• Title/Summary/Keyword: Stabilization materials

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Effect of Process Variables and exisisting Ions on Highly Active Nano-sized ITO Powders Prepared by Precipitation Method (고활성 ITO (Indium-Tin Oxide) 나노 분말을 침전법으로 합성시의 공정 변수 및 존재하는 이온의 영향)

  • Lee, In-Gyu;Noh, Bong-Hyun
    • Journal of Powder Materials
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    • v.15 no.6
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    • pp.450-457
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    • 2008
  • The objectives of this study were the development of a synthesis technique for highly active nanosized ITO powder and the understanding of the reaction mechanisms of the ITO precursors. The precipitation and agglomeration phenomena in ITO and $In_{2}O_{3}$ precursors are very sensitive to reaction temperature, pH, and coexisting ion species. Excessive $Cl^-$ ion and $Sn^{+4}$ ions had a negative effect an synthesizing highly active powders. However, with a relevant stabilizing treatment the shape and size of ITO and $In_{2}O_{3}$ precursors could be controlled and high density sintered products of ITO were obtained. By applying the reprecipitation process (or stabilization technique), highly active ITO and $In_{2}O_{3}$ powders were synthesized. Sintering these powders at $1500^{\circ}C$ for 5 hours produced 97% dense ITO bodies.

A Study on the Characteristics of Machining for AC8A-T6 Aluminum Alloy (AC8A-T6 알루미늄 합금재의 절삭가공 특성에 관한 연구)

  • 최현민;김경우;김우순;김용환;김동현;채왕석
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.10a
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    • pp.192-197
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    • 2002
  • In this study, examined the cutting characteristics of alumuminum alloy AC8A-T6 that is used to present car piston materials. And in been holding materials machining empirically escape as result that experiment comparison changing the cutting speed and feed on various condition to choose efficient machining condition. The following results can be summarized from this research. 1. As the cutting speed decreased, principal cutting force and thrust cutting force is increased, and reason that cutting force interacts greatly in the low cutting speed is thought by result by BUE's stabilization. 2. The feed speed and cutting speed increase, friction factor is decrescent and the cause appeared the thrust cutting force is fallen than cutting force relatively because chip flow according to increase of the feed rate is constraint. 3. Though specific cutting resistance grows cutting area and the feed rate are few, the cause was expose that shear angle decreases by rake face of tool gets into negative angle remarkably as wear of a cutting tool or defect part of workpiece is cut. 4. Cutting speed do greatly depth of cut is slow, surface roughness examined closely through an experiment that becomes bad, and know that it can get good surface that process cutting speed because do feed rate by 0.1mm/rev low more than 250m/min to get good surface roughness can.

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Feasibility of Recycling Residual Solid from Hydrothermal Treatment of Excess Sludge

  • Kim, Kyoung-Rean;Fujie, Koichi;Fujisawa, Toshiharu
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.112-118
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    • 2008
  • Residual solid in excess sludge treated by hydrothermal reaction was investigated as raw material for its recycling. Treated excess sludge and residual solid were also focused on their content change during hydrothermal reaction. Two kinds of excess sludge, obtained from a local food factory and a municipal wastewater treatment process, were tested under various conditions. Following hydrothermal reaction, depending on the reaction conditions, biodegradable substrates in treated excess sludge appeared to increase. The separated residual solid was a composite composed of organic and inorganic materials. The proportion of carbon varied from 34.0 to 41.6% depending on reaction conditions. Although 1.89% of hazardous materials were detected, SiO2 (Quartz) was a predominant constituent of the residual solid. X-ray diffraction (XRD) experiments revealed that the residual solid was of a partially amorphous state, suggesting that the residual solids could be easily converted to stable and non harmful substances through a stabilization process. Thus, this technology could be successfully used to control excess sludge and its reuse.

