• Title/Summary/Keyword: Stability Agent

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Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(II). -Application Methods of Chemicals for Improving Water and Moisture Resistance of Corrugated Boards- (농산물 저온유통용 내수 골판지 상자의 제조(제2보) - 골판지의 내수 및 내습성 향상을 위한 약품 적용 방법 -)

  • 조중연;민춘기;신준섭
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.2
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    • pp.60-69
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    • 2004
  • Application methods of chemicals were investigated to minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stein hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stein hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

Study on Genipin: A New Alternative Natural Crosslinking Agent for Fixing Heterograft Tissue

  • Yoo, Jae-Suk;Kim, Yong-Jin;Kim, Soo-Hwan;Choi, Seung-Hwa
    • Journal of Chest Surgery
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    • v.44 no.3
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    • pp.197-207
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    • 2011
  • Background: In cardiac surgery, especially in the reconstruction of vascular structures and intracardiac defects, glutaraldehyde has usually been used as the reagent for fixing porcine or bovine pericardial tissues. But the well-known problem of calcification or cytotoxicity of glutaraldehyde motivates the search for a replacement. The aim of this study is to investigate the physical, mechanical, and biochemical characteristics of bovine pericardial tissues fixed with genipin, which is known to be a less toxic and more natural fixing reagent. Materials and Methods: Bovine pericardial tissues were fixed with different concentrations and conditions of glutaraldehyde and genipin. To determine the physical, mechanical, and biochemical differences among different concentrations and conditions, we divided the tissue into 18 groups by concentration, the addition of organic solvents, and the timing of adding the organic solvents, and compared the characteristics of each group. Results: Tensile strength, physical activity, and thermal stability tests revealed that the tissues fixed with glutaraldehyde were better with regard to mechanical strength and biochemical durability. However, the difference was not significant statistically. Conclusion: Genipin can be used as an alternative crosslinking agent for pericardial tissue, considering given its physical, mechanical, biochemical characteristics and low cytotoxicity comparable to glutaraldehyde. However, further studies are needed on the immune reaction and the long term changes in genipin-fixed tissues in the human body.

The Estrous Cycle and Induction of Ovulation in Mares

  • Yoon, Min-Jung
    • Journal of Animal Science and Technology
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    • v.54 no.3
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    • pp.165-174
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    • 2012
  • For horse breeders or managers, it is critical to understand the estrous cycle of mares. Breeding of mares cannot be successfully achieved throughout the whole year as mares breed seasonally. Mares are only able to breed when day length is more than 16 h, and this period is known as the breeding season. Their estrous cycle is approximately 21 days with 5-7 days of estrus and 14 to 15 days of a diestrus period. The estrous cycle of the mare is mainly controlled by gonadotropins, which control follicular development and ovulation. Mares exhibit unique ovulatory events which are not observed in other species. A LH surge occurs for several days, with levels of LH reaching their peak after ovulation. The LH level at the time of LH peak is lower than most other species. The unique anatomical structure of the ovaries of mares is known to limit the number of eggs ovulated. Several attempts have been made to develop chemical/hormonal agents which might be used to manipulate the timed ovulation of mares. Agents that have been tested include hCG, native GnRH, Deslorelin (Ovuplant, GnRH-agonist), Buserelin (GnRH analogue), equine pituitary extracts and equine chorionic gonadotropin (eCG or PMSG). However, the function, purity or stability of these agents is not reliable. Recombinant equine LH, an alternative agent for the timed ovulation, has been developed and tested for its biological activities, through the use of both in vitro and in vivo experiments. The reLH was suggested to be a reliable agent in inducing ovulation within 48 h after being administered through injection, when the size of dominant follicle is 35 mm in diameter.

Evaluation of Ceramics, Alumina and Silicone Carbide Added Concrete Surface Protecting Agent (세라믹스, 알루미나 및 실리콘 카바이드 혼합물이 첨가된 콘크리트 표면보호재의 성능 평가)

  • Kong, Jin-Hee;Kim, Young-Geun;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.43-46
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    • 2009
  • The purpose of this study is to enhance durability of concrete structures that uses this surface protecting material by carrying out the performance test of the surface protecting material of concrete, and as s result, we reached out the conclusion as follow. 1. As a result of the test measuring the stability and adhesive power of conductive film against ultraviolet, freezing & thawing, and damage from seawater that deteriorate the surface protecting material, it was turned out to meet the performance criteria specifying in the KS standard enough to gain a good evaluation to use as a surface protecting material. 2. As a result of the test identifying the neutralization-furtherance, it was assessed to be capable of protecting effectively concrete structures from carbonic acid gas by a very low depth of 0.1mm of neutralization. 3. As a result of the test identifying Penetrated Resistance Properties of chloride ion, as it was turned out to have a very low value of 819 Coulombs, it was assessed that even in the environment where the corrosion by chloride such sea environment is very affective, the film can effectively protect the concrete structure. 4. As a result of the test identifying freezing & thawing, as there was no change in reduction of mass after 400 cycle, it was assessed that the film has a good resistance against freezing & thawing. According to the results of study above, it is expected that this technology can extend its durability of concrete structure and be widely used for concrete structure through means (methods) to prevent the neutralization and damage from seawater as original purposes of the surface protecting material.

