• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.304-309
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• 1999

Aluminum-pillared clay was prepared by the intercalation of Al-hydroxy oligomer into domestic bentonite. The solid products are characterized by XRD, nitrogen adsorption/desorption, EDX, and SEM. The solid products show relatively high specific surface areas in the range of $104{\sim}228m^2/g$, and their specific surface area, micropore surface area, and micropore volume increase with increasing the mole ratio of OH/Al. From the results of pore size distribution calculated by BJH equation, it was found that aluminum-pillared clay also contains much mesopore near $40{\AA}$. These results indicate that Al-hydroxy oligomer was intercalated into bentonite, and aluminum oxide was pillared among the layers of bentonite, and micropore and mesopore was finally developed into layers. As OH/Al mole ratio increases, the thermal stability of aluminum-pillared clay increases. This result can be explained by the fact that the density of layers is increased due to the formation of aluminum pillars.

• Korean Journal of Environment and Ecology
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• v.7 no.2
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• pp.118-134
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• 1994

This study was conducted to investigated the plant community structure and to revaluate the part of plant ecosystem on statement of environmental impact assessment in Muju resort golf course, Solch'on area, Tokyusan National Park. The actual vegetation was comprised of Pinus densiflora-Quercus mongolica-Q. serrata community(33.21%), Q. spp. community(27.30%), P. densiflora community(20.68%) and high mountain marsh(4.93%) etc., which communities were the major vegetation and the forest vegetation was came to being a peculiar to environmental condition. The degree of green naturality 8, 9 was covered 93% in survey area, and so this result reflect the stability of ecosystem. There was all the difference between the statement of environmental impact assessment of development concerned and this study result in the estimation of degree of green naturality. The plant community were divided into six groups in fifty-four plots by DCA and the dividing groups were P. densiflora, P. densiflora-Q. mongolica, P. densiflora-Q. serrata-F. mandschurica-B. davurica, Q. mongolica-Q. serrata-P. densiflora, Q. mongolica-Q. variabilis, Salix koreansis- B. davurica community. Except P. densiflora forest in survey site, the ecological succession trend of the other communities was seemed to be from P. densiflora to Q. spp.

• Journal of the Korean Vacuum Society
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• v.20 no.2
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• pp.155-163
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• 2011

Carbon nanotubes (CNT) have been attracted much attention since they have been expected to be used in various areas by virtue of their outstanding physical, electrical, and chemical properties. In order to make full use of their prominent electric conductivity in some areas such as electron emission sources, device interconnects, and electrodes in energy storage devices, direct growth of CNT with vertical alignment is definitely beneficial issue because they can maintain mechanical stability and high conductivity at the interface between substrates. Here, we report direct growth of vertically aligned CNT (VCNT) on Cu foils using thermal chemical vapor deposition and characterize the field emission property of the VCNT. The VCNT's height was controlled by changing the growth temperature, growth time, and catalytic layer thickness. Optimum growth condition was found to be $800^{\circ}C$ for 20 min with acetylene and hydrogen mixtures on Fe catalytic layer of 1 nm thick. The diameter of VCNT grown was smaller than that of usual multi walled CNT. Based on the result of field emission characterization, we concluded that the VCNT on Cu foils can be useful in various potential applications where high conductivity through the interface between CNT and substrate is required.

• Economic and Environmental Geology
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• v.36 no.5
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• pp.365-374
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• 2003

