictures were those of Han period, wall painting of old tombs in Koguryeo kingdom and old Japanese kingdom. Referring to the Emperor's ceremonial flags in Daemyeongjibyei, symbolic meanings changed historically and the complete systems of the ceremonial flags were established in Song period when the divine person was drawn on the flags. Animals concerned properly with the particular star and the shapes of the star were both drawn on the flags in Won period and only the shapes of the particular star in Myeong period. In the Imperial enthronement of Kojong the ceremonial flags might be made by the examples of those of Myeong period and remains are now found at Changdeok Palace, which need a further study because the references in detail are not available.