• Title/Summary/Keyword: Stabilization materials

검색결과 404건 처리시간 0.019초

저가형 탄소섬유 개발을 위한 자외선 조사 기반 의류용 PAN 섬유의 연속식 안정화 공정 개발 (Developing Continuous Stabilization Process for Textile-Grade PAN Fiber-Based Carbon Fiber Using UV Irradiation)

  • 문준하;성홍규;유지선;조세연;최재원
    • 한국분말재료학회지
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    • 제29권5호
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    • pp.418-423
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    • 2022
  • Carbon fibers (CFs) are considered promising composite materials for various applications. However, the high cost of CFs (as much as $26 per kg) limits their practical use in the automobile and energy industries. In this study, we developed a continuous stabilization process for manufacturing low-cost CFs. We employed a textile-grade polyacrylonitrile (PAN) fiber as a low-cost precursor and UV irradiation technique to shorten the thermal stabilization time. We confirmed that UV irradiation on the textile-grade PAN fibers could lower the initial thermal stabilization temperature and also lead to a higher reaction. These resulted in a shorter overall stabilization time and enhancement of the tensile properties of textile-grade PAN-based CFs. Our study found that only 70 min of stabilization time with UV irradiation was required to prepare textile-grade PAN-based low-cost CFs with a tensile strength of 2.37 ± 0.22 GPa and tensile modulus of 249 ± 5 GPa.

제지회계 지반개량재로 처리된 연약점토의 물리적 특성 (Physical Characteristics of Soft Clay Improved by PFA Stabilization Agent)

  • 김광빈;이용안;김유성
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 가을 학술발표회 논문집
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    • pp.561-568
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    • 2002
  • PFA(Paper Fly Ash) are reclaimed mainly or used in cement industry field as mixture agent in terms of materials recycling. Recently, research for recycling PFA as embankment materials or soil stabilization agent are undergoing in geotechnical engineering field. In this study, physical characteristics of PFA stabilization agent-soil admixtures are examined in change of water content, void ratio, consistency, grain distribution, specific gravity and density. Futhermore, the physical characteristics are compared with unconfined strength as engineering characteristics. Test results showed that unconfined strength and density are increased with increasing of PFA stabilization agent mixed ratio. On the other hand, specific gravity, void ratio and water content are decreased with increasing of PFA stabilization agent mixed ratio. It would be concluded that natural high water content ratio weak soil could be highly improved engineering and physical characteristics with PFA stabilization agent

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비압축성 물체의 수치해 안정화 기법 (A Pressure Stabilization Technique for Incompressible Materials)

  • Lee, Sang-Ho;Kim, Sang-Hyo
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1995년도 가을 학술발표회 논문집
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    • pp.153-160
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    • 1995
  • Mixed finite element formulations for incompressible materials show pressure oscillations or pressure modes in four-node quadrilateral elements. The criterion for the stability in the pressure solution is the so-called Babufka-Brezzi stability condition, and the four-node elements based on mixed variational principles do not appear to satisfy this condition. In this study, a pressure continuity residual based on the pressure discontinuity at element edges is used to study the stabilization of pressure solutions in bilinear displacement-constant pressure four-node quadrilateral elements. It is shown that the pressure solutions, although stable, exhibit sensitivity to the stabilization parameters.

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Yield enhancement of matrix precursor in short carbon fiber reinforced randomly oriented carbon/carbon composite

  • Raunija, Thakur Sudesh Kumar;Sharma, Sharad Chandra;Verma, Anil
    • Carbon letters
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    • 제19권
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    • pp.57-65
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    • 2016
  • Isroaniso matrix precursor synthesized from commercially available petroleum pitch was stabilized in air. The influence of oxygen mass gain during stabilization on the yield of matrix precursor was studied. Additionally, the influence of pressure on the yield of the stabilized matrix precursor in a real system was studied. The fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), yield, yield rate, and yield impact were used to check the effect of stabilization and pressure on the yield of the matrix precursor and the end properties of the composite thereafter. The results showed that the yield increased with stabilization duration up to 20 h whereas it decreased for stabilization duration beyond 20 h. Further results showed that the stabilized matrix precursor for a duration of 5 h could withstand almost two-fold greater hot-pressing pressure without resulting in exudation as compared to that of a 1 h stabilized matrix precursor. The enhanced hot-pressing pressure significantly improved the yield of the matrix precursor. As a consequence, the densification and mechanical properties were increased significantly. Further, the matrix precursor stabilized for a duration of 20 h or more failed to provide proper and uniform binding of the reinforcement.

