• Title/Summary/Keyword: Stabilized Interface

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Growth and properties of LCMO/YBCO heterostructure

  • Kumar, Manish;Lee, Hyun Hwi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.151.1-151.1
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    • 2016
  • Complex oxide heterointerfaces have been extensively explored in the past due to the novel phenomenon emerging at such interfaces that differ from their individual bulk counterparts. The integration of a ferromagnetic (FM) material with the superconducting (SC) material leading to proximity effect is one of the commonly studied phenomenon in these heterostructures. In continuation, we have stabilized the FM layer La0.7Ca0.3MnO3 (LCMO) on SC material YBa2Cu3O7-${\delta}$ (YBCO) using pulsed laser deposition technique and explored the structural, magnetic, electrical and magneto-transport properties of this heterostructure. ${\Phi}$-scan measurements confirm the epitaxial nature of LCMO/YBCO heterostructure grown on single crystalline SrTiO3 substrate. The FM transition of LCMO and SC transition of YBCO are observed in the magnetization measurements of the bilayer structure. Through electrical measurements, we understood that the proximity effect leads to lowering of the SC transition of YBCO. The role of interface in the bilayer structure is also realized through electrical transport measurements.

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Relative Comparison of Cathode Polarizations in Solid Oxide Fuel Cells Using the Spreading Concept in AC 2 Point Impedance Spectroscopy

  • Lee, Byung-Kook;Kim, Eui-Hyun;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.163-167
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    • 2013
  • A modified two-point impedance spectroscopy technique exploits the geometric constriction between an electrolyte and a cathode with an emphasis on semispherical-shaped electrolytes. The spatial limitation in the electrolyte/electrode interface leads to local amplification of the electrochemical reaction occurring in the corresponding electrolyte/electrode region. The modified impedance spectroscopy was applied to electrical monitoring of a YSZ ($Y_2O_3$-stabilized $ZrO_2$)/SSC ($Sm_{0.5}Sr_{0.5}CoO_3$) system. The resolved bulk and interfacial component was numerically analyzed in combination with an equivalent circuit model. The effectiveness of the "spreading resistance" concept is validated by analysis of the electrode polarization in the cathode materials of solid oxide fuel cells.

Computer Simulations on the Thermal Behaviors of a Friction Pad in High-Speed Train Disk Brakes

  • Kim, Chung Kyun
    • KSTLE International Journal
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    • v.1 no.2
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    • pp.95-100
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    • 2000
  • The thermal behaviors of disk-pad braking models has been analyzed for a high-speed train brake system using the coupled thermal-mechanical analysis technique. The temperature distribution, thermal distortion, and contact stress in the disk-pads contact model have been investigated as functions of the convective heat transfer rate. The FEM results indicate that multiple spot type pads show more stabilized thermal characteristics compared with those of the flat type pads for the increased convective heat transfer rate. The maximum contact stress for a friction pad loaded against a rubbing disk was occurred on the edge of the pad at the disk-pad interface.

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Condition and New Testing Method of Interfacial Oxide Films in Directly Bonded Silicon Wafer Pairs (직접 접합된 실리콘 기판쌍에 있어서 계면 산화막의 상태와 이의 새로운 평가 방법)

  • ;;;;D.B. Murfett;M.R.Haskard
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.3
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    • pp.134-142
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    • 1995
  • We discovered that each distinct shape of the roof-shaped peaks of (111) facets, which are generated on (110) cross-section of the directly bonded (100) silicon wafer pairs after KOH etching, can be mapped to one of three conditions of the interfacial oxide existing at the bonding interface as follows. That is, thick solid line can be mapped to stabilization, thin solid line to disintegration, and thin broken line to spheroidization. also we confirmed that most of the interfacial oxides of a well-aligned wafer pairs were disintegrated and spheroidized through high-temperature annealing process above 900$^{\circ}$C while the oxide was stabilized persistently when two wafers are bonded rotationally around their common axis perpendicular to the wafer planes.

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Investigation of Interface Reaction between TiAl Alloys and Mold Materials

  • 김명균;김영직
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.289-289
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    • 1999
  • This paper describes the investment casting of TiAl alloys. The effects of mold material and mold preheating temperature for the investment casting of TiAl on metal-mold interfacial reaction were investigated by means of optical micrography, hardness profiles and an electron probe microanalyzer. The mold materials examined were colloidal silica bonded ZrO₂, ZrSiO₄, A1₂O₃and CaO stabilized ZrO₂. When compared with conventional titanium a1loy, the high aluminum concentration of TiAl alloys helps to lower their reactivity in the molten state. The A1₂O₃mold is a promising mold material for the investment casting of TiAl in terms of the thermal stability, formability and cost. Special attention need to be paid to thermal stability and mold preheating when developing the investment calling of TiAl alloys.

