• 제목/요약/키워드: Stainless steels

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Can the Point Defect Model Explain the Influence of Temperature and Anion Size on Pitting of Stainless Steels

  • Blackwood, Daniel J.
    • Corrosion Science and Technology
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    • 제14권6호
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    • pp.253-260
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    • 2015
  • The pitting behaviours of 304L and 316L stainless steels were investigated at $3^{\circ}C$ to $90^{\circ}C$ in 1 M solutions of NaCl, NaBr and NaI by potentiodynamic polarization. The temperature dependences of the pitting potential varied according to the anion, being near linear in bromide but exponential in chloride. As a result, at low temperatures grades 304L and 316L steel are most susceptible to pitting by bromide ions, while at high temperatures both stainless steels were more susceptible to pitting by small chloride anions than the larger bromide and iodide. Thus, increasing temperature appears to favour attack by smaller anions. This paper will attempt to rationalise both of the above findings in terms of the point defect model. Initial findings are that qualitatively this approach can be reasonably successful, but not at the quantitative level, possibly due to insufficient data on the mechanical properties of thin passive films.

Effects of Tungsten on the Precipitation Kinetics of Secondary Phases and the Associated Susceptibility to Pitting Corrosion in Duplex Stainless Steels

  • Park, Chan-Jin;Kwon, Hyuk-Sang
    • Corrosion Science and Technology
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    • 제5권6호
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    • pp.189-195
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    • 2006
  • Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.

오스테나이트계 스테인리스강의 용접성과 내식성에 미치는 합금원소의 영향(I) - 응고균열 감수성을 중심으로 - (The Effect of Alloying Elements on Weldability and Corrosion Resistance of Austenitic Stainless Steels(I))

  • 정호신;이윤용;배동수
    • Journal of Welding and Joining
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    • 제30권3호
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    • pp.57-65
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    • 2012
  • The interest of austenitic heat resistant stainless steels containing high Si has increased because they have higher resistance of oxidation and higher strength at high temperature than STS 310. This study carried out Varestraint test for evaluation of solidification cracking sensitivity of 14 different stainless steels. As a result of Varestraint test, all specimens solidified as primary ferrite, and solidification crack sensitivity increased with adding $N_2$ to shielding gas. Nb and W had beneficial effect on solidification crack resistance in case of less than FN 2 containing, but crack sensitivity increased with Nb and W in case of more than FN 2. Ce had beneficial effect on solidification crack resistance but impaired weld bead appearance.

저항 점 용접을 이용한 AISI 316 스테인레스강과 용융아연도금 강판의 이종접합 (Resistance Spot Welding of Dissimilar Materials of Austenitic Stainless Steels and IF (Interstitial Free) Steels)

  • 이진범;남대근;강남현;김양도;오원태;박영도
    • 한국재료학회지
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    • 제19권7호
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    • pp.369-375
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    • 2009
  • The spot weldability of dissimilar metal joints between stainless steels (AISI316) and interstitial free (IF) steels were investigated. This study was aimed to determine the spot welding parameters for a dissimilar metal joint and to evaluate the dissimilar metal joint's weldability, including its welding nugget shape, tensileshear strength, hardness, and microstructure. The fracture surface was investigated by using a Scanning Electron Microscopy (SEM). The experimental results showed that the shape of nugget was asymmetric, in which the fusion zone of the STS316 sheet was larger due to the higher bulk-resistance. The microstructure of the fusion zone was fully martensite. In order to evaluate the microstructure further, dilution of stainless steels were calculated and imposed onto the Schaeffler diagram. The predicted microstructure from the Schaeffler diagram was martensite. In order to confirm the predicted microstructure, XRD measurements were carried out. The results showed that that initial weld nugget was composed of austenite and martensite.

Effect of Thermal History on Pitting Corrosion of High Nitrogen and Low Molybdenum Stainless Steels

  • Kim, Kwangsik;Chang, Hyunyoung;Kim, Youngsik
    • Corrosion Science and Technology
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    • 제2권2호
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    • pp.75-81
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    • 2003
  • Chromium, molybdenum. and nitrogen are very important alloying elements in stainless steels and its effect was approved in pitting resistance equivalent (PRE) equations and many experimental results. However, Cr can improve the corrosion resistance, but facilitate the formation of sigma phase. Also. Mo has the same effect in stainless steels. If Cr and Mo are added at high amount to increase the corrosion resistance of stainless steel, corrosion resistance in annealed alloys can be improved, but in case of welding or aging heat treatment. its resistance will be drastically decreased. In this work, increasing Cr and N contents but decreasing Mo than the commercial alloys made the experimental alloys. Typical alloys are 25Cr-4.5Mo-0.43N alloy, 27Cr-4.7Mo-0.4N alloy, 27Cr-5.3Mo-0.25N alloy, 32Cr-2.6Mo-0.36N alloy. After annealing and aging heat treatment, microstructures, anodic polarization test, and pitting corrosion test were performed. Annealed alloys showed $100^{\circ}C$ of CPT and aged alloys showed the different tendency depending upon Cr and Mo contents(SFI)