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Microencapsulation of Surface-modified Carbon Black by Miniemulsion Polymerization (미니유화중합법에 의한 표면개질된 카본블랙의 마이크로캡슐화)

  • Jang, Heang Sin;Hong, Jinho;Lee, Jeongwoo;Shim, Sang Eun
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.669-675
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    • 2008
  • Carbon black has been widely used in composites, tonor resin, and ink materials. Since carbon black readily agglomerates, it is important to disperse carbon black in real applications. Aiming to improve dispersion stability, carbon black was chemically oxidized to possess hydroxyl groups using a phase transfer catalyst at room temperature. The modified carbon black (CB-OH) was grafted by a silane coupling agent, p-methylacryloxypropyltrimethoxysilane, to carry teminal vinyl groups. The modified carbon black was subsequently used in miniemulsion polymerization to achieve encapsulted core-shell structure. Finally, well-encapsulated carbon black by polymer was obtained in the size range of 100-500 nm. Throughout the polymerization, the effects of surface modification, types of monomers, initiators, and emulsifiers were investigated.

A Fundamental Test of Temperature Crack Reduction Method Application by Setting Time Control of Large-Scaled Mat Foundation Mass Concrete (초대형 매트기초 매스 콘크리트의 응결시간조정에 의한 온도균열저감 공법적용의 기초적 실험)

  • Han, Cheon-Goo;Lee, Jae-Sam;Noh, Sang-Kyun
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.3
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    • pp.95-101
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    • 2009
  • Constructing large-scale mat foundation mass concrete is increasing for the stability of building structure, because a lot of high rise building are being built in order to make full use of limited space. However, It is of increasing concerns that because limited placing equipments, available job-site and systems for mass concete placement in construction field do not allow to place great quantity of concrete at the same time in large scale mat foundation, consistency between placement lift can not be secured. And also, it is likely to crack due to stress caused by the difference of hydration heat generation time. To find out the solution against above problems, this study is to reconfirm the performance of normal concrete designed by mix proportion and super retarding concrete. The Fundamental test shows what happens if low heat proportioning and control method of setting time are applied at the job-site of newly constructed high rise building. The test result show that slump flow of concrete has been somewhat increased as the target retarding time gets longer, while the air content has been slightly decreased but this is no great difference from normal concrete. The setting time shows to be retarded as target retarding time gets longer, the range of retarding time increases. It is necessary to increase the amount of mix of super retarding agent in the proportion ration by setting curing temperature high since outdoor curing is about 6 hours faster than standard curing, which means the temperature of the concrete will be higher than the temperature of the surrounding environment, due to its high hydration heat when applying in a construction site. The compressive strength of super retarding concrete appears to be lower than normal concrete due to the retarding action in the early stage. However, as the time goes by, the compressive strength gets higher, and by the 28th day the strength becomes the same or higher than normal concrete.

Porosity Control in LSM Electrode Formation in Layered Plannar SOFC Module (적층 평판형 SOFC에서 LSM 전극의 기공 제어)

  • Lee, Won-Jun;Yeo, Dong-Hun;Shin, Hyo-Soon;Jeong, Dea-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.866-870
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    • 2014
  • In solid oxide fuel cell system, yttria-stabilized zirconia is generally adopted as the electrolyte, which has high strength and superior oxygen ion conductivity, and the air electrode and the fuel electrode are attached to this. Recently, new structure of 'layered planar SOFC module' was suggested to solve the reliability problem due to the high temperature stability of a sealing agent and a binding material. In this study to materialize the air electrode in a layered planar SOFC module, the LSM ink was coated to form homogeneous electrode in the channel after the ink preparation. As the porosity control agent, PMMA or active carbon powder was adopted with use of a commercial dispersant in ethanol. The optimal amounts of both the porosity control agents and the dispersant were determined. Four (4) vol% of the dispersant for the LSM-PMMA case and 15 vol% for LSM-carbon powder showed the lowest viscosities respectively to indicate the best dispersed states of the slurries. With PMMA and carbon powder, sintered LSM ink shows the relatively homogeneous distributions of pores and with increases of the agents, the porosities increased in both cases. From this, it can be thought that the amount of the PMMA or carbon powder could be used to control the porosity of the LSM ink.

