• 대한기계학회논문집B
• /
• 제28권2호
• /
• pp.146-153
• /
• 2004

A Promising new approach to achieve low pollutant emissions and improvement of flame stability is tested experimentally using a cyclone jet hybrid combustor employing both premixed and diffusion combustion mode. Three kinds of nozzle are tested for mixing enhancement of fuel and air. The LNG (Liquified Natural Gas) is used as a fuel. The combustor is operated by two methods. One is DC (Diffusion Combustion) mode generated swirl flow by air as general swirl combustor, and the other is HC (Hybrid Combustion) mode. The HC mode consists of diffusion jet flame of axial direction and premixed cyclone flame of tangential direction in order to stabilized the diffusion jet flame. The results showed that the flame stability of HC mode is significantly enhanced than that of DC mode through the change of mixing characteristics by modifications of fuel nozzle. In addition, the reductions of CO and NOx emission in HC mode, as compared with that for the DC mode, is large than about 50% in stable region. Also, even using the low calorific fuel as $CO_2$-blended gas, it is identified that the cyclone jet hybrid combustor has the high performance of flame stability.

• 한국마린엔지니어링학회:학술대회논문집
• /
• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
• /
• pp.87-92
• /
• 2005

Experiments at the Japan Microgravity Center(JAMIC) have investigated the interaction between diffusion flames and solid surfaces placed near flames. The fuel for the flames was $C_2H_4$. The surrounding oxygen concentration was 35% with temperatures of $T_a$=300. Especially, the effect of wall temperature on soot deposition from a diffusion flame placed near the wall has been studied by utilizing microgravity environment, which can attain very stable flame along the wall. Cylindrical burner with fuel injection was adopted to obtain two dimensional soot distributions by laser extinction method. In the experiment two different wall temperatures, $T_w$=300,800K, were selected as test conditions. The results showed that the soot distribution between flame and burner wall was strongly affected by the wall temperature and soot deposition increases with decrease in wall temperature. The comparison among the values for two different wall temperatures suggested that the change in thermophoretic effect is the most dominant factor to give the change in soot deposition characteristics.

• 한국재료학회지
• /
• 제17권9호
• /
• pp.463-468
• /
• 2007

The interdiffusion characteristics of Cu-plug/Capping Layer/NiSi contacts were investigated. Capping layers were deposited on Ni/Si to form thermally-stable NiSi and then were utilized as diffusion barriers between Cu/NiSi contacts. Four different capping layers such as Ti, Ta, TiN, and TaN with varying thickness from 20 to 100 nm were employed. When Cu/NiSi contacts without barrier layers were furnace-annealed at $400^{\circ}C$ for 40 min., Cu diffused to the NiSi layer and formed $Cu_3Si$, and thus the NiSi layer was dissociated. But for Cu/Capping Layers/NiSi, the Cu diffusion was completely suppressed for all cases. But Ni was found to diffuse into the Cu layer to form the Cu-Ni(30at.%) solid solution, regardless of material and thickness of capping layers. The source of Ni was attributed to the unreacted Ni after the silicidation heat-treatment, and the excess Ni generated by the transformation of $Ni_2Si$ to NiSi during long furnace-annealing.

• 한국표면공학회지
• /
• 제48권1호
• /
• pp.11-22
• /
• 2015

Pd alloy hydrogen membranes for hydrogen purification and separation need thermal stability at high temperature for commercial applications. Intermetallic diffusion between the Pd alloy film and the porous metal support gives rise to serious problems in long-term stability of Pd alloy membranes. Ceramic barriers are widely used to prevent the intermetallic diffusion from the porous metal support. However, these layers result in poor adhesion at the interface between film and barrier because of the fundamentally poor chemical affinity and a large thermal stress. In this study, we developed Pd alloy membranes having a dense microstructure and saturated composition on modified metal supports by advanced DC magnetron sputtering and heat treatment for enhanced thermal stability. Experimental results showed that Pd-Cu and Pd-Ag alloy membranes had considerably enhanced long-term stability owing to stable, dense alloy film microstructure and saturated composition, effective diffusion barrier, and good adhesive interface layer.