Various deleterious chemicals can be introduced to existing concrete structures from various external sources. The deterioration of concrete by seawater attack is involved in complex processes due to various elements contained in seawater. In the present study, attention was paid to the formation of secondary minerals and characteristics of mineralogical and micro-structural changes involved in concrete deterioration caused by the influence of major seawater composition. The characteristics of deterioration occurred in existing concrete structures was carefully observed and samples were collected at many locations of coastal areas in Busan-Kyungnam. The petrographic, XRD, SEM/EDAX analyses were conducted to determine chemical, mineralogical and micro-structural changes in the aggregate and cement paste of samples. The experimental concrete deteriorations were performed using various chloride solutions (NaCl, CaCl, $MgCl_2$ and $Na_2SO_4$ solution. The experimental results were compared with the observation results in order to determine the effect of major elements in seawater on the deterioration. The alkalies in seawater appear to accelerate alkali-silica reaction (ASR). The gel formed by ASR is alkali-calcium-silica gel which known to cause severe expansion and cracking in concrete. Carbonation causes the formation of abundant less-cementitious calcite and weaken the cement paste. Progressive carbonation significantly affects on the composition and stability of some secondary minerals. Abundant gypsum generally occurs in concretes subjected to significant carbonation, but thaumasite ({$Ca_6/[Si(OH)_6]_2{\cdot}24H_2O$}${\cdot}[(SO_4)_2]{\cdot}[(CO_3))2]$) occurs as ettringite-thaumasite solid solution in concretes subjected to less significant carbonation. Experimentally, ettringite can be transformed to trichloroaluminate or decomposed by chloride ingress under controlled pH conditions. Mg ions in seawater cause cement paste deterioration by forming non-cementitious brucite and magnesium silicate hydrate (MSH).

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.593-599
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• 2017

In order to enhance ultra battery performances, the electrochemical characteristics of nano Pb/AC anode composite was investigated. Through nano Pb adsorption onto activated carbon, nano Pb/AC was synthesized and it was washed under vacuum process. The prepared anode materials was analysed by SEM, BET and EDS. The specific surface area and average pore size of nano Pb/AC composite were $1740m^2/g$ and 1.95 nm, respectively. The negative electrode of ultra battery was prepared by nano Pb/AC dip coating on lead plate. The electrochemical performances of ultra battery were studied using $PbO_2$ (the positive electrode) and prepared nano Pb/AC composite (the negative electrode) pair. Also the electrochemical behaviors of ultra battery were investigated by charge/discharge, cyclic voltammetry, impedance and rate capability tests in 5 M $H_2SO_4$ electrolyte. The initial capacity and cycling performance of the present nano Pb/AC ultra battery were improved with respect to the lead battery and the AC-coated lead battery. These experimental results indicate that the proper addition of nano Pb/AC into the negative electrode can improve the discharge capacity and the long term cycle stability and remarkably suppress the hydrogen evolution reaction on the negative electrode.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.21 no.1
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• pp.42-51
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• 2007

An AC electrical railroad system has rapidly changing dynamic single-phase load, and at a feeding substation, three-phase electric power is transformed to the paired directional single-phase electric power. There is a great difference in electrical phenomenon between the load of AC electrical railroad system and that of general power system. Electric characteristics of AC electrical railroad's trainload are changed continuously according to the traction, operating characteristic, operating schedule, track slope, etc. Because of the long feeding distance of the dynamic trainload, power quality problems such as voltage drop, voltage imbalance and harmonic distortion my also occur to AC electrical railroad system. These problems affect not only power system stability, but also power quality deterioration in AC electrical railroad system. The dynamic simulation model of AC electrical railroad system presented by PSCAD/EMTDC is modeled in this paper, andthen, it is analyzed voltage drop for AC electrical railroad system both with single-phase distributed STATCOM(Static Synchronous Compensator) installed at SP(Sectioning Post) and without.

• Spatial Information Research
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• v.22 no.4
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• pp.77-87
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• 2014

Recently there are many disasters caused by volcanic activities such as the eruptions in Tungurahua, Ecuador(2014) and $Eyjafjallaj\ddot{o}kull$, Iceland(2010). Therefore, it is required to prepare countermeasures for the disasters. This study analyzes the Baekdu Mountain area, where is the risky area because it is active volcano, based on the observed data and scientific methods in order to assess a risk, produce a hazard map and analyze a degree of risk caused by the volcano. Firstly, it is reviewed for the research about the Baekdu mountain volcanic eruption in 1215(${\pm}15$ years) done by Liu Ruoxin. And the factors causing volcanic disaster, environmental effects, and vulnerability of Baekdu Mountain are assessed by the dataset, which includes the earthquake monitoring data, the volcanic deformation monitoring data, the volcanic fluid geochemical monitoring data, and the socio-economic statistics data. A hazard, especially caused by a volcano, distribution map for the Baekdu Mountain Area is produced by using the assessment results, and the map is used to establish the disaster risk index system which has the four phases. The first and second phases are very high risky area when the Baekdu Mountain erupts, and the third and fourth phases are less dangerous area. The map shows that the center of mountain has the first phase and the farther area from the center has the lower phase. Also, the western of Baekdu Mountain is more vulnerable to get the risk than the eastern when the factors causing volcanic disasters are equally applied. It seems to be caused by the lower stability of the environment and the higher vulnerability.