Evaluation of Shear-Induced Phase Transformation of $\beta$-Cristobalite by Fiber Push-Out Technique

  • Sang Jin Lee;Dong Zhu;Jae Suk Sung
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.208-212
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    • 1997
  • Shear-induced phase transformation behavior of chemically stabilized $\beta$-cristobalite was studied by the fiber push-out technique. To obtain the critical grain size for phase transformation, the hot-pressed polycrystalline $\beta$-cristobalite, which was used as the interphase between fiber and matrix, was annealed at $1300^{\circ}C$ for 10h. Two types of fibers, mullite and sapphire fiber, were used in this study. Debonding between mullite fiber and cristobalite interphase occurred at a critical load of 230 MPa. Static friction and fiber sliding were continuously followed by debonding. Shear-induced transformation induced cracks in the cristobalite interphase at the debonding stage. In the case of the sapphire fiber, the debonding occurred at a lower load of 180 MPa due to the residual stress in the interface caused by the difference in thermal expansion coefficients between the fiber and the cristobalite interphase. The load was insufficient for shear-induced phase transformation.

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Fracture Characteristics of NiCr/ZrO2 Functionally Graded Material by Gas Burner Thermal Shock (가스버너 열충격에 의한 NiCr/ZrO2계 경사기능재의 열적 파괴특성)

  • Song, Jun-Hee
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.247-252
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    • 2006
  • Joining Yittria Stabilized Zirconia (YSZ) to NiCr metal was fabricated using YSZ/NiCr Functionally Graded Materials (FGM) Interlayer by hot pressing process. Microscopic observations demonstrate that the composition and microstructure of YSZ/NiCr FGM distribute gradually in stepwise way, eliminating the macroscopic ceramic/metal interface such as that in traditional ceramic/metal joint. The thermal characteristics of this YSZ/FGM/NiCr joint were studied by thermal shock testing and therml barrier testing. Thermal shock test was conducted by gas burner rig. Acoustic Emission (AE) monitoring was performed to analyze the microfracture behavior during the thermal shock test. It could be confirmed that FGM was the excellent performance of thermal shock/barrier resistance at above $1000^{\circ}C$.

Characteristics of Composite Electrolyte with Graphene Quantum Dot for All-Solid-State Lithium Batteries (이종 계면저항 저감 구조를 적용한 그래핀 양자점 기반의 고체 전해질 특성)

  • Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.114-118
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    • 2022
  • The stabilized all-solid-state battery structure indicate a fundamental alternative to the development of next-generation energy storage devices. Existing liquid electrolyte structures severely limit battery stability, creating safety concerns due to the growth of Li dendrites during rapid charge/discharge cycles. In this study, a low-dimensional graphene quantum dot layer structure was applied to demonstrate stable operating characteristics based on Li+ ion conductivity and excellent electrochemical performance. Transmission electron microscopy analysis was performed to elucidate the microstructure at the interface. The low-dimensional structure of GQD-based solid electrolytes has provided an important strategy for stable scalable solid-state lithium battery applications at room temperature. This study indicates that the low-dimensional carbon structure of Li-GQDs can be an effective approach for the stabilization of solid-state Li matrix architectures.

Evaluation of Crack Width Based on the Actual Bond Stress-Slip Relationship in Structural Concrete Members (부착응력-미끌림 관계에 기반한 철근콘크리트 부재의 균열폭 산정)

  • Kim, Woo;Lee, Ki-Yeol;Kim, Jang-Hyun
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.91-100
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    • 2006
  • This paper presents an analytical model for evaluation of crack widths in structural concrete members. The model is mathematically derived from the actual bond stress-slip relationships between the reinforcement and the surrounding concrete, and the relationships summarized in CEB-FIP Model Code 1990 are employed in this study together with the assumption of a linear slip distribution along the interface at the stabilized cracking stage. With these, the actual strains of the steel and the concrete are integrated respectively along the embedment length between the adjacent cracks so as to obtain the difference in the axial elongation. The model is applied to the test specimens available in literatures, and the predicted values are shown to be in good agreement with the experimentally measured data.

Modeling of Tension Stiffening Effect Based on Nonlinear Bond Characteristics in Structural Concrete Members (비선형 부착 특성에 기반한 철근콘크리트 부재의 인장증강효과 모델)

  • Lee, Gi-Yeol;Ha, Tae-Gwan;Kim, Woo
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.745-754
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    • 2007
  • This paper presents a unified modeling technique for tension stiffening effect in structural concrete members. The model is mathematically derived from the bond stress-slip relationships which account for splitting crack. The relationships in CEB-FIP Model Code 1990 and Eurocode 2 are employed together with the assumptions of a linear slip distribution along the interface and the uniform condition of concrete tensile contribution for the mid section of cracked member at the stabilized cracking stage. With these assumptions, a model of tension stiffening effect is proposed by accounting for the force equilibrium and strain compatibility condition associated to the steel strain and concrete contribution by bond stress. The model is applied to the test results available in literatures, and the predicted values are shown to be in good agreement with the experimentally measured behavior.