• 제목/요약/키워드: Stability of dispersion

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입자의 분산안정성이 고형오구의 세척성에 미치는 영향(제1보) - Nonyl Phenol Polyoxyethylene Ether 용액 내에서 α-Fe2O3 입자의 분산안정성 - (Effect of Dispersion Stability of Particles on Detergency of Particulate Soil(Part 1) - The Dispersion Stability of α-Fe2O3 Particles in the Nonyl Phenol Polyoxyethylene Ether Solution -)

  • 강인숙
    • 한국의류산업학회지
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    • 제4권1호
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    • pp.86-91
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    • 2002
  • To estimate dispersion stability of particles, suspending power and particle size were examined as functions of pHs, surfactants, electrolytes and ionic strengths using ${\alpha}-Fe_2O_3$ particle as the model of particulate soil. Suspending power and particle size were determined by UV-Vis spectrumeter and by light scattering using the polarization ratio method, respectively. The suspending power was relatively high with polyanion electrolytes and was low with neutral salts. The suspending power was biphasis, minimum pH 6~7, and the effect of surfactant on the suspending power was insignificant. Generally suspending power increased with decreasing the particle size governed aggregation of dispersed particles regardless of solution conditions. Hence the suspending power was inversely related to the particle size.

Novel 2D FDTD Scheme with Isotropic Dispersion Characteristics

  • Koh, Il-Seuk;Kim, Hyun;Yook, Jong-Gwan
    • 한국전자파학회:학술대회논문집
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    • 한국전자파학회 2005년도 종합학술발표회 논문집 Vol.15 No.1
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    • pp.183-186
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    • 2005
  • A two dimensional (2-D) finite-difference time-domain (FDTD) method based on a novel finite difference scheme is developed to eliminate the numerical dispersion errors. In this paper, numerical dispersion and stability analysis of the new scheme are given, which show that the proposed method is nearly dispersionless, and stable for a larger time step than the standard FDTD method.

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고/액간 계면에 있어서 분산의 안정성에 관한 이론적 고찰 (The Theoretical Investigation on the Stability of Solid/Liquid Dispersion)

  • 김태영;조경행;남기대
    • 한국응용과학기술학회지
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    • 제12권1호
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    • pp.1-11
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    • 1995
  • In this outline, the stability of solid/liquid dispersion was theoretically investigated the matter from all angles by using the modified DLVO theory. The stability was handled various considerations such as a production and characteristics of electrical double layer, total interaction$(V_T)$ that consisting of attractive force$(V_A)$ and repulsion$(V_R)$. coagulation, the stability ratio(W), critical flocculation concentration (cfc) and zeta potential$(\zeta)$ etc. It was possible for us to examine with the stability ratio(W), critical flocculation concentration (cfc) and zeta potential$(\zeta)$ that may estimation of stability of solid/liquid dispersion experimentally.

손실 매질에 대한 2차원 등방 시간 영역 유한 차분법 (Two Dimensional Explicit ID(Isotropic-Dispersion)-FDTD Scheme for Lossy Media)

  • 고일석;김현;육종관
    • 한국전자파학회논문지
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    • 제18권6호
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    • pp.664-673
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    • 2007
  • 본 논문에서는 참고문헌 [1], [2]에서 무손실 매질을 가정하고 보고하였던 ID-FDTD 기법을, 손실 매질로 확장시켜 정리하였다. 확장된 내용으로는 기법의 안정도 분석(stability analysis), 손실 매질에 대한 ID-FDTD 기법의 분산 관계(dispersion relation), 무손실 손실 매질 모두에 적용할 수 있는 보정치를 수식 등 크게 세 가지이다. 이러한 분석 결과 ID-FDTD 기법은 참고문헌 [3]의 standard 기법보다 큰 시간 증분에서도 안정성을 유지하면서도 적은 분산 오차(dispersion error)를 가지는 것을 확인할 수 있었다. 이는 두 가지 경우의 전자기파 산란 문제를 계산함으로써 검증하였다.