• 정보보호학회논문지
• /
• 제33권6호
• /
• pp.1111-1123
• /
• 2023

최근 생성 모델이 발전함에 따라 생성 모델을 위협하는 연구도 활발히 진행되고 있다. 본 논문은 Text-to-Image 모델에 대한 멤버십 추론 공격을 위한 새로운 제안 방법을 소개한다. 기존의 Text-to-Image 모델에 대한 멤버십 추론 공격은 쿼리 이미지의 caption으로 단일 이미지를 생성하여 멤버십을 추론하였다. 반면, 본 논문은 Textual Inversion을 통해 쿼리 이미지에 personalization된 임베딩을 사용하고, Adversarial Prompt 생성 방법으로 여러 장의 이미지를 효과적으로 생성하는 멤버십 추론 공격을 제안한다. 또한, Text-to-Image 모델 중 주목받고 있는 Stable Diffusion 모델에 대한 멤버십 추론 공격을 최초로 진행하였으며, 최대 1.00의 Accuracy를 달성한다.

• 공업화학
• /
• 제2권4호
• /
• pp.399-410
• /
• 1991

저장 안정한 액체염료의 제조를 위하여 새로운 분리 기술을 도입하였다. 액체염료에 함유된 무기염의 종류, 농도 및 액체염료의 저장기간이 염료분자의 집합(aggregation)과 안정성에 미치는 영항을 실험측정하였다. 높은 염농도에 의한 염료분자의 집합의 형성을 방지하지 위해 표면처리한 중공사막을 이용한 역확산(counter diffusion)법을 도입하여 액체염료에 함유된 염을 선택적으로 제거하였다. 역확산에 의한 염의 제거 효율은 1회 통과에 5-20%였고 염과 염료의 분리비는 10-700으로 매우 큰 값을 갖는 반면 염료의 손실율은 0.4% 이하였다. 모델식을 이용하여 구한 염과 염료의 막에 대한 물질전달 계수 ($U_{M,Na}$, $U_{M,Dye}$)는 표면처리한 경우에 각각 2.75와 $0.72l/m^2/hr$의 값을 나타내어 염과 염료의 혼합액에서 염의 선택적 분리가 가능함을 보여주었다. 또한 탈거수 및 공급액의 유속, 막의 막힘현상이 염의 제거 효율에 미치는 영향을 연구하였다.

• 한국재료학회지
• /
• 제26권12호
• /
• pp.751-756
• /
• 2016

Graphite was diffusion-bonded by hot-pressing to W-25Re alloy using a Ti interlayer. For the joining, a uniaxial pressure of 25 MPa was applied at $1600^{\circ}C$ for 2 hrs in an argon atmosphere with a heating rate of $10^{\circ}C\;min^{-1}$. The interfacial microstructure and elemental distribution of the W-25Re/Ti/Graphite joints were analyzed by scanning electron microscopy (SEM). Hot-pressed joints appeared to form a stable interlayer without any micro-cracking, pores, or defects. To investigate the high-temperature stability of the W-25Re/Ti/Graphite joint, an oxy-acetylene torch test was conducted for 30 seconds with oxygen and acetylene at a 1.3:1 ratio. Cross-sectional analysis of the joint was performed to compare the thickness of the oxide layer and its chemical composition. The thickness of W-25Re changed from 250 to $20{\mu}m$. In the elemental analysis, a high fraction of rhenium was detected at the surface oxidation layer of W-25Re, while the W-25Re matrix was found to maintain the initial weight ratio. Tungsten was first reacted with oxygen at a torch temperature over $2500^{\circ}C$ to form a tungsten oxide layer on the surface of W-25Re. Then, the remaining rhenium was subsequently reacted with oxygen to form rhenium oxide. The interfacial microstructure of the Ti-containing interlayer was stable after the torch test at a temperature over $2500^{\circ}C$.