페라이트계 스테인레스강의 STICKING 발생 및 성장기구 (Nucleation and Growth Mechanism of Sticking Phenomenon in Ferritic Stainless Steel)

  • 진원;최점용
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1999년도 제3회 압연심포지엄 논문집 압연기술의 미래개척 (Exploitation of Future Rolling Technologies)
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    • pp.373-382
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    • 1999
  • Nucleation and growth process of sticking particle in ferritic stainless steels was investigated using a two disk type hot rolling simulator. The sticking behavior was strongly dependent on the surface roughness of a high speed steel roll(HSS) and the oxidation resistance of the ferritic stainless steels. A hot rolling condition with the lower oxidation resistance of the stainless steel and the higher surface roughness of HSS roll was more sensitive to sticking occurrence. It was also illucidated that the initial sticking particles were nucleated at the scratches formed on the roll surface and were served as the sticking growth sites. As rolling proceeded, the sticking particles grew sites. As rolling proceeded, the sticking particles grew by the process that the previous sticking particles provided the sticking growth sites.

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스테인리스강의 기계적 성질에 미치는 예비처리 후 가스질화조건의 영향 (Effect of Gas Nitriding Characteristics on the Mechanical Properties after Pre-Heat Treatment of Stainless Steels)

  • 김용현;김한군
    • 열처리공학회지
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    • 제23권3호
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    • pp.142-149
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    • 2010
  • Austenitic stainless steel is more or less difficult with conventional gas nitriding treatment, but it can be nitrided after appropriate pre-heat treatment. The pretreatment was more effective upon nitriding for austenitic stainless steel than martensitic stainless steel. Both thickness and microhardness measurements indicated that effect of the nitriding treatment was more sensitive in austenitic stainless steel than martensitic stainless steel with nitriding time. Fatigue strength was most increased with SACM 645 steel among three steels.

Development of High Performance Stainless Steel Powders

  • Schade, Christopher;Schaberl, John;Narasimhan, Kalathur S.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.169-170
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    • 2006
  • Advanced melting technology is now being employed in the manufacture of stainless steel powders. The new process currently includes electric arc furnace (EAF) technology in concert with Argon Oxygen Decarburization (AOD), High Performance Atomizing (HPA) and hydrogen annealing. The new high performance-processing route has allowed the more consistent production of existing products, and has allowed enhanced properties, such as improved green strength and green density. This paper will review these processing changes along with the potential new products that are being developed utilizing this technology. These include high strength stainless steels such as duplex and dual phase as well as stainless steel powders used in high temperature applications such as diesel filters and fuel cells.

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페라이트계 스테인리스강 용접접합부의 모재 블록전단파단에 관한 실험적 연구 (An Experimental Study on Block Shear Fracture of Base Metal in Ferritic Stainless Steel Welded Connection)

  • 김태수
    • 한국강구조학회 논문집
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    • 제28권5호
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    • pp.303-312
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    • 2016
  • 최근에 스테인리스강의 우수한 연성과 내식성 등의 재료적 특성으로 건축물의 구조용 강재로 적용하기 위한 많은 연구들이 수행되어 오고 있다. 특히, 니켈을 거의 함유하고 있지 않은 페라이트계 스테인리스강은 재료비 측면에서 니켈을 함유하고 있는 오스테나이트계 스테인리스강에 비해 저렴하고 탄소강에 비해서는 월등한 내식성능과 구조성능을 제공하기 때문에 그 사용성이 증대되고 있다. 본 연구에서는 페라이트계 스테인리스강 용접접합부에 있어 용착금속이 아닌 모재 블록전단파단의 구조적 거동을 조사하기 위해 용접길이와 용접방법(아크, 티그)을 변수로 하여 단순인장 실험을 실시하였다. 용접접합부의 블록전단 거동은 용접에 의한 삼축응력효과 때문에 볼트접합부의 블록전단 거동과 상이하며, 현행설계기준식은 이러한 특성을 반영하지 못하고 있다. 티그용접 접합부의 변형능력과 최대내력이 아크용접 접합부보다 높게 나타났고, 현행기준식과 기존연구자에 의해 제시된 내력식에 의한 예측내력과 실험결과 최대내력을 비교 검토하였다.