• 제목/요약/키워드: Stability of dispersion

검색결과 521건 처리시간 0.035초

난류특성을 이용한 대기오염확산모델의 예측능에 관한 연구 (A Study on the Predictability of the Air Pollution Dispersion Model Composed of the Turbulent Parameters)

  • 박기학;윤순창
    • 환경영향평가
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    • 제10권2호
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    • pp.123-133
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    • 2001
  • Gaussian dispersion model is the most widely used tool for the ground level air pollution simulation. Though in spite of the convenience there are important problems on the Pasquill- Gifford' stability classification scheme which was used to define the turbulent state of the atmosphere or to describe the dispersion capabilities of the atmosphere which was each covers a broad range of stability conditions, and that they were very site specific, and the vertical dispersion calculation formula on the case of the unstable atmospheric condition. This paper was carried out to revise the Gaussian dispension model for the purposed of increase the modeling performance and propose the revised model, which was composed of the turbulent characteristics in the unstable atmospheric conditions. The proposed models in this study were composed of the profile method, Monin-Obukhove length, the probability density function model and the lateral dispersion function which was composed of the turbulent parameters, $u_*$(friction velocity), $w_*$(convective velocity scale), $T_L$(lagrangian time scale) for the model specific. There were very good performance results compare with the tracer experiment result on the case of the short distance (<1415m) from the source, but increase the simulation error(%) to stand off the source in the all models. In conclusion, the revised Gaussian dispersion model using the turbulent characteristics may be a good contribution for the development of the air pollution simulation model.

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수계분산매체에서 나노 $CeO_2$ 입자의 계면전위 거동 (Surface Potential Behavior of Nano $CeO_2$ Particles in Aqueous Media)

  • 이태원;백운규;최성철;이상훈;임형섭;김철진
    • 한국세라믹학회지
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    • 제37권7호
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    • pp.721-725
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    • 2000
  • In this study, the dispersion stability of nano-sized CeO2 particles, synthesized by hydrothermal method in aqueous was evaluated from observing the surface potential behavior of CeO2 particle synthesized by solid state reaction. The isoelectric point(IEP) of nano-sized CeO2 synthesized by hydrothermal synthesis was found to be pH 9 contrary to the isoelectric point of micro-sized CeO2 synthesized by solid state reaction at pH 6.7. IEP was shifted to pH 2.0 as the addition of D-3019 from 0.1 to 1.0 wt%. The surface potential of CeO2 particles synthesized by hydrothermal synthesis was reduced as the addition of B-1001 used as a binder without change of IEP because the absorption of B-1001 polymer on the CeO2 particles shifted the shear plane of CeO2 particles outward away from the surface. This surface potential behavior was well correlated with the dispersion stability of slurry.

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Biopharmaceutical Evaluation of a Solid Dispersion System Containing Sibutramine Freebase

  • Lee, Min-Suk;Chang, Hee-Chul;Kim, Taewan;Park, Jung-Hwa;Lee, Bong-Sang;Kim, Sung-Hee;Kim, Do-Hwan;Kim, Bo-Gyun;Oh, Seong-Tae;Kang, Myung-Joo;Park, Jong-Hyeok;Lee, Jaehwi;Choi, Young-Wook
    • Bulletin of the Korean Chemical Society
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    • 제29권4호
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    • pp.749-754
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    • 2008
  • To increase the solubility of sibutramine freebase, the solid dispersion was prepared using a fluid-bed granulator. The solid dispersion containing sibutramine freebase was characterized by differential scanning calorimetry (DSC) and powder X-ray diffraction (XRD). After filling the sibutramine solid dispersion in the gelatin hard capsule, we performed in vitro dissolution test, the stability test under accelerated conditions and pharmacokinetic study in beagle dogs. The DSC and XRD data showed that sibutramine solid dispersion would be amorphous state. The dissolution rate of sibutramine solid dispersion was significantly increased about 70% than sibutramine freebase. The stability of sibutramine solid dispersion capsules was equivalent or above to commercial product of sibutramine. In beagle dogs, the sibutramine solid dispersion showed equivalent pharmacokinetic behavior with commercial product of sibutramine hydrochloride. In conclusion, the solid dispersion system provided a possible way to overcome the low solubility of sibutramine freebase, and the sibutramine solid dispersion can be a bioequivalent with the commercial product in humans.