Production of Cyanocarboxylic Acid by Acidovorax facilis 72W Nitrilase Displayed on the Spore Surface of Bacillus subtilis

  • Zhong, Xia;Yang, Shaomin;Su, Xinying;Shen, Xiaoxia;Zhao, Wen;Chan, Zhi
    • Journal of Microbiology and Biotechnology
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    • v.29 no.5
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    • pp.749-757
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    • 2019
  • Nitrilase is a valuable hydrolase that catalyzes nitriles into carboxylic acid and ammonia. Its applications, however, are severely restricted by the harsh conditions of industrial reaction processes. To solve this problem, a nitrilase from Acidovorax facilis 72W was inserted into an Escherichia coli-Bacillus subtilis shuttle vector for spore surface display. Western blot, enzyme activity measurements and flow cytometric analysis results all indicated a successful spore surface display of the CotB-nit fusion protein. In addition, the optimal catalytic pH value and temperature of the displayed nitrilase were determined to be 7.0 and $50^{\circ}C$, respectively. Moreover, results of reusability tests revealed that 64% of the initial activity of the displayed nitrilase was still retained at the $10^{th}$ cycle. Furthermore, hydrolysis efficiency of upscale production of cyanocarboxylic acid was significantly higher in the displayed nitrilase-treated group than in the free group expressed by E. coli (pET-28a-nit). Generally, the display of A. facilis 72W nitrilase on the spore surface of Bacillus subtilis may be a useful method for immobilization of enzyme and consequent biocatalytic stabilization.

Arthroscopic Stabilization of Acromioclavicular Joint Dislocation using TightRope® (TightRope®를 이용한 내시경하 급성견봉쇄골관절 탈구의 고정술 메리놀병원 정형외과)

  • Choi, Sun-Jin;Park, Jong-Hoon;Lee, Hyeong-Seok
    • Clinics in Shoulder and Elbow
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    • v.11 no.2
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    • pp.172-176
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    • 2008
  • Purpose: The proper surgical methods for treating acromioclavicular joint dislocation is still controversial. New methods should provide better early motion with sufficient strength. Materials and Methods: We performed arthroscopic stabilization using TightRope$^{(R)}$ (Arthrex, Inc, Naples, FL) in 10 cases of acromioclavicular joint dislocation between April, 2007, and December, 2007, and followup for a minimum of 10 months. We performed radiologic evaluation by comparing the clavicle anteroposterior radiograph with the contralateral one. Clinical evaluation was made for pain, function, and range of joint motion by Imatani's methods. Results: In clinical evaluation, 6 cases were excellent, 3 cases were good, and 1 case was poor. In radiologic evaluation, 9 cases were excellent and 1 case was poor. Redislocation occurred in 1 case. Conclusion: During short-term followup, 9 of 10 patients who underwent arthroscopic stabilization using TightRope$^{(R)}$ had excellent results in Imatini tests and radiologic evaluation, except 1 patient with redislocation.

Stabilization of Heavy Metal and CO2 Sequestration in Industrial Solid Waste Incineration Ash by Accelerated Carbonation (산업폐기물의 가속 탄산화법을 이용한 CO2 고용화 및 중금속 안정화 특성 연구)

  • Jung, Seong-Myung;Nam, Seong-Young;Um, Nam-Il;Seo, Joobeom;Yoo, Kwang-Suk;Ohm, Tae-In;Ahn, Ji-Whan
    • Mineral and Industry
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    • v.26
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    • pp.1-12
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    • 2013
  • In this study, an accelerated carbonation process was applied to stabilize hazardous heavy metals of industrial solid waste incineration (ISWI) bottom ash and fly ash, and to reduce $CO_2$ emissions. The most commonly used method to stabilize heavy metals is accelerated carbonation using a high water-to-solid ratio including oxidation and carbonation reactions as well as neutralization of the pH, dissolution, and precipitation and sorption. This process has been recognized as having a significant effect on the leaching of heavy metals in alkaline materials such as ISWI ash. The accelerated carbonation process with $CO_2$ absorption was investigated to confirm the leaching behavior of heavy metals contained in ISWI ash including fly and bottom ash. Only the temperature of the chamber at atmospheric pressure was varied and the $CO_2$ concentration was kept constant at 99% while the water-to-solid ratio (L/S) was set at 0.3 and $3.0dm^3/kg$. In the result, the concentration of leached heavy metals and pH value decreased with increasing carbonation reaction time whereas the bottom ash showed no effect. The mechanism of heavy metal-stabilization is supported by two findings during the carbonation reaction. First, the carbonation reaction is sufficient to decrease the pH and to form an insoluble heavy metal-material that contributes to a reduction of the leaching. Second, the adsorbent compound in the bottom ash controls the leaching of heavy metals; the calcite formed by the carbonation reaction has high affinity of heavy metals. In addition, approximately 5 kg/ton and 27 kg/ton $CO_2$ were sequestrated in ISWI bottom ash and fly ash after the carbonation reaction, respectively.