• KSBB Journal
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• v.17 no.6
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• pp.571-576
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• 2002

Recombinant E. coli DH5 ${\alpha}$/pSB311 was made by cloning the genes encoding bacterial luciferase and aldehyde substrate proteins from Photohabdus luminescense, to complement defects of Lumistox, which is normally used in bioassays to monitor toxic substances in water environmental systems. The conditions for stable light production by the recombinant strains were investigated with respect to cell growth stage, cell number, and buffer conditions. The optimum growth stage was a middle-exponential stage with an OD$_{660nm}$ value of 0.6-0.7. ADout 10$^{6}$-10$^{7}$ cells per test tube was optimum for stable light emission. The effect of buffer was not significant if an optimum viable cell number was maintained. The bioluminescence of the recombinant E. coli harboring the lux operon of Photohabdus luminescense was not affected by temperature, while the bioluminescence of Lumistox was temperature sensitive. The recombinant E. coli was more sensitive to heavy metals (Cd, Cu, Hg, Zn) than Lumistox, because it does not require high concentrations of NaCl in the buffer.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.817-820
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• 2008

The river environments of many streams in korea have been deteriorate through the rapid industrialization and urbanization since the 1960s. In korea, on the other hand, much efforts on the research and project have been made for the restoration of the deteriorated streams to close-to-nature. in order to restore the deteriorated streams, therefore, it is necessary to investigate such advanced technologies and materials. In view of this requirement, various research paths are being taken focusing on coarse aggregates to make multi-functional porous concrete having continuous voids so as to improve water and air permeability, acoustic absorption, water purification and applicability to vegetation. The Purpose of this study is to investigate the method for recovery of the environment in the streams area using porous concrete retaining wall block. the multi-P.O.C block applies for test in the Jangduri-cheon have been monitored planting, stability etc. after 6 months, plant grows flourishing and reconstructed in state such as nature rivers.

• Journal of Conservation Science
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• v.29 no.3
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• pp.287-296
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• 2013

Excavated iron objects are preserved in stable condition through processes of conservation treatment because they are found in the form of various corrosion products. However, the conservation treatment leads to re-corrosion over time and accordingly, iron objects can be severely damaged, and therefore fundamental measures need to be prepared to control it. In this study, the types and characteristics of corrosion products were scientifically analyzed according to the re-corrosion of iron artifacts. In addition, the stability of the corrosion products was evaluated by exposing the standard samples under the re-corrosion environment. Re-corrosion proceeded with weeping in reddish brown on the cracks of iron artifacts. Weeping was detected akagan$\acute{e}$ite had a low hydrogen ion concentration and high chloride ion. The selection of standard sample goethite, lepidocrocite, hematite, and magnetite, were evaluated corrosive by weeping. After the samples were immersed in HCl(pH 1), $H_2SO_4$(pH 1), $H_2O$(pH 6) solution, they had been maintained for 180 days in relative humidity of 20%, 50%, 80% to investiage the changes of chemical components. As a result of analysis, the changes of chemical components were not showed in goethite, lepidocrocite, and hematite. But magnetite was changed to lepidocrocite in solution including chloride ion($Cl^-$) and to goethite and lepidocrocite solution including sulfuric acid($SO{_4}^{2-}$). Results of the study, in the case of magnetite known as s stable corrosion compound, it was identified the corrosion of magnetite occurs by corrosive ions, which means weeping generated in the iron artifacts can corrode magnetite as well as base metal.