• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.299-303
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• 2015

The electrolyte is an important component in determining the performance of Fuel Cells. Especially, investigation of the conduction properties of electrolytes plays a key role in determining the performance of the electrolyte. The electrochemical properties of Yttrium stabilized zirconia (YSZ) were measured to allow the use of this material as an electrolyte for solid oxide fuel cells (SOFC) in the temperature range of $700-1000^{\circ}C$ and in $0.21{\leq}pO_2/atm{\leq}10^{-23}$. A Hebb-Wagner polarization experimental cell was optimally manufactured; here we discuss typical problems associated with making cells. The partial conductivities due to electrons and holes for 8YSZ, which is known as a superior oxygen conductor, were obtained using I-V characteristics based on the Hebb-Wagner polarization method. Activation energies for holes and electrons are $3.99{\pm}0.17eV$ and $1.70{\pm}0.06eV$ respectively. Further, we calculated the oxygen ion conductivity with electron, hole, and total conductivity, which was obtained by DC four probe conductivity measurements. The oxygen ion conductivity was dependent on the temperature; the activation energy was $0.80{\pm}0.10eV$. The electrolyte domain was determined from the top limit, bottom limit, and boundary (p=n) of the oxygen partial pressure. As a result, the electrolyte domain was widely presented in an extensive range of oxygen partial pressures and temperatures.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.2
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• pp.174-177
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• 2019

The traditional yttria-stabilized zirconia (YSZ) used in thermal barrier coatings has a limited operating temperature owing to densification and volume changes at high temperatures. A $(La_{1-x}Y_x)_2Zr_2O_7$ sintered compound was prepared by the co-precipitation and oxalate methods, by adding lanthanum zirconate to yttria. The thermal properties and crystallinity obtained by the two different methods were compared. Both methods yielded pyrochlore structures, and the oxalate method confirmed phases at low temperatures. The thermal conductivity of the sintered bulk prepared by co-precipitation was 0.93 W/mK, while that prepared by the oxalate method was 0.85 W/mK. These values are superior to that of 4YSZ at $1,000^{\circ}C$, which is widely used in industries.

• Korean Journal of Metals and Materials
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• v.50 no.9
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• pp.685-690
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• 2012

Decalcomania is a new method for SOFCs (solid oxide fuel cells) unit cell fabrication. A tight and dense $5{\mu}m$ Yttria-stabilized zirconia (8YSZ) electrolyte layer on anode substrate was fabricated by the decalcomania method. After 8YSZ as the electrolyte starting material was calcined at $1200^{\circ}C$, the particle size was controlled by the attrition mill. The median particle size (D50) of each 8YSZ was $39.6{\mu}m$, $9.30{\mu}m$, $6.35{\mu}m$, and $3.16{\mu}m$, respectively. The anode substrate was coated with decalcomania papers which were made by using 8YSZ with different median particle sizes. In order to investigate the effect of median particle sizes and sintering conditions on the electrolyte density, each sample was sintered for 2, 5 and 10 h, respectively. 8YSZ with a median particle size of $3.16{\mu}m$ which was sintered at $1400^{\circ}C$ for 10 had the highest density. With this 8YSZ, a SOFCs unit cell was manufactured with a $5{\mu}m$ layer by the decalcomania method. Then the unit cell was run at $800^{\circ}C$. The Open Circuit Voltage (OCV) and Maximum power density (MPD) was 1.12 V and $650mW/cm^2$, respectively.

• Carbon letters
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• v.14 no.2
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• pp.94-98
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• 2013

Isotropic pitch fibers were stabilized and carbonized for preparing carbon fibers. To optimize the duration and temperature during the stabilization process, a thermogravimetric analysis was conducted. Stabilized fibers were carbonized at 1000, 1500, and $2000^{\circ}C$ in a furnace under a nitrogen atmosphere. An elemental analysis confirmed that the carbon content increased with an increase in the carbonization temperature. Although short graphitic-like layers were observed with carbon fibers heat-treated at 1500 and $2000^{\circ}C$, Raman spectroscopy and X-ray diffraction revealed no significant effect of the carbonization temperature on the crystalline structure of the carbon fibers, indicating the limit of developing an ordered structure of isotropic pitch-based carbon fibers. The electrical conductivity of the carbonized fiber reached $3.9{\times}10^4$ S/m with the carbonization temperature increasing to $2000^{\circ}C$ using a four-point method.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.547-550
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• 2005