CaCO3 안료의 분산 안정성에 대한 용제의 영향 (Effect of Solvent on the Dispersion Stability of CaCO3 Pigment)

  • 이근대;류영철;서차수;홍성수;안병현;문명준
    • 공업화학
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    • 제8권2호
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    • pp.252-261
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    • 1997
  • 여러 종류의 용제와 수지용액에 있어서의 $CaCO_3$ 안료의 분산 안정성을 Dynometer를 이용하여 조사하였다. Dynometer를 이용하여 비교적 단시간에 분산계의 분산 안정성을 평가할 수 있었으며, Dynometer를 이용한 분산 안정성 평가로부터 구한 $CaCO_3$ 안료의 용해성 파라미터, ${\delta}$는 11.62(${\delta}_d=8.04$, ${\delta}_p=5.05$, ${\delta}_h=6.70$)이었다. 안료와 친화력이 약한 용제가 첨가되는 경우 수지 용액내에서의 안료표면에의 수지 흡착층을 증가시켜 수지 용액내에서의 분산 안정성을 증가시켰다. 수지 용액 제조시 소량 첨가된 용제도 안료를 포함한 전체 분산계의 유동성과 분산 안정성에 큰 영향을 미친다는 것을 알 수 있었다.

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생체분자 분리를 위한 Fe3O4 나노입자의 표면수식과 분산 안정성 향상 (Functionalization of Fe3O4 Nanoparticles and Improvement of Dispersion Stability for Seperation of Biomolecules)

  • 김민정;안국환;임보라미;김희택;좌용호
    • 한국분말재료학회지
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    • 제14권4호
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    • pp.256-260
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    • 2007
  • The surface of magnetite ($Fe_{3}O_{4}$) nanoparticles prepared by coprecipitation method was modified by carboxylic acid group of poly(3-thiophenacetic acid (3TA)) and meso-2,3-dimercaptosuccinic acid (DMSA). Then the lysozyme protein was immobilized on the carboxylic acid group of the modification of the magnetite nanoparticles. The magnetite nanoparticles are spherical and the particle size is approximately 10 nm. We measured quantitative dispersion state by dispersion stability analyzer for each $Fe_{3}O_{4}$ nanoparticles with and without surface modification. The concentration of lysozyme on the modified magnetite nanoparticles was also investigated by a UV-Vis spectrometer and compared to that of magnetite nanoparticles without surface modification. The functionalized magnetite particles had higher enzymatic capacity and dispersion stability than non-functionalized magnetite nanoparticles.

PAC-PAE 2중 고분자 내첨 지료의 고분자 흡착 및 교질 분산계의 안정성 연구 (Polymer Adsorption and fiber Dispersion Stability of a Paper Stock Colloidal Suspension with a PAC-PAE Dual Polymer System)

  • 윤성훈;김태영;김덕기;송병규
    • 펄프종이기술
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    • 제35권2호
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    • pp.18-25
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    • 2003
  • The adsorption of co-cationic dual polymer system was investigated as was the fiber dispersion stability of a paper stock suspension. Polyaluminum chloride(PAC) and polyamidoamine epichlorohy-drin(PAE) polymers were used as wet-end additives. The adsorbed amounts of PAE polymer in a wet stock were measured by using polyelectrolytic PCD titration. The sheet forming experiments were carried out in a standard handsheet machine. Fiber dispersion stability and relative retention were evaluated in terms of M/K non-uniformity index and sheet basis weight, respectively. The PAE polymer adsorption of Langmuir-isothermal type decreased with increasing PAC addition level. The combination of the two cationic polymers presumably exerts a site-blocking effect by the low molecular weight PAC which gives a partial charge neutralization at a minimum level of addition. From a thermodynamic view point of PAE adsorption, an increase in adsorption entropy and a decrease in train number suggests that the PAR polymer has an extended conformation structure that potentially leads to an enhancement of the fiber dispersion stability. This conclusion is supported by handsheet experiments that examined the PAC-PAE dual polymer effects on the sheet formation and retention.

