• 한국산학기술학회논문지
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• 제18권5호
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• pp.16-21
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• 2017

본 연구의 목적은 스테인레스 강 제조시 발생하는 페로니켈 슬래그를 파쇄한 미분말을 이용하여 지하매설물용 유동성 뒤채움재로 활용하기 위한 것이다. 페로니켈 슬래그 미분말을 이용한 유동성 뒤채움재의 최적배합설계를 수행하였다. 실험용 조합은 Case A (모래), Case B (흙) 등 2개 조합을 이용하였다. Case A의 최적배합비는 모래(58.4%), 페로니켈 슬래그 미분말 (21.6%), 시멘트(1.8%), 물(18.2%)이고, Case B의 최적배합비는 흙(53.0%), 페로니켈 슬래그 미분말 (20.0%), 시멘트(1.7%), 물(25.3%)로 결정되었다. 전체적으로 일반모래에 페로니켈슬래그 미분말을 혼합한 Case A의 일축압축강도가 흙을 이용한 Case B에 비해 상대적으로 크게 나타났다. 또한, 시편의 강도는 양생시간에 따라 증가하는 경향을 나타냈다. 전체적으로 양생시간에 따라 일축압축강도가 증가하는 경향을 보이고 있다. 또한, 일반모래를 주재료로 이용한 유동성뒤채움재의 일축압축강도가 흙을 주재료로 이용한 혼합재료에 비해 상대적으로 크게 나타났다. Case A의 경우 양생시간 7일, 14일 및 28일에 따른 일축압축강도의 범위는 각각 0.17-0.33 MPa, 0.21-0.39 MPa, 0.19-0.40 MPa 수준으로 평가되었다. 실험결과로부터 Case A3 정도면 FNS미분말과 시멘트 혼합비율 가장 적정한 것으로 판단되었다. 흙을 주재료로 이용한 Case B의 경우도 Case A와 전체적으로 유사한 경향을 나타냈다. FNS미분말의 환경유해성 평가를 위한 용출시험결과, 환경에 유해한 물질의 용출은 없는 것으로 나타났다.

• Journal of Welding and Joining
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• 제18권2호
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• pp.176-176
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• 2000

Recently developed Austenite stainless steel,309L was to overlay on 3Cr-1Mo-V-Ti-B steels, using Electroslag welding process, which wide electrodes were adopted. Transition region in welding interlayer relating to disbonding crack was investigated. Also. the effect of welding condition on the width of transition region and coarsening grains of the austenite were studied.1) With increasing welding speed the width of martensite at transient region was increased, but the amount of delta ferrite in weld metal was reduced, being fine grained.2) The form of martensite at the transition region was occured by reversible transition region, leading to increasing Ms point.3) With increasing welding speed, the grain of austenite formed at the welding interface was finer. With increasing welding current under the same welding speed, the grain size of the austenite was finer. At high current, original grain size of the austenite is coarse, but the austenite has fine grains because the austenite was transformed to martensite during cooling.4) In the case of high welding speed, the width of martensite at the welding interface was increased, but the grain size of austenite at the welding interface was finer. This indicates that the inhibition of disbonding crack may be achieved through dispersening fine carbides in the grain boudary.(Received August 3, 1999)

• 한국광물학회지
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• 제18권1호
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• pp.11-17
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• 2005