• 한국산업보건학회지
• /
• 제7권1호
• /
• pp.21-31
• /
• 1997

Toluene, n-hexane, and methyl ethyl ketone(MEK) were exposed to the activated carbon fiber(ACF) and 3M(Model 3500) diffusive samplers under low and high humidity levels. In order to evaluate these two samplers, the sampling capacity, sampling rate, reverse diffusion, and storage stability were obtained. At low humidity level($8{\pm}3%RH$), the adsorption amount of all three organic vapors to the ACF diffusive sampler showed a positive linear relationship up to 8 hours. However, at high humidity level($90{\pm}5%RH$), n-hexane and MEK maintained a positive linear relationship up to 1.5 hrs, but decreased in their adsorption amounts afterwards. On the other hand, the adsorption amount of n-hexane, MEK, and toluene to 3M diffusive sampler showed almost a positive linear relationship up to 8 hours at both humidity levels. At low humidity level, there was almost no reverse diffusion for both 3M and ACF diffusive samplers. However, when the ACF diffusive sampler was used at high humidity level, there was about 52.63% of MEK sample loss and about 92.59% of n-hexane sample loss. The storage stabilities of the ACF and 3M diffusive samplers were both relative stable except for MEK. In the case of MEK, the difference between the analysis of the organic vapor right after the sampling and that of 3 weeks later at room temperature was 45% for the ACF diffusive sampler and 18% for the 3M diffusive sampler. Since the storage stability of the samples stored in a refrigerator was relatively stable, they need to be refrigerated until the analysis is done.

• 한국표면공학회지
• /
• 제49권3호
• /
• pp.286-300
• /
• 2016

Pd-Ag alloy membranes have attracted a great deal of attention for their use in hydrogen purification and separation due to their high theoretical permeability, infinite selectivity and chemical compatibility with hydro-carbon containing gas streams. For commercial application, Pd-based membranes for hydrogen purification and separation need not only a high perm-selectivity but also a stable long-term durability. However, it has been difficult to fabricate thin, dense Pd-Ag alloy membranes on a porous stainless steel metal support with surface pores free and a stable diffusion barrier for preventing metallic diffusion from the porous stainless steel support. In this study, thin Pd-Ag alloy membranes were prepared by advanced Pd/Ag/Pd/Ag/Pd multi-layer sputter deposition on the modified porous stainless steel support using rough polishing/$ZrO_2$ powder filling and micro-polishing surface treatment, and following Ag up-filling heat treatment. Because the modified Pd-Ag alloy membranes using rough polishing/$ZrO_2$ powder filling method demonstrate high hydrogen permeability as well as diffusion barrier efficiency, it leads to the performance improvement in hydrogen perm-selectivity. Our membranes, therefore, are expected to be applicable to industrial fields for hydrogen purification and separation owing to enhanced functionality, durability and metal support/Pd alloy film integration.

• 한국진공학회지
• /
• 제13권3호
• /
• pp.109-113
• /
• 2004

InP에서 열처리 온도와 시간 및 활성화 온도에 따른 Zn의 확산의 특성을 electrochemical capacitance-voltage 법으로 조사하였다. InP층은 metal organic chemical vapor deposition를 이용하여 성장하였으며, 화산방법으로는 $Zn_3P_2$ 확산과 박막과 rapid thermal annealing를 사용하였다. 최대의 정공 농도를 갖는 p-lnP 층은 $550^{\circ}C$에서 5분 동안 확산과 활성화를 한 시료에서 얻었고, Zn의 농도는 $1\times10^{19}\textrm{cm}^{-3}$이었다. $550^{\circ}C$에서 5-20 분 동안 확산을 수행한 결과 정공농도의 확산 깊이는 1.51 $\mu\textrm{m}$에서 3.23 $\mu\textrm{m}$로 이동하였고, Zn의 확산계수는 $5.4\times10^{-11}\textrm{cm}^2$/sec이었다. 활성화 시간의 증가로, Zn가 더 깊게 확산하지만, 정공농도는 거의 변화가 없었다. 이는 도핑된 영역의 과잉의 침입형 Zn가 도핑되지 않은 영역으로 빠르게 확산하고 치환형 Zn로 변한다는 것을 의미한다. 정공농도는 $SiO_2$ 박막의 두께가 1,000$\AA$ 이상이어야 안정적으로 분포된다.