Gauge blocks are the most widely used material measure in length field in industry. The gauge block interferometer, which is the gauge block measuring system, comprises Twyman-Green type interferometer optics and light sources having precisely known wavelengths. This paper describes the work done for advancing the measurement system and automating the measurement process. The advancing of the system was done mainly by exchanging the spectral lamp with the frequency stabilized lasers, and the automation of measurement was achieved by modifying the hardware and developing the automatic measuring software. As the results of this work, the contrast of interferometric fringes of gauge blocks longer than 100 mm s enhanced about 20 times, and the measurement time has reduced down to 50% by automation.

• Korean Journal of Optics and Photonics
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• v.15 no.2
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• pp.177-182
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• 2004

We have observed the saturated absorption spectrum of the P(16) line of the V$_1$＋V$_3$ band of $^{13}$ C$_2$H$_2$ molecule by using the external cavity spectroscopy method. The frequency of laser has been stabilized to the saturated absorption spectrum. The relative contrast of the saturation spectrum is about 7 % with respect to the linear absorption and the linewidth is about 1.8 MHz. The frequency fluctuation of the stabilized LD is about $\pm$20 KHz during the sampling time 100 S.

• Journal of the Korean Society of Propulsion Engineers
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• v.3 no.1
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• pp.48-54
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• 1999

A method was disclosed for making phase stabilized ammonium nitrate(PSAN), where the process involves precipitation of ammonium nitrate(AN) with potassium dinitramide(KDN) from the aqueous solutions of their salts using a salting out technique. The organic solvent used as a precipitant was acetonitrile. The DSC results showed that the precipitates are PSAN, and AN is stable over the temperature range from $0^{\cire}C$ to $80^{\cire}C$ if the KDN concentration in the precipitated solids is greater than about 6 wt.%. The particles prepared are expected to be useful as an oxidizer for the solid rocket propellants and explosives.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.10
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• pp.3234-3242
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• 1996

This paper describes experimental results of modified small punch( MSP) test conducted to evaluate the fracure characteristics and mechanical properties of plasma sparayed zirconia ($ZrO_2$ stabilized with 8wt. % $Y_20_3$ : YSZ) NiCrAlY composite. The mixing ratios of YSZ/NiCrAlY were 0/100, 25/75, 50/50, 100/0 v.%. Test temperatures ranged from 293K to 1473K. This study is directed at development of thermal barrrier coating(TBC) system with superior heat resistance and mechanical properties. The microstructure and fracture process of the composite were examined by SEM and AE method. The mechanical properties of 100% YSZ were nearly independent of the temperatures tested in this study. In contrast, the NiCrAlY-containing composites showed a significant decrease of the mechanical properties above 1273K, showing a ductile- brittle transition behavior up to the temperature. Furthermore, it can seen that 25% YSZ/75% NiCrAlY composite gave the highest fracure strength and fracture energy among the mixing ratio tested over the temperature range.

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.9-17
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• 1996

Solid oxide electrolytes of 8mol% YSZ($Y_2O_3$ stabilized zirconia) were prepared at various sintering conditions and their ionic conductivities were measured. The highest ionic conductivity of $10^{-1}S.cm^{-1}$ was obtained when the sintering temperature was 1400oC and the sintering time was 10hr. Also the cathode material, $La_{1-x}Sr_xMnO_3$ was prepared by solid state reaction method and the overpotential, electrical conductivity, and charge transfer resistance between cathode material and YSZ electrolyte were studied. It was found that the optimum doping content of Sr for La was 50mo1%.

• Korean Journal of Optics and Photonics
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• v.13 no.6
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• pp.530-536
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• 2002

The accurate measurements of thermal expansion coefficients is one of the most important techniques required not only in material science but also in industries. A high precision interferometric dilatometer, using acoustic optical modulator, has been constructed and its performance has been tested. The system consists of a double-path optical heterodyne interferometer and a radiant heating furnace. This provides highly accurate length measurement, and allows rapid heating and cooling method for the specimen. A three longitudinal mode frequency stabilized He-Ne laser, using the secondary beat frequency, is constructed. Its stability is found to be $5{\times}10^{-9}$. The uncertainty in the length measurement is estimated to be of nanometer order in the range between room temperature to 1100 K.