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Reduction of the Nitrogen in the Secondary Effluent by the Hybrid Sequential Aerobic-Anoxic Natural System (자연현상을 이용한 질산화-탈질공정에 의한 하수처리장 유출수의 질소제거)

  • Kim, Young-Chul;Chung, Paul-Gene;An, Ik-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.323-329
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    • 2005
  • In this paper, performance of a hybrid sequential aerobic-anaerobic natural system was investigated. Continuous aerobic and anoxic conditions were created by alternatively placing waste stabilization pond (WSP) and wale. hyacinth pond (WHP). Two pilot-scale treatment lines were built and operated; The first consists of WSP integrated with WHP and the second of WSP connected with Dark Pond(DP), namely control system ponds which were used to examine the effects of water hyacinth on nitrification and de-nitrification. The overall performance in nitrogen was 86% reduction in WSP-WHP and 36% in WSP-control pond system. Nitrogen was mostly removed by nitrification and de-nitrification which simultaneously occurred in the same water hyacinth ponds. For the de-nitrification, benthic layer was found out to be adequate support as a carbon source. In addition, WSP-WHP system was very effective in reducing phosphorus. Overall P removal efficiency in WSP-WHP is 81%, while it is only 16% in WSP-control. difference in phosphorus reduction between those two systems is thought to be caused by the plants and probably their roots producing extra-cellular materials, but these aspects need to be further studied.

Characteristics of Stabilization of Excavated Solid Wastes by Aerobic and Anaerobic Landfilling (호기 및 혐기매립에 의한 굴착폐기물의 안정화 특성 연구)

  • Park, Jin-Kyu;Oh, Dong Ik;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.76-85
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    • 2004
  • Anaerobic decomposition of municipal solid waste (MSW) had potential adverse impacts such as the production of methane and long-term post closure on human health and the environment. It was demonstrated that aerobic degradation of MSW resulted in the reduction of a methane yield and the enhancement of stabilization of MSW. Excavated solid wastes were both aerobically and anaerobically treated in order to evaluate the effects of air injection on the stabilization of landfill site. The municipal solid waste (MSW) samples were excavated from a 10-year old landfill (operation period: 1991. 11~1994. 11), Jeonju, Korea. Excavated municipal solid wastes are primarily composed of soils and vinyl/plastics. For the two aerobic simulated lysimeters, the levels of $O_2$ ranged 1.6~23.1% and the levels of $CO_2$ ranged 1.5~15.1%, which confirmed the aerobic decomposition. Aeration did prevent methane formation. For the anaerobic simulated lysimeter, the $CO_2$ rose as $O_2$ was consumed and low levels of CH4 were produced. The pH levels ranged from 7.7 to 8.9 for anaerobic lysimeter and from 7.3 to 8.5 for aerobic lysimeters. As expected, aerobic treatment proved to enhance the removal of biodegradable materials in the excavated solid wastes when monitoring the concentration of BOD, COD, $NH_4-N$, and $NO_3-N$ in the leachate.

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An Experimental Study on the Improvement of Microscopic Machinability of Glass using the Discharging Peak Control Techniques in the Electrochemical Discharge Machining Technologies

  • Chang, In-Bae;Kim, Nam-Hyeock;Kim, Byeong-Hee;Kim, Heon-Young
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.315-316
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    • 2002
  • Electrochemical discharge machining is a very recent technique for non-conducting materials such as ceramics and glasses. ECDM is conducted in the NaOH solution and the cathode electrode is separated from the solution by $H_2$ gas bubble. Then the discharge is appeared and the non-conductive material is removed by spark and some chemical reactions. In the ECDM technology, the $H_2$ bubble control is the most important factor to stabilize the discharging condition. In this paper, we proposed the discharge peak monitoring/ discharging duty feedback algorithms for the discharge stabilization and the feasibility of this algorithm is verified by various pattern machining in the constant preload conditions for the cathode electrode.

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Distance-based Formation Control: Background, Principal Results and Issues (거리기반 편대 제어: 기초지식, 주요결과 및 이슈)

  • Kang, Sung-Mo;Park, Myoung-Chul;Lee, Byung-Hun;Oh, Kwang-Kyo;Ahn, Hyo-Sung
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.5
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    • pp.398-409
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    • 2013
  • This paper provides an overview of distance-based formation control. Firstly, in this paper, we introduce preliminary background materials that are used in defining the distance-based formation control. Then, based on the preliminary background, we briefly review main results developed thus far in this field. Lastly, we provide some issues that need to be studied further in future works.