입력변수의 조건에 따른 대기확산모델의 민감도 분석 (Sensitivity Analysis of the Atmospheric Dispersion Modeling through the Condition of Input Variable)

  • 정진도;김장우;김정태
    • 한국환경과학회지
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    • 제14권9호
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    • pp.851-860
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    • 2005
  • In order to how well predict ISCST3(lndustrial Source Complex Short Term version 3) model dispersion of air pollutant at point source, sensitivity was analysed necessary parameters change. ISCST3 model is Gaussian plume model. Model calculation was performed with change of the wind speed, atmospheric stability and mixing height while the wind direction and ambient temperature are fixed. Fixed factors are wind direction as the south wind(l80") and temperature as 298 K(25 "C). Model's sensitivity is analyzed as wind speed, atmospheric stability and mixing height change. Data of stack are input by inner diameter of 2m, stack height of 30m, emission temperature of 40 "C, outlet velocity of 10m/s. On the whole, main factor which affects in atmospheric dispersion is wind speed and atmospheric stability at ISCST3 model. However it is effect of atmospheric stability rather than effect of distance downwind. Factor that exert big influence in determining point of maximum concentration is wind speed. Meanwhile, influence of mixing height is a little or almost not.

한우 및 젖소농장 발생 악취의 확산특성 연구 (A Study on Dispersion Characteristics of Odor from Hanwoo and Dairy Farms)

  • 김두환;하덕민;이재영;김희호;송준익
    • 한국축산시설환경학회지
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    • 제21권1호
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    • pp.1-8
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    • 2015
  • This study was conducted to investigate the dispersion prediction of odor from Hanwoo and dairy farms. Gaussian Plume model used in considering of farm size, wind velocity, atmospheric stability and threshold odor unit to prediction of odor dispersion based on the survey on current state of odor emission and control from 9 site of Hanwoo and 9 site of dairy farms. Farm size, wind velocity and atmospheric stability were affected the distance of odor dispersion, showed longer distance in cases of large farm, low wind velocity and stable atmospheric condition. We will suggestion the adjusted distance of odor dispersion according to farm size was estimated to 50~100 m in Hanwoo farm and 50~150 m in dairy farm when apply the 3OU, 5 m/s wind velocity and stable atmospheric condition.

양돈장 발생 악취의 확산특성 연구 (A Study on Dispersion Characteristics of Odor from Swine Farms)

  • 김두환;하덕민;이인복;최동윤;송준익
    • 한국축산시설환경학회지
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    • 제20권2호
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    • pp.41-48
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    • 2014
  • This study was conducted to investigate the dispersion prediction of odor from swine farms in Korea. Gaussian Plume model used in considering of farm size, wind velocity, atmospheric stability and threshold odor unit to prediction of odor dispersion based on the survey on current state of odor emission and control from 48 site of swine farms. Farm size, wind velocity and atmospheric stability were affected the distance of odor dispersion, showed longer distance in cases of large farm, low wind velocity and stable atmospheric condition. We will suggestion the adjusted distance of odor dispersion according to farm size was estimated to 180 m in small farm and 320 m in large farm when apply the 3 OU, 5 m/s wind velocity and stable atmospheric condition.

APSM의 예측능 평가에 관한 연구 (A study on the Assessment of the Predictability of the APSM)

  • 박기하;윤순창
    • 한국환경과학회지
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    • 제12권3호
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    • pp.265-274
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    • 2003
  • The Pasquill-Gifford stability category is a very important scheme of the Gaussian type dispersion model defined the complex turbulence state of the atmosphere by A grade(very unstable) to F grade(very stable). But there has been made a point out that this stability category might decrease the predictability of the model because it was each covers a broad range of stability conditions, and that they were very site specific. The APSM (Air Pollution Simulation Model) was composed of the turbulent parameters, i.e. friction velocity(${\mu}$$\_$*/), convective velocity scale($\omega$$\_$*/) and Monin-Obukhov length scale(L) for the purpose of the performance increasing on the case of the unstable atmospheric conditions. And the PDF (Probability Density Function)model was used to express the vertical dispersion characteristics and the profile method was used to calculate the turbulent characteristics. And the performance assessment was validated between APSM and EPA regulatory models(TEM, ISCST), tracer experiment results. There were very good performance results simulated by APSM than that of TEM, ISCST in the short distance (<1415 m) from the source, but increase the simulation error(%) to stand off the source in others. And there were differences in comparison with the lateral dispersion coefficient($\sigma$$\_$y/) which was represent the horizontal dispersion characteristics of a air pollutant in the atmosphere. So the different calculation method of $\sigma$$\_$y/ which was extrapolated from a different tracer experiment data might decrease the simulation performance capability. In conclusion, the air pollution simulation model showed a good capability of predict the air pollution which was composed of the turbulent parameters compared with the results of TEM and ISCST for the unstable atmospheric conditions.