Comparison of the Physical Properties for Alternative Eire Extinguishing of Pure and Mixture Component of Inert Gases (불활성가스계 단일 성분 및 혼합물 성분의 대체 소화제의 물성 비교)

  • 김재덕;이광진;한순구;이윤우;노경호
    • Fire Science and Engineering
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    • v.18 no.2
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    • pp.12-19
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    • 2004
  • The commercially available IG-541 extinguished agent composed of inert gases was developed for environmental protection. The extinguished agents were considered in terms of physical properties, efficient characteristic, environment, stability, and economical efficiency. The pure and mixture components of physical properties of $N_2$, Ar and $CO_2$ were chosen and compared. The physical properties of density, viscosity and surface tension of inert gases were plotted with the molar ratios of $N_2$/$CO_2$ and Ar/$CO_2$ in terms of a temperature. The extinguished agent in the composition of $N_2$, Ar and $CO_2$, 50/40/10 (mol %) showed relatively high density, low viscosity and moderate surface tension, therefore it was suitable for the alternative extinguished agents.

Effect of Silk Fibroin Biomaterial Coating on Cell Viability and Intestinal Adhesion of Probiotic Bacteria

  • Kwon, Gicheol;Heo, Bohye;Kwon, Mi Jin;Kim, Insu;Chu, Jaeryang;Kim, Byung-Yong;Kim, Byoung-Kook;Park, Sung Sun
    • Journal of Microbiology and Biotechnology
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    • v.31 no.4
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    • pp.592-600
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    • 2021
  • Probiotics can be processed into a powder, tablet, or capsule form for easy intake. They are exposed to frequent stresses not only during complex processing steps, but also in the human body after intake. For this reason, various coating agents that promote probiotic bacterial stability in the intestinal environment have been developed. Silk fibroin (SF) is a material used in a variety of fields from drug delivery systems to enzyme immobilization and has potential as a coating agent for probiotics. In this study, we investigated this potential by coating probiotic strains with 0.1% or 1% water-soluble calcium (WSC), 1% SF, and 10% trehalose. Under simulated gastrointestinal conditions, cell viability, cell surface hydrophobicity, and cell adhesion to intestinal epithelial cells were then measured. The survival ratio after freeze-drying was highest upon addition of 0.1% WSC. The probiotic bacteria coated with SF showed improved survival by more than 10.0% under simulated gastric conditions and 4.8% under simulated intestinal conditions. Moreover, the cell adhesion to intestinal epithelial cells was elevated by 1.0-36.0%. Our results indicate that SF has positive effects on enhancing the survival and adhesion capacity of bacterial strains under environmental stresses, thus demonstrating its potential as a suitable coating agent to stabilize probiotics throughout processing, packaging, storage and consumption.

Effect of Chelating Agent on Li1.5Al0.5Ti1.5(PO4)3 Particles by Sol-gel Method and Densification (Sol-Gel법에 의한 Li1.5Al0.5Ti1.5(PO4)3 고체전해질 제조 및 chelating agent의 영향)

  • SungJoon Ryu;Seul Ki Choi;Jong Ho Won;MinHo Yang
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.394-401
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    • 2023
  • Li1.5Al0.5Ti1.5(PO4)3 (LATP) is considered to be one of the promising solid-state electrolytes owing to its excellent chemical and thermal stability, wide potential range (~5.0 V), and high ionic conductivity (~10-4 S/cm). LATP powders are typically prepared via the sol-gel method by adding and mixing nitrate or alkoxide precursors with chelating agents. Here, the thermal properties, crystallinity, density, particle size, and distribution of LATP powders based on chelating agents (citric acid, acetylacetone, EDTA) are compared to find the optimal conditions for densely sintered LATP with high purity. In addition, the three types of LATP powders are utilized to prepare sintered solid electrolytes and observe the microstructure changes during the sintering process. The pyrolysis onset temperature and crystallization temperature of the powder samples are in the order AC-LATP > CA-LATP > ED-LATP, and the LATP powder utilizing citric acid exhibits the highest purity, as no secondary phase other than LiTi2PO4 phase is observed. LATP with citric acid and acetylacetone has a value close to the theoretical density (2.8 g/cm3) after sintering. In comparison, LATP with EDTA has a low sintered density (2.2 g/cm3) because of the generation of many pores after sintering.