소각재 용융슬래그를 출발물질로 하여 알카리 조건하에서 활성화시킴으로써 Na-A형 제올라이트를 합성하였다. 합성실험은 스텐레스 철재로 제작된 반응용기를 사용하였다. 출발물질은 슬래그 외에 수정인공합성 공장에서 배출되는 '규산질 수용액'과 NaAlO₂ 수용액을 사용하였는데, 전자의 화학조성은 SiO₂ 5.7 wt% Na₂O 3.2 wt%이고, 후자는 몰비가 Na₂O/Al₂O₃= 1.2와 H₂O/Ma₂O=9의 조건으로 알루미늄 드로스와 NaOH 수용액을 반응시켜 제조하였다. 위에서 언급된 슬래그, '규산질 수용액' 그리고 NaAlO₂ 수용액을 혼합시킨 혼성물을 약 80℃에서 7∼8시간 반응시키면 Na-A형 제올라이트가 단일상으로 합성되었다. 출발물질의 이상적인 혼합비율은 Na₂O:Al₂O₃:SiO₂의 몰비가 1.3∼l.4 : 0.8∼0.9 : 2이었으며 반응용액과 슬래그의 비율은 1 : 7∼10 (g/cc)이었다. 합성된 제올라이트의 형태는 균일한 입방형이었으며 입도는 약 1 ㎛이었다. 한편, Ca/sup 2+/이온에 대한 이온교환 용량(CEC)은 180∼210 meq/100 g이었으므로 통용되는 세제용 제올라이트와 비교하면 약 80% 수준이었으므로 폐수처리나 오염된 중금속처리와 같은 환경처리용으로 사용될 수 있을 것이다.

• Journal of Advanced Marine Engineering and Technology
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• 제31권3호
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• pp.282-292
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• 2007

The present paper describes the results of high speed photography, acoustic emission (AE) detection and plasma light emission (LE) measurement during $CO_2$ laser welding of 304 stainless steel in different processing conditions. Video images with high spatial and temporal resolution allowed to observe the melt dynamics and keyhole evolution. The existence of keyhole was confirmed by the slag motion on the weld pool. The characteristic frequencies of flow instability and keyhole fluctuations at different welding speed were measured and compared with the results of Fourier analyses of temporal AE and LE spectra. The experimental results were compared with the newly developed numerical model of keyhole dynamics. The model is based on the assumption that the propagation of front part of keyhole into material is due to the melt ejection driven by laser induced surface evaporation. The calculations predict that a high speed melt flow is induced at the front part of keyhole when the sample travel speed exceeds several 10 mm/s. The numerical analysis also shows the hump formation on the front keyhole wall surface. Experimentally observed melt behavior and transformation of the AE and LE spectra with variation of welding speed are qualitatively in good agreement with the model predictions.

• Journal of Welding and Joining
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• 제16권5호
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• pp.108-118
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• 1998

This study proposes th analysis and evaluation method of time series ultrasonic signal using the chaos feature extraction for ultrasonic pattern recognition. Features extracted from time series data using the chaos time series signal analyze quantitatively weld defects. For this purpose, analysis objective in this study is fractal dimension and Lyapunov exponent. Trajectory changes in the strange attractor indicated that even same type of defects carried substantial difference in chaosity resulting from distance shifts such as 0.5 and 1.0 skip distance. Such differences in chaosity enables the evaluation of unique features of defects in the weld zone. In quantitative chaos feature extraction, feature values of 4.511 and 0.091 in the case of side hole and 4.539 and 0.115 in the case of vertical hole were proposed on the basis of fractal dimension and Lyapunov exponent. Proposed chaos feature extraction in this study can enhances ultrasonic pattern recognition results from defect signals of weld zone such as side hole and vertical hole.

• 해양환경안전학회지
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• 제3권2호
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• pp.23-31
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• 1997

The results of high speed photography, acoustic emission detection and plasma UV radiation intensity measurement during CO2 laser welding of stainless steel 304 are presented. Video images with high spatial and temporal resolution allowed to observe the melt dynamics and keyhole evolution. The existence of a high speed melt flow which originated from the part of weld pool and flowed along the sides wall of keyhole was confirmed by the slag motion on the weld pool. the characteristic frequencies of flow instability and keyhole fluctuations at different welding speed were measured and compared with the results of Fourier analyses of temporal acoustic emission (AE) and light emission (LE) spectra. The experimental results were compared with the newly developed numerical model of keyhole dynamics. (The model is based on the assumption that the propagation of front part of keyhole into material is due to the melt ejection driven by laser induced surface evaporation.) The calculations predict that a high speed melt flow is induced at the front part of keyhole when the sample travel speed exceeds several 10mm/s. The numerical analysis also shows the hump formation on the front keyhole wall surface. Experimentally observed melt behavior and transformation of the AE and LE spectra with variation of welding speed are qualitatively in good agreement with the model predictions.