A Simple Mlodel for Dispersion in the Stable Boundary Layer

  • Sung-Dae Kang;Fuj
    • 한국환경과학회지
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    • 제1권1호
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    • pp.35-43
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    • 1992
  • Handling the emergency problems such as Chemobyl accident require real time prediction of pollutants dispersion. One-point real time sounding at pollutant source and simple model including turbulent-radiation process are very important to predict dispersion at real time. The stability categories obtained by one-dimensional numerical model (including PBL dynamics and radiative process) are good agreement with observational data (Golder, 1972). Therefore, the meteorological parameters (thermal, moisture and momentum fluxes; sensible and latent heat; Monin-Obukhov length and bulk Richardson number; vertical diffusion coefficient and TKE; mixing height) calculated by this model will be useful to understand the structure of stable boundary layer and to handling the emergency problems such as dangerous gasses accident. Especially, this simple model has strong merit for practical dispersion models which require turbulence process but does not takes long time to real predictions. According to the results of this model, the urban area has stronger vertical dispersion and weaker horizontal dispersion than rural area during daytime in summer season. The maximum stability class of urban area and rural area are "A" and "B" at 14 LST, respectively. After 20 LST, both urban and rural area have weak vertical dispersion, but they have strong horizontal dispersion. Generally, the urban area have larger radius of horizontal dispersion than rural area. Considering the resolution and time consuming problems of three dimensional grid model, one-dimensional model with one-point real sounding have strong merit for practical dispersion model.al dispersion model.

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The Annual Averaged Atmospheric Dispersion Factor and Deposition Factor According to Methods of Atmospheric Stability Classification

  • Jeong, Hae Sun;Jeong, Hyo Joon;Kim, Eun Han;Han, Moon Hee;Hwang, Won Tae
    • Journal of Radiation Protection and Research
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    • 제41권3호
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    • pp.260-267
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    • 2016
  • Background: This study analyzes the differences in the annual averaged atmospheric dispersion factor and ground deposition factor produced using two classification methods of atmospheric stability, which are based on a vertical temperature difference and the standard deviation of horizontal wind direction fluctuation. Materials and Methods: Daedeok and Wolsong nuclear sites were chosen for an assessment, and the meteorological data at 10 m were applied to the evaluation of atmospheric stability. The XOQDOQ software program was used to calculate atmospheric dispersion factors and ground deposition factors. The calculated distances were chosen at 400 m, 800 m, 1,200 m, 1,600 m, 2,400 m, and 3,200 m away from the radioactive material release points. Results and Discussion: All of the atmospheric dispersion factors generated using the atmospheric stability based on the vertical temperature difference were shown to be higher than those from the standard deviation of horizontal wind direction fluctuation. On the other hand, the ground deposition factors were shown to be same regardless of the classification method, as they were based on the graph obtained from empirical data presented in the Nuclear Regulatory Commission's Regulatory Guide 1.111, which is unrelated to the atmospheric stability for the ground level release. Conclusion: These results are based on the meteorological data collected over the course of one year at the specified sites; however, the classification method of atmospheric stability using the vertical temperature difference is expected to be more conservative.

Impact of boundary layer simulation on predicting radioactive pollutant dispersion: A case study for HANARO research reactor using the WRF-MMIF-CALPUFF modeling system

  • Lim, Kyo-Sun Sunny;Lim, Jong-Myung;Lee, Jiwoo;Shin, Hyeyum Hailey
    • Nuclear Engineering and Technology
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    • 제53권1호
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    • pp.244-252
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    • 2021
  • Wind plays an important role in cases of unexpected radioactive pollutant dispersion, deciding distribution and concentration of the leaked substance. The accurate prediction of wind has been challenging in numerical weather prediction models, especially near the surface because of the complex interaction between turbulent flow and topographic effect. In this study, we investigated the characteristics of atmospheric dispersion of radioactive material (i.e. 137Cs) according to the simulated boundary layer around the HANARO research nuclear reactor in Korea using the Weather Research and Forecasting (WRF)-Mesoscale Model Interface (MMIF)-California Puff (CALPUFF) model system. We examined the impacts of orographic drag on wind field, stability calculation methods, and planetary boundary layer parameterizations on the dispersion of radioactive material under a radioactive leaking scenario. We found that inclusion of the orographic drag effect in the WRF model improved the wind prediction most significantly over the complex terrain area, leading the model system to estimate the radioactive concentration near the reactor more conservatively. We also emphasized the importance of the stability calculation method and employing the skillful boundary layer parameterization to ensure more accurate low atmospheric conditions, in order to simulate more feasible spatial distribution of the radioactive dispersion in leaking scenarios.