폐자원을 이용한 중금속 오염토양의 안정화 - 총설 (Heavy Metal Stabilization in Soils using Waste Resources - A Critical Review)

  • 임정은;문덕현;김권래;양재의;이상수;옥용식
    • Journal of Applied Biological Chemistry
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    • 제58권2호
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    • pp.157-174
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    • 2015
  • 토양 중금속 안정화를 위해 농축수산 부산물, 산업부산물 등과 같은 다양한 폐자원이 활용되고 있다. 일례로 석회, 패각류, 난각류, 산업부산물 등의 알칼리물질, 동물의 뼈 및 인산용액, 인광석 등의 인 함유물질, 퇴비(compost), 가축분(manure), 바이오차(biochar) 등의 유기성물질과 이 외에도 영가철, 제오라이트(zeolite) 등의 다양한 물질들을 토양 내 중금속 안정화의 소재로 활용하기 위한 효율성, 적용성 연구가 진행되고 있다. 이들 물질에 대한 토양 적용 후 중금속 안정화 기작은 일부 보고된 바 있으나 장기적 안정성과 현장 적용성을 평가한 연구는 여전히 부족한 실정이다. 본 연구에서는 여러 가지 폐자원을 활용한 선행 연구들에서 제시된 토양 중금속 안정화 관련 내용을 요약하였다.

산업부산물을 활용한 지반고화재의 환경안정성 평가 (The Assessment for Environmental Stabilization of Ground Solidification Materials using Industrial y-product)

  • 이영원;문경주
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.116-117
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    • 2014
  • This study is to environmental safety assessment of ground solidification materials using industrial by-products. also, physical and chemical properties were investigated. as a result, compared to conventional cement the survival rates are capable, was judged to be possible utilizing of ECO-friendly ground solidification materials.

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Stabilization of pressure solutions in four-node quadrilateral elements

  • Lee, Sang-Ho;Kim, Sang-Hyo
    • Structural Engineering and Mechanics
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    • 제6권6호
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    • pp.711-725
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    • 1998
  • Mixed finite element formulations for incompressible materials show pressure oscillations or pressure modes in four-node quadrilateral elements. The criterion for the stability in the pressure solution is the so-called Babu$\check{s}$ka-Brezzi stability condition, and the four-node elements based on mixed variational principles do not appear to satisfy this condition. In this study, a pressure continuity residual based on the pressure discontinuity at element edges proposed by Hughes and Franca is used to study the stabilization of pressure solutions in bilinear displacement-constant pressure four-node quadrilateral elements. Also, a solid mechanics problem is presented by which the stability of mixed elements can be studied. It is shown that the pressure solutions, although stable, are shown to exhibit sensitivity to the stabilization parameters.

동(Cu) 및 동합금(Bronze)의 부식생성물과 탈염처리 (Corrosion Products and Desalting Treatments of Copper and Copper Alloy (Bronze))

  • 김상범;김현철;박형호
    • 한국재료학회지
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    • 제20권2호
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    • pp.82-89
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    • 2010
  • Benzotriazole (B.T.A) which has been mainly used for the stabilization processing method of excavated copper and bronze artifacts is vaporized within 2~3 years after the usage because it is unstable at the acid conditions and cannot protect the surface of artifacts. In this study, NaOH method which has been used for the steel artifacts was applied as a stabilization process for the method of copper and bronze artifacts to gush chlorine ion out. For the reproduction of excavated samples, copper and bronze plates were dipped in 0.1M HCl for 26 hrs to form CuCl, rusted at $70^{\circ}C$ with RH 75% for the formation of corrosion products, and desalted in 0.1 M NaOH solution. The concentration of chlorine ion was measured by using ionchromatography. During the desalting process, a large quantity of chlorine ions was gushed out in early period and corrosion products were not additionally generated through the re-corrosion experiment. This NaOH desalting process was found to be a method of stabilization process for copper and bronze artifacts from the formation of Tenorite (CuO) during desalting as a protection layer for corrosion.

PAN 전구체 섬유의 안정화시 전자선 전류의 영향 (Effect of Electron Beam Currents on Stabilization of Polyacrlonitrile Precursor Fiber)

  • 신혜경;전준표;김현빈;강필현
    • 방사선산업학회지
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    • 제5권1호
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    • pp.41-46
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    • 2011
  • Polyacrylonitrile (PAN) fibers are the most widely used precursor of the materials for carbon fibers. The conventional process of carbon fibers from PAN precursor fiber includes two step; stabilization at low temperature and carbonization at high temperature. Compared to thermal stabilization, the stabilization process by electron beam (E-beam) irradiation is a advanced and brief method. However, a stabilization by E-beam irradiation was required a high dose (over 5,000 kGy) and spend over 1.5 hr (1.14 MeV, 1 mA). In the present work the main goal is exploring a quick stabilization process by cotrolling E-beam currents. The effect of various E-beam currents on stabilization of PAN precursor fiber was studied by gel fraction test, thermo gravimertic analysis (TGA), differential scanning calorimetry (DSC), tensile strength, and scanning electron microscopy (SEM) images.

The Development of High Oxygen Pressures and the Stabilization of Unusual Oxidation States of Transition Metals

  • Gerard DEMAZEAU
    • 대한화학회지
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    • 제42권1호
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    • pp.135-140
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    • 1998
  • High oxygen pressures appear an important tool in Solid State Chemistry. Two main routes can be developed: (i) the stabilization of thermally unstable oxides, used as precursors, in order to open the synthesis of new materials, (ii) the stabilization of the highest oxidation states of transition metals. This paper is essentially devoted to this second research axis. The methodology developed for preparing new oxides containing Fe(Ⅴ), Ir(Ⅵ), high spin Fe(Ⅳ) and Cu(Ⅲ) is described.

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