계면활성제 용액네에서 고형오구의 직물에서의 부착에 영향을 주는 전해질 효과-$\alpha$-$Fe_2O_3$입자의 PET 섬유직물에의 부착- (Effect of Electrolyte on the Adhesion of Particulate Soil to Fabric in the Surfactant Solution-Adhesion of -$\alpha$-$Fe_2O_3$Particles to PET Fabric-)

  • 강인숙;김병주
    • 한국의류학회지
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    • 제25권8호
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    • pp.1465-1474
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    • 2001
  • The dispersion stability of particles and the adsorption of surfactant were examined as a fundamental environment to adhesion of particulate soil to fabric. The adsorption of surfactant on the PEF fabrics decreased with the addition of electrolytes and decreased with increasing the ionic strengths showed similar tendency to PET fabric. And the dispersion force of $\alpha$-Fe$_2$O$_3$particles decreased with the addition of electrolyte. The adhesion of particulate soil to fabric, increased with decreasing the adsorption of surfactant the correlation between the two was high at low ionic strength. The correlation between the adsorption of surfactants on $\alpha$-Fe$_2$O$_3$ particles and the adhesion of particles to fabric was smaller as shown in the correlation between the adsorption of surfactants on fiber substrate and the adhesion of particles on fabric. However, the correlation between the adhesion of particles to fabric and the stability of particle dispersion was relatively more significant.

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Dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium

  • Chun, M.P.;Chung, Y.B.;Ma, Y.J.;Cho, J.H.;Kim, B.I.
    • 한국결정성장학회지
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    • 제15권6호
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    • pp.239-243
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    • 2005
  • The effect of pH and particle size on the dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium have been investigated by means of zeta potential, sediment experiments, and powder properties (particle analysis, specific surface area) etc. Zeta potential as a function of pH for two particles of different size increases from -75 to +10 mV with decreasing pH from 8.5 to 1.4. The curve of zeta potential for small particle (150 nm) has slow slope than that of large particle (900nm), giving IEP (isoelectric point) value of pH=1.6 for small particle and pH=1.9 for large particle respectively, which means that it is more difficult to control zeta potential with pH fur small particle than large particle. The dispersion stability of $BaTiO_3$ particles in aqueous medium was found to be strongly related with the agglomeration of colloidal suspensions with time through the sedimentation behaviors of colloidal particles with time and pH value.

수열합성법으로 합성된 나노 SmxCe1-xO2-2/x 분말의 수계 분산 (Dispersion of SmxCe1-xO2-2/x Nanoparticles which is Synthesized by Hydrothermal Process in Aqueous System)

  • 배동식;김은정;한경섭
    • 한국재료학회지
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    • 제15권2호
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    • pp.112-114
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    • 2005
  • Dispersion stability of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles, which was produced by hydrothermal process, was studied in aqueous suspension using ESA (Eletrokinetic Sonic Amplitude). The average particle size of the synthesized $Sm_xCe_{1-x}O_{2-2/x}$ at nanoparticles was about $5{\pm}2nm$. The dispersion and rheological behavior of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles aqueous suspension was investigated using $NH_4OH\;and\;HNO_3$ as a disperse agent. The colloidal stability of aqueous suspensions with $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles at different pH values has been investigated by means of zeta potential, average particle size, and the distribution of synthesized $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles. The isoelectric point of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles was at pH around 11 and the value of zeta potential was at its maximum near